Negative electrode active material
View Patent ↗Provided is a negative electrode active material that can improve the capacity per volume and charge-discharge cycle characteristics of a nonaqueous electrolyte secondary battery represented by a lithium ion secondary battery. The negative electrode active material according to the present embodiment contains an alloy phase. The alloy phase undergoes thermoelastic diffusionless transformation when releasing or occluding metal ions. The negative electrode active material of the present embodiment is used in a nonaqueous electrolyte secondary battery. Thermoelastic diffusionless transformation refers to so-called thermoelastic martensitic transformation.
1. A negative electrode active material, comprising an alloy phase that undergoes thermoelastic diffusionless transformation either when releasing metal ions, or when occluding the metal ion, wherein
the alloy phase undergoes the thermoelastic diffusionless transformation when occluding the metal ions, and undergoes reverse transformation when releasing the metal ions, wherein
the alloy phase after the thermoelastic diffusionless transformation contains a crystal structure which is 2H in Ramsdell notation, and
the alloy phase after the reverse transformation contains a crystal structure which is DO 3 in Strukturbericht notation, wherein
the negative electrode active material contains 21 to 27 at % of Sn, with the balance being Cu and impurities, or
the negative electrode active material contains:
Sn: 10 to 35 at %, and
one or more selected from the group consisting of Ti: 9.0 at % or less, V: 49.0 at % or less, Cr: 49.0 at % or less, Mn: 9.0 at % or less, Fe: 49.0 at % or less, Co: 49.0 at % or less, Ni: 9.0 at % or less, Zn: 29.0 at % or less, Al: 49.0 at % or less, Si: 49.0 at % or less, B: 5.0 at % or less, and C: 5.0 at % or less, with the balance being Cu and impurities.
2. The negative electrode active material according to claim 1 , wherein
the negative electrode active material further contains one or more selected from the group consisting of δ phase of F-Cell structure, ε phase, η′ phase, and a phase having DO 3 structure, each including site deficiency.
3. A negative electrode, comprising the negative electrode active material according to claim 1 .
4. A battery, comprising the negative electrode according to claim 3 .