Hydrophilic sheet and process for producing the same
Provided is a hydrophilic fluororesin sheet having significantly improved properties such as filtering performance which includes primary fibers and secondary fibers having a smaller fiber diameter than a fiber diameter of the primary fibers, the secondary fibers crosslinking in each of the primary fibers and/or crosslinking between different primary fibers in such a manner that no knots are formed at crosslinking points, the primary fibers and the secondary fibers including fluororesin fibers including polytetrafluoroethylene [PTFE], wherein a surface of the sheet to which hydrophilization treatment has been applied.
1. A hydrophilic sheet obtained by applying hydrophilization treatment to a fluororesin sheet,
wherein a surface of the hydrophilic sheet has hydrophilicity such that a water contact angle is 90° or less, and
wherein the fluororesin sheet comprises primary fibers and secondary fibers having a smaller fiber diameter than a fiber diameter of the primary fibers,
the secondary fibers crosslinking in each of the primary fibers and/or crosslinking between different primary fibers in such a manner that no knots are formed at crosslinking points,
the primary fibers and the secondary fibers comprising fluororesin fibers that comprise polytetrafluoroethylene [PTFE],
wherein the primary fibers have a fiber diameter of from 500 nm to 1 μm, and the secondary fibers have a fiber diameter of from 30 nm to 300 nm.
2. The hydrophilic sheet according to claim 1 , wherein the fluororesin fibers comprise, in addition to PTFE, at least one kind of fluororesin selected from the group consisting of tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer [PFA], tetrafluoroethylene-hexafluoropropylene copolymer [FEP], tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer [EPE], poly(chlorotrifluoroethylene) [PCTFE], tetrafluoroethylene-ethylene copolymer [ETFE], low melting point ethylene-tetrafluoroethylene copolymer, ethylene-chlorotrifluoroethylene copolymer [ECTFE], polyvinylidene fluoride [PVDF], fluoroethylene-vinyl ether copolymer [FEVE] and tetrafluoroethylene-perfluorodioxole copolymer [TFEPD], the fluororesin(s) being contained at more than 0 wt % and less than 50 wt % provided that PTFE and the fluororesin(s) total 100 wt %.
3. The hydrophilic sheet according to claim 1 , wherein the fluororesin fibers consist of PTFE.
4. The hydrophilic sheet according to claim 1 , wherein the hydrophilization treatment is a coating treatment using a hydrophilic group-having compound.
5. The hydrophilic sheet according to claim 4 , wherein the hydrophilic group-having compound is at least one compound selected from the group consisting of hydroxyl group-containing compounds, carboxylic acid group-containing compounds, sulfonic acid group-containing compounds, ether group-containing compounds, epoxy group containing compounds and amino group-containing compounds.
6. The hydrophilic sheet according to claim 4 , wherein the hydrophilic group-having compound is polyvinyl alcohol [PVA].
7. The hydrophilic sheet according to claim 2 , wherein the hydrophilization treatment is a coating treatment using a hydrophilic group-having compound.
8. The hydrophilic sheet according to claim 3 , wherein the hydrophilization treatment is a coating treatment using a hydrophilic group-having compound.
9. The hydrophilic sheet according to claim 5 , wherein the hydrophilic group-having compound is polyvinyl alcohol [PVA].
10. A process for producing the hydrophilic sheet according to claim 1 comprising:
a secondary fiber formation step of causing stress in at least two directions in a fluororesin fiber sheet made of fluororesin fibers while heating the sheet to form the secondary fibers thereby obtaining a fluororesin sheet; and
a hydrophilization step of applying hydrophilization treatment to a surface of the fluororesin sheet to obtain the hydrophilic sheet.
11. The process for producing the hydrophilic sheet according to claim 10 , wherein
the fluororesin fiber sheet is a fluororesin fiber sheet formed into a sheet from fluororesin fibers, the fluororesin fibers being prepared by electrospinning method,
a temperature of the heating ranges from 180° C. to 400° C., and
the stress is caused by applying compressive load ranging from 0.01 kg/cm 2 to 10 kg/cm 2 and shearing load.
12. The process for producing the hydrophilic sheet according to claim 11 , wherein
the temperature of the heating ranges from 300° C. to 360° C., and the stress is caused by applying compressive load ranging from 0.05 kg/cm 2 to 1 kg/cm 2 and shearing load.
13. The process for producing the hydrophilic sheet according to claim 10 , wherein the hydrophilization step comprises:
a step (v) of immersing the fluororesin sheet in a solution of the hydrophilic group-having compound to coat the fluororesin sheet with the compound, and
a step (vi) of crosslinking the compound having coated the fluororesin sheet obtained in the step (v).
14. The process for producing the hydrophilic sheet according to claim 11 , wherein the hydrophilization step comprises:
a step (v) of immersing the fluororesin sheet in a solution of the hydrophilic group-having compound to coat the fluororesin sheet with the compound, and
a step (vi) of crosslinking the compound having coated the fluororesin sheet obtained in the step (v).
15. The process for producing the hydrophilic sheet according to claim 12 , wherein the hydrophilization step comprises:
a step (v) of immersing the fluororesin sheet in a solution of the hydrophilic group-having compound to coat the fluororesin sheet with the compound, and
a step (vi) of crosslinking the compound having coated the fluororesin sheet obtained in the step (v).