IP Library Granted Patent US 9,796,839
Granted Patent B2
US 9,796,839 · App. 14/414,576 · Granted Oct 24, 2017

Polypropylene compounds having non-migratory slip properties

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Quick Facts
Patent No.
US 9,796,839
App. No.
14/414,576
Granted
Oct 24, 2017
Kind
B2
Abstract

A masterbatch having epoxy-functionalized silicone as a slip additive, the polypropylene compound that the silicone-containing masterbatch has been let down into, and the plastic articles and films from such compounds having improved slip properties are disclosed. The improved slip properties are evidenced by (1) essentially no migration of the slip additive 12 weeks after manufacturing, (2) a dynamic coefficient of friction value of less than 0.4 and a static coefficient of friction 0.6 or less within the first day of manufacturing according to the ASTM D1894-01 method, and (3) less than 15% change in the dynamic and static coefficient of friction values between the first day of manufacturing and 20 days after manufacturing.

Claims (27)

1. A masterbatch for polypropylene, comprising in weight percent of the masterbatch:

(a) from 45 to 81 weight percent of polypropylene carrier,

(b) from 5 to 10 weight percent of epoxy functionalized polysiloxane,

(c) from 9 to 45 weight percent of functionalized polyolefin, and

(d) optionally, from 0 to 10 weight percent of other additives;

wherein the functionalized polyolefin contains a maleic anhydride group and is a grafting agent for the epoxy functionalized polysiloxane.

2. The masterbatch of claim 1 , wherein the functionalized polyolefin is selected from the group consisting of maleic anhydride grafted polypropylene, maleic anhydride polypropylene copolymer, ethylene ethyl acrylate maleic anhydride terpolymer, and combinations of them.

3. A polypropylene compound comprising the masterbatch of claim 1 and polypropylene resin.

4. A polypropylene compound comprising:

(a) polypropylene matrix and

(b) a slip additive comprising in weight percent of the slip additive

(i) from 45 to 81 weight percent of polypropylene carrier,

(ii) from 5 to 10 weight percent of epoxy functionalized polysiloxane,

(ii) from 9 to 45 weight percent of functionalized polyolefin, and

(iv) optionally, from 0 to 10 weight percent of other additives;

wherein the functionalized polyolefin contains a maleic anhydride group and is a grafting agent for the epoxy functionalized polysiloxane.

5. The polypropylene compound of claim 4 , wherein the functionalized polyolefin is miscible with the polypropylene matrix.

6. The polypropylene compound of claim 4 , wherein the additive is selected from the group consisting of anti-blocking agents; adhesion promoters; biocides (antibacterials, fungicides, and mildewcides), anti-fogging agents; anti-static agents; bonding, blowing and foaming agents; dispersants; fillers and extenders; fire and flame retardants and smoke suppressants; impact modifiers; initiators; lubricants; micas; pigments, colorants and dyes; plasticizers; processing aids; other slip or release agents; silanes, titanates and zirconates; stabilizers; stearates; ultraviolet light absorbers; viscosity regulators; waxes; and combinations of them.

7. The polypropylene compound of claim 4 , wherein one or more additives are added in the form of a masterbatch concentrate.

8. The polypropylene compound of claim 4 , in the shape of a molded plastic article, an extruded plastic article, or a calendered plastic article.

9. A film having at least one layer comprised of the polypropylene compound of claim 4 .

10. A laminate of the film of claim 9 , wherein there is more than one film layer, and wherein each layer comprises same or different ingredients.

11. The laminate of claim 10 , wherein there is a skin layer contacting one surface of a core layer also having an opposing surface; and wherein the skin layer has a thickness between about 0.5 microns and about 1 millimeter.

12. The laminate of claim 11 , further comprising a second skin layer contacting the opposing surface of the core layer, wherein the core layer comprises polyolefin resin.

13. The laminate of claim 11 , wherein the skin layer has dynamic coefficient of friction value of 0.4 or less and static coefficient of friction value of 0.6 or less, according to the ASTM D1894-01 method, within 1 day after manufacturing of the laminate.

14. The laminate of claim 11 , wherein the change between static coefficient of friction and dynamic coefficient of friction values of the skin layer within 1 day after manufacturing and 20 days after manufacturing, according to the ASTM D1894-01 method, is 15% or less.

15. The laminate of claim 11 , wherein there is essentially no migration of the slip additive from the skin layer into another film layer measured 12 weeks after manufacturing.

Assignments (9)
RELEASE OF SECURITY INTERESTS IN PATENTS RECORDED AT REEL 037101, FRAME 0448. Recorded Jun 24, 2025
From: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
To: AVIENT CORPORATION (F/K/A POLYONE CORPORATION); COLORMATRIX HOLDINGS, INC.
Reel/Frame 071730/0746 →
SECURITY AGREEMENT Recorded Jun 12, 2025
From: AVIENT CORPORATION; COLORMATRIX HOLDINGS, INC.; COLORMATRIX GROUP, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 071574/0571 →
CHANGE OF NAME Recorded Jul 13, 2020
From: POLYONE CORPORATION
To: AVIENT CORPORATION
Reel/Frame 053197/0141 →
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME 037113/0144 Recorded Mar 23, 2018
From: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: POLYONE CORPORATION; COLORMATRIX HOLDINGS, INC.
Reel/Frame 045680/0342 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT APPLICATION NUMBER 14/501,050 PREVIOUSLY RECORDED ON REEL 037101 FRAME 0448. ASSIGNOR(S) HEREBY CONFIRMS THE PATENT SECURITY AGREEMENT. Recorded Jan 27, 2016
From: POLYONE CORPORATION; COLORMATRIX HOLDINGS, INC.; POLYONE DESIGNED STRUCTURES AND SOLUTIONS LLC
To: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 037603/0208 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT APPL. NO. 14/501,050 PREVIOUSLY RECORDED AT REEL: 037113 FRAME: 0144. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT. Recorded Jan 7, 2016
From: POLYONE CORPORATION; COLORMATRIX HOLDINGS, INC.; POLYONE DESIGNED STRUCTURES AND SOLUTIONS LLC
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 037508/0012 →
SECURITY AGREEMENT Recorded Nov 19, 2015
From: POLYONE CORPORATION; COLORMATRIX GROUP, INC.; COLORMATRIX HOLDINGS, INC.; THE COLORMATRIX CORPORATION; GAYSON SILICONE DISPERSIONS, INC.; POLYONE DESIGNED STRUCTURES AND SOLUTIONS LLC
To: CITIBANK, N.A,, AS ADMINISTRATIVE AGENT
Reel/Frame 037146/0724 →
PATENT SECURITY AGREEMENT Recorded Nov 16, 2015
From: POLYONE CORPORATION; COLORMATRIX HOLDINGS, INC.; POLYONE DESIGNED STRUCTURES AND SOLUTIONS LLC
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 037113/0144 →
SECURITY INTEREST Recorded Nov 12, 2015
From: POLYONE CORPORATION; COLORMATRIX HOLDINGS, INC.; POLYONE DESIGNED STRUCTURES AND SOLUTIONS LLC
To: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 037101/0448 →