Lubricating oil composition for internal combustion engines
View Patent ↗A lubricating oil composition for internal combustion engines containing a base oil mixture with specific properties and a monoglyceride with a specific structure. The lubricating oil composition of the present 5 invention, as well as providing outstanding wear resistance and fuel economy, causes condensed water etc. from water vapor produced as a result of fuel combustion to be dispersed in the oil, so preventing corrosion or rusting of the engine.
1. A lubricating oil composition for internal combustion engines comprising:
(A) a base oil mixture comprising at least two base oils in different API (American Petroleum Institute) categories, the base oil mixture having a sulphur content of from 0.14 to 0.7 mass %, % CA in accordance with ASTM D3238 of from 0.9 to 5.0, and % CP in accordance with ASTM D3238 of 60 or more, and
(B) a monoglyceride with a hydrocarbon group having from 8 to 22 carbon atoms (a glycerine fatty acid ester with the fatty acid ester bonded to one of the three hydroxyl groups of the glycerine), wherein the monoglyceride has a hydroxyl value of from 150 to 300 mgKOH/g and is present at a level of from 0.3 to 2.0 mass % based on the total mass of the composition, wherein the base oil mixture (A) comprises a base oil classified as Group 1 by the API (American Petroleum Institute) with a kinematic viscosity at 100° C. in the range of from 3 to 12 mm 2 /s, a viscosity index in the range of from 90 to 120, a sulphur content of from 0.03 to 0.7 mass %, % CA of 5 or less according to ASTM D3238, and % CP of 60 or more according to ASTM D3238, and present at a level of from 25 to 50 mass % based on the total mass of the composition;
wherein the lubricating oil composition comprises a friction coefficient in the range of 0.095 to 0.098 at a temperature of 80° C. and a load of 300 newton (N); and
wherein the lubricating oil composition is subjected to an emulsification test to determine emulsion stability.
2. The lubricating oil composition for internal combustion engines according to claim 1 , wherein the monoglyceride (B) is glycerine monooleate.
3. The lubricating oil composition for internal combustion engines according to claim 1 , wherein the composition has a kinematic viscosity at 100° C. in the range of from 5.6 to 15 mm 2 /s.
4. The lubricating oil composition for internal combustion engines according to claim 1 wherein the monoglyceride is present at a level of from 0.4 to 1.7 mass % based on the total mass of the composition.
5. The lubricating oil composition for internal combustion engines according to claim 1 wherein the monoglyceride is present at a level of from 0.5 to 1.5 mass % based on the total mass of the composition.
6. The lubricating oil composition for internal combustion engines according to claim 1 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the % CA in the base oil mixture is in the range of from 0.1 to 1.0.
7. The lubricating oil composition for internal combustion engines according to claim 1 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the % CA in the base oil mixture is in the range of from 0.3 to 1.0.
8. The lubricating oil composition for internal combustion engines according to claim 1 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the sulphur mass % in the base oil mixture is in the range of from 1.0 to 6.5.
9. The lubricating oil composition for internal combustion engines according to claim 1 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the sulphur mass % in the base oil mixture is in the range of from 3.5 to 6.0.
10. A method comprising lubricating an internal combustion engine with a lubricating oil composition that comprises:
(A) a base oil mixture comprising at least two base oils in different API (American Petroleum Institute) categories, the base oil mixture having a sulphur content of from 0.14 to 0.7 mass %, % CA in accordance with ASTM D3238 of from 0.9 to 5.0, and % CP in accordance with ASTM D3238 of 60 or more, and
(B) a monoglyceride with a hydrocarbon group having from 8 to 22 carbon atoms (a glycerine fatty acid ester with the fatty acid ester bonded to one of the three hydroxyl groups of the glycerine), wherein the monoglyceride has a hydroxyl value of from 150 to 300 mgKOH/g and is present at a level of from 0.3 to 2.0 mass % based on the total mass of the composition, and wherein the internal combustion engine uses a fuel with H/C ratios of from 1.93 to 4, is fitted with idlestop equipment, or uses a fuel incorporating a biofuel or a biodiesel, wherein the base oil mixture (A) comprises a base oil classified as Group 1 by the API (American Petroleum Institute) with a kinematic viscosity at 100° C. in the range of from 3 to 12 mm 2 /s, a viscosity index in the range of from 90 to 120, a sulphur content of from 0.03 to 0.7 mass %, % CA of 5 or less according to ASTM D3238, and % CP of 60 or more according to ASTM D3238, and present at a level of from 25 to 50 mass % based on the total mass of the composition;
wherein the lubricating oil composition comprises a friction coefficient in the range of 0.095 to 0.098 at a temperature of 80° C. and a load of 300 newton (N); and
wherein the lubricating oil composition is subjected to an emulsification test to determine emulsion stability.
11. The method according to claim 10 wherein the monoglyceride (B) is glycerine monooleate.
12. The method according to claim 10 wherein the composition has a kinematic viscosity at 100° C. in the range from 5.6 to 15 mm 2 /s.
13. The method according to claim 10 wherein the monoglyceride is present at a level of from 0.4 to 1.7 mass % based on the total mass of the composition.
14. The method according to claim 10 wherein the monoglyceride is present at a level of from 0.5 to 1.5 mass % based on the total mass of the composition.
15. The method according to claim 10 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the % CA in the base oil mixture is in the range of from 0.1 to 1.0.
16. The method according to claim 10 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the % CA in the base oil mixture is in the range of from 0.3 to 1.0.
17. The method according to claim 10 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the sulphur mass % in the base oil mixture is in the range of from 1.0 to 6.5.
18. The method according to claim 10 wherein the ratio of the monoglyceride mass % in the lubricating oil composition to the sulphur mass % in the base oil mixture is in the range of from 3.5 to 6.0.