IP Library Granted Patent US 9,670,319
Granted Patent B2
US 9,670,319 · App. 14/416,935 · Granted Jun 6, 2017

Polyamide, preparation process therefor and uses thereof

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Quick Facts
Patent No.
US 9,670,319
App. No.
14/416,935
Granted
Jun 6, 2017
Kind
B2
Abstract

The present invention relates to a novel polyamide synthesized from biobased monomers. The novel polyamide comprises the repeating unit of formula (I) below: Formula (I), in which R represents a covalent bond or a divalent hydrocarbon-based chosen from saturated or unsaturated aliphatics, saturated or unsaturated cycloaliphatics, aromatics, arylaliphatics and alkylaromatics. The present invention also relates to the process for preparing the said polyamide, to its uses, and to articles and compositions comprising the polyamide.

Claims (17)

1. A process for preparing a polyamide comprising the repeating unit of formula I below:

in which

R represents a covalent bond or a divalent hydrocarbon-based group chosen from saturated or unsaturated aliphatics, saturated or unsaturated cycloaliphatics, aromatics, arylaliphatics and alkylaromatics; the process comprising a polycondensation reaction between:

at least one dicarboxylic acid or at least one carboxylic acid diester, at least one dinitrile or at least one acyl dichloride of respective formulae IV, IV′, IV″ and IV″′ below:

where R 1 and R 2 , which are identical or different, are chosen from C1-C4 alkyls;

and

at least one diamine of formula V below:

H 2 N—R—NI 2   (V)

wherein R represents a covalent bond or a divalent hydrocarbon-based group chosen from saturated or unsaturated aliphatics, saturated or unsaturated cycloaliphatics, aromatics, arylaliphatics and alkylaromatics.

2. The process according to claim 1 , wherein at least one diamine of formula V is biobased according to standard ASTM D6866.

3. The process according to claim 1 , wherein said process comprises a polycondensation reaction between:

at least one dicarboxylic acid of formula IV below:

and

at least one diamine of formula V below:

H 2 N—R—NH 2   (V).

4. The process according to claim 1 , wherein at least the dicarboxylic acid of formula IV is biobased according to standard ASTM D6866.

5. A method for making articles comprising preparing a polyamide according to the process of claim 1 , and molding, injection-molding, injection/blow-molding, extrusion/blow-molding, extruding or spinning the polyamide.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2024
From: RHODIA OPERATIONS
To: SPECIALTY OPERATIONS FRANCE
Reel/Frame 066374/0642 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2023
From: RHODIA OPERATIONS
To: SPECIALTY OPERATIONS FRANCE
Reel/Frame 065488/0365 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2015
From: JEOL, STÉPHANE; DECAMPO, FLORYAN; ZHU, LEON
To: RHODIA OPERATIONS
Reel/Frame 034811/0973 →