Separator for electricity storage device, laminate and porous film
An object is to provide a separator excellent in adhesiveness to electrodes and a separator for an electricity storage device also excellent in handling performance. A separator for an electricity storage device having a polyolefin microporous film and a thermoplastic polymer coating layer covering at least a part of at least one of surfaces of the polyolefin microporous film, in which the thermoplastic polymer coating layer, on the polyolefin microporous film, has a portion containing a thermoplastic polymer and a portion not containing the thermoplastic polymer in a sea-island configuration, the thermoplastic polymer coating layer contains the thermoplastic polymer having at least two glass-transition temperatures, at least one of the glass-transition temperatures is in a range of less than 20° C. and at least one of the glass-transition temperatures is in a range of 20° C. or more.
1. A separator for an electricity storage device comprising a polyolefin microporous film and a thermoplastic polymer coating layer covering at least a part of at least one of surfaces of the polyolefin microporous film, wherein
the thermoplastic polymer coating layer, on the polyolefin microporous film, comprises a thermoplastic polymer in a sea-island configuration,
the thermoplastic polymer coating layer contains the thermoplastic polymer having at least two glass-transition temperatures,
at least one of the glass-transition temperatures is in a range of less than 20° C., and
at least one of the glass-transition temperatures is in a range of 20° C. or more.
2. The separator for the electricity storage device according to claim 1 , wherein, in the thermoplastic polymer coating layer,
a thermoplastic resin having a glass-transition temperature of 20° C. or more is present on a side of a outermost surface of the separator for the electricity storage device, and
a thermoplastic resin having a glass-transition temperature of less than 20° C. is present on a side of a interface between the polyolefin microporous film and the thermoplastic polymer coating layer.
3. The separator for the electricity storage device according to claim 1 , wherein a peel strength of an aluminum foil after the aluminum foil is pressed at a temperature of 25° C. and a pressure of 5 MPa for 3 minutes against the outermost surface of the separator for the electricity storage device having the thermoplastic polymer coating layer thereon is 8 gf/cm or less.
4. The separator for the electricity storage device according to claim 1 , wherein a peel strength of an aluminum foil after the aluminum foil is pressed at a temperature of 80° C. and a pressure of 10 MPa for 3 minutes against the outermost surface of the separator for the electricity storage device having the thermoplastic polymer coating layer thereon is 10 gf/cm or more.
5. The separator for the electricity storage device according to claim 1 , wherein a 90° peel strength of the polyolefin microporous film and the thermoplastic polymer coating layer is 6 gf/mm or more.
6. The separator for the electricity storage device according to claim 1 , wherein, in the thermoplastic polymer coating layer, at least a part of the thermoplastic polymer present on the outermost surface of the separator for the electricity storage device is a particulate thermoplastic polymer.
7. The separator for the electricity storage device according to claim 6 , wherein the particulate thermoplastic polymer has an average particle size of 0.01 μm to 0.4 μm.
8. The separator for the electricity storage device according to claim 1 , wherein an area ratio of the polyolefin microporous film covered with the thermoplastic polymer coating layer is 95% or less based on 100% of a total area of the polyolefin microporous film.
9. The separator for the electricity storage device according to claim 1 , wherein an area ratio of the polyolefin microporous film covered with the thermoplastic polymer coating layer is 50% or less based on 100% of the total area of the polyolefin microporous film.
10. A laminate formed by laminating the separator for the electricity storage device according to claim 1 and electrodes.
11. The separator for the electricity storage device according to claim 1 , wherein the thermoplastic polymer coating layer has an average thickness of 1.5 μm or less.
12. The separator for the electricity storage device according to claim 1 , wherein a content of the thermoplastic polymer in the thermoplastic polymer coating layer is 0.05 g/m 2 or more and 1.0 g/m 2 or less.