Hard coating film
The present invention relates to a hard coating film, and, more particularly, to a hard coating film having hardness and excellent physical properties. According to the present invention, the hard coating film has high physical properties including hardness, fouling resistance, slip resistance, scratch resistance, transparency, durability, light resistance, and light transmittance. Thus, the hard coating film can find useful applications in various fields thanks to its excellent physical properties.
1. A hard coating film, comprising:
a supporting substrate;
a first hard coating layer, formed on one side of the supporting substrate, having a first surface energy; and
a second hard coating layer, formed on another side of the supporting substrate, having a second surface energy, with a difference between the first and the second surface energies set to be 3 mN/m or greater, and
wherein the hard coating film exhibits a pencil hardness of 7H or more at a load of 1 kg.
2. The hard coating film of claim 1 , wherein the first surface energy is 26 mN/m or more and the second surface energy is 23 mN/m or less.
3. The hard coating film of claim 1 , wherein the second hard coating layer has a fluorine (F) content of 12 mol % or more, based on the total element content thereof, as measured on a surface thereof or at a depth of 1 mm from the surface by XPS.
4. The hard coating film of claim 1 , wherein the second hard coating layer contains a fluorine compound.
5. The hard coating film of claim 1 , wherein the second hard coating layer has a fluorine (F) content of 12 mol % or less, based on the total element content thereof, as measured on a surface thereof or at a depth of 1 mm from the surface by XPS.
6. The hard coating film of claim 1 , wherein the first hard coating layer is surface treated with plasma, corona discharge, or an alkaline solution.
7. The hard coating film of claim 1 , wherein the first and the second hard coating layers are the same or different, and independently comprise a photocurable crosslinking copolymer of a tri- to hexa-functional acrylate monomer.
8. The hard coating film of claim 7 , wherein the first and the second hard coating layer are the same or different, and independently comprise a photocurable crosslinking copolymer of a tri- to hexa-functional acrylate monomer and a mono- to bi-functional acrylate in addition to the tri- to hexa-functional acrylate monomer.
9. The hard coating film of claim 1 , wherein the first and the second hard coating layer are the same or different, and independently comprise a photocurable crosslinking copolymer of a photocurable elastic polymer in addition to the tri- to hexa-functional acrylate monomer.
10. The hard coating film of claim 9 , wherein the photocurable elastic polymer has an elongation of 15 to 200%, as measured according to ASTM D638.
11. The hard coating film of claim 9 , wherein the photocurable elastic polymer is selected from the group consisting of a polycaprolactone, a urethane acrylate polymer, a polyrotaxane, and a combination thereof.
12. The hard coating film of claim 11 , wherein the polyrotaxane comprises a cyclic moiety (macrocycle) in which lactone compounds with a (meth) acrylate moiety conjugated to the end thereof are bonded to each other; a thread moiety held within the macrocycle; and stoppers provided at both ends of the thread moiety so as to prevent dissociation of the macrocycle.
13. The hard coating film of claim 7 , wherein the first and the second hard coating layers are the same or different, and independently further comprise inorganic microparticles dispersed in the photocurable crosslinking polymer.
14. The hard coating film of claim 1 , wherein the first and the second hard coating layers are the same or different, and independently range in thickness from 50 to 300 μm.
15. The hard coating film of claim 7 , wherein the tri- to hexa-functional acrylate monomer comprises at least one selected from the group consisting of trimethylolpropane triacrylate (TMPTA), trimethylolpropane ethoxytriacrylate (TMPEOTA), glycerin propoxylated triacrylate (GPTA), pentaerythritol tetraacrylate (PETA), and dipentaerythritol hexaacrylate (DPHA).
16. The hard coating film of claim 1 , wherein the supporting substrate includes at least one selected from consisting of polyethyleneterephtalate (PET), ethylene vinyl acetate (EVA), a cyclic olefin polymer (COP), a cyclic olefin copolymer (COC), polyacrylate (PAC), polycarbonate (PC), polyethylene (PE), polymethylmethacrylate (PMMA), polyetheretherketon (PEEK), polyethylenenaphthalate (PEN), polyetherimide (PEI), polyimide (PI), triacetylcellulose (TAC), MMA (methyl methacrylate) and a fluoro-polymer.
17. The hard coating film of claim 1 , wherein the hard coating film does not crack when a 22 g steel ball is freely dropped 10 times thereon from a height of 50 cm.
18. The hard coating film of claim 1 , two or less scratches are formed when the surface of the hard coating film is rubbed by reciprocating a steel wool #0000 thereon 400 times under a load of 500 g.
19. The hard coating film of claim 1 , having a light transmittance of 91% or more, a haze of 0.4 or less, and a color b* value of 1.0 or less.
20. The hard coating film of claim 1 , wherein the hard coating film has a color b* value after exposure to UV B for 72 hrs which differs from a pre-exposed, color b* value by 0.5 or less.
21. The hard coating film of claim 1 , wherein when the hard coating film is disposed on a plane after exposure to a temperature of 50 ° C. or higher at a humidity of 80% or higher for 70 hrs or longer, film is spaced apart maximally.
22. The hard coating film of claim 1 , further comprising on the first or the second hard coating layer at least one layer selected from the group consisting of a plastic resin film, an adhesive film, an releasable film, an electrically conductive film, an electrically conductive layer, a curable resin layer, a non-conductive film, a metal mesh layer, and a patterned metal layer.