Flame-Resistant Coating For The Rear Side Of A Carpet
A hot-melt adhesive designed to be flame-resistant, characterized in that the adhesive contains the following components: a) 20 to 70 percent by weight of one or more polyolefin wax(es) of one or more C3-C18 [alpha]-olefin(s) and optionally ethylene; b) 9 to 30 percent by weight of expanded graphite; c) 5 to 30 percent by weight of a further flame retardant; d) 0 to 15 percent by weight of an antistatic agent; e) 0 to 12 percent by weight of one or more resin(s); f) 0 to 40 percent by weight of one or more amorphous, atactic poly [alpha]-olefin(s) (APAO).
1 . A hot-melt adhesive composition having a flame-retardant finish, comprising:
a) 20 to 70 wt. % of one or more polyolefin waxes of one or more C 3 -C 18 -α-olefin(s) and optionally ethylene,
b) 9 to 30 wt. % of expandable graphite,
c) 5 to 30 wt. % of a further flameproofing agent,
d) 0 to 15 wt. % of an antistatically active auxiliary substance,
e) 0 to 12 wt. % of one or more resin(s) resins, and
f) 0 to 40 wt. % of one or more amorphous, atactic poly-α-olefin(s) (APAO)
2 . A hot-melt adhesive composition having a flame-retardant finish, comprising:
a) 40 to 70 wt. % of one or more polyolefin waxes of one or more C 3 -C 18 -α-olefin(s) and optionally ethylene,
b) 9 to 30 wt. % of expandable graphite,
c) 5 to 30 wt. % of a further flameproofing agent,
d) 0 to 15 wt % of an antistatically active auxiliary substance, and
e) 0 to 12 wt. % of one or more resin(s) resins
3 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin waxes are one or more homopolymers based on ethylene or propylene or one or more copolymers comprising propylene and 0.1 to 30 wt. % of ethylene, 0.1 to 50 wt. % of at least one branched or unbranched C 4 -C 20 α-olefin or a combination thereof.
4 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin waxes have a ring/ball softening point of between 40° C. and 160° C., and a melt viscosity, measured at 170° C., of a maximum of 40,000 mPa·s.
5 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin wax has a weight-average molecular weight M w of between 1,000 and 40,000 g/mol and a number-average molecular weight M n of between 500 and 25,000 g/mol, and an M w /M n of <5.
6 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin wax has been prepared with the aid of metallocene catalysts.
7 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claims 1 , comprising a synergistic combination of expandable graphite and one or more further flameproofing agent in the combination of expandable graphite to flameproofing agent (combination) of from 1:3 to 3:1.
8 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising as a further flameproofing agent one or more from the group of halogenated, N based or a combination thereof.
9 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising a sterically hindered alkoxyamine as a flameproofing agent.
10 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising an antistatically acting auxiliary substance from the group of conductive antistatics.
11 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 comprising colophony resins and derivatives thereof or hydrocarbon resins.
12 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising up to 40 wt. % of one or more amorphous, atactic poly-alpha-olefins having predominantly amorphous melting properties and a crystallinity of less than 30%, determined by differential scanning calorimetry.
13 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claims 1 , wherein the hot-melt adhesive composition has a ring/ball softening point of between 40 and 160° C., and a melt viscosity, measured at 170° C., of between 5,000 and 120,000 mPa·s.
14 . A hot-melt adhesive comprising a hot-melt adhesive composition as claimed in claim 1 .
15 . A hot-melt adhesive composition as claimed in claim 1 , wherein this is applied without using a solvent as a finished mixture in the melt at between 100 to 180° C.
16 . A hot-melt adhesive for the reverse side coating of textile sheet-like structures comprising a hot-melt adhesive composition as claimed in claim 1 .
17 . A hot-melt adhesive for the reverse side coating of electrically heated textile sheet-like structures comprising a hot-melt adhesive composition as claimed in claim 1 .
18 . A hot-melt adhesive for gluing electrically heated textile composites comprising a hot-melt composition as claimed in claim 1 .
19 . A hot-melt adhesive composition claim 1 , wherein after finishing of textile sheet-like structures, the textile sheet-like structures have a surface resistance and a volume resistance of less than 10 10 Ω.
20 . A hot-melt adhesive as claimed in claim 16 , wherein the application weight of the hot-melt adhesive is between 25 to 2,000 g/m 2 .
21 . A hot-melt adhesive as claimed in claim 16 for finishing textile sheet-like structures, wherein the fibers of the sheet-like structure are made of wool, cotton, flax, sisal, coconut fibers, cellulose fibers or of combustible synthetic fibers polyester or of polyamide or polyacrylonitrile or mixtures thereof and optionally comprise a flame-retardant finish.
22 . The use of a hot-melt adhesive as claimed in claim 21 , wherein the fibers additionally comprise a content of non-combustible fibers, glass fibers or a combination thereof.
23 . A hot-melt adhesive composition as claimed in comprises further fillers.
24 . A hot-melt adhesive composition as claimed in claim 1 , wherein the polyolefin wax is separated off in a pure form from the other constituents of the hot-melt adhesive composition having a flame-retardant finish and from the components of the textile sheet-like structure finished therewith by a suitable solvent-based separation method at temperatures below 100° C. with, toluene or xylene.
25 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 24 , wherein the recycled polyolefin wax in the pure form deviates from its original mechanical material properties by not more than 15%.
26 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin waxes have a ring/ball softening between 80° C. and 140° C.
27 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin waxes have a melt viscosity, measured at 170° C., of a maximum of 20,000 mPa·s.
28 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin wax has a weight-average molecular weight 1%, of between 1,000 and 40,000 g/mol and a number-average molecular weight M n of between 500 and 25,000 g/mol, and an M w /M n of <2.5.
29 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the polyolefin wax has a weight-average molecular weight M w of between 1,000 and 40,000 g/mol and a number-average molecular weight M n of between 500 and 25,000 g/mol, and an M w /M n of <1.8.
30 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising a synergistic combination of expandable graphite and one or more further flameproofing agent in the combination of expandable graphite to flameproofing agent combination of from 1:1 to 2:1.
31 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , further comprising a synergistic combination of expandable graphite and one or more further flameproofing agent in the combination of expandable graphite to flameproofing agent of 1:1 to 3:2.
32 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising as a further flameproofing agent one or more from the group of organophosphorus-based flameproofing agents.
33 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising as a further flameproofing agent one or more from the group of inorganic flameproofing agents.
34 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , comprising an antistatically acting auxiliary substance selected from the group consisting of: conductive carbon black, metal powder, metal wires, metal threads and non-conductive antistatics, and quaternary ammonium compounds.
35 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the hot-melt adhesive composition has a ring/ball softening point of between 80 and 160° C.
36 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the hot-melt adhesive composition has a melt viscosity, measured at 170° C., of between 5,000 and 80,000 mPa·s.
37 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 1 , wherein the hot-melt adhesive composition has a melt viscosity, measured at 170° C., between 10,000 and 70,000 mPa·s.
38 . A hot-melt adhesive composition according to the invention as claimed in claim 1 , wherein this is applied without using a solvent as a finished mixture in the melt at between 120 to 170° C.
39 . A hot-melt adhesive composition according to the invention as claimed in claim 1 , wherein this is applied without using a solvent as a finished mixture in the melt at between 140-160° C.
40 . A hot-melt adhesive composition as claimed in as claimed in claim 1 , wherein after finishing of textile sheet-like structures, the textile sheet-like structures have a surface resistance and a volume resistance of less than 10 8 Ω.
41 . A hot-melt adhesive composition as claimed in as claimed in claim 1 , wherein after finishing of textile sheet-like structures, the textile sheet-like structures have a surface resistance and a volume resistance of less than 10 6 Ω.
42 . A hot-melt adhesive as claimed in claim 16 , wherein the application weight of the hot-melt adhesive is between 100-1,000 g/m 2 .
43 . A hot-melt adhesive as claimed in claim 16 , wherein the application weight of the hot-melt adhesive is between 300-400 g/m 2 .
44 . The hot-melt adhesive composition having a flame-retardant finish as claimed in claim 24 , wherein the recycled polyolefin wax in the pure form deviates from its original mechanical material properties by not more than 5%.