IP Library Granted Patent US 10,011,548
Granted Patent B2
US 10,011,548 · App. 14/422,433 · Granted Jul 3, 2018

Process for production of DME from crude methanol

Inventors: Per Juul Dahl (Vedbæk, DK); Janni Østergaard (Brønshøj, DK)
Assignee: Haldor Topsoe A/S
C07C41/42B01D3/143B01J19/24C07C41/09B01J2219/00006B01J2219/24
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Quick Facts
Patent No.
US 10,011,548
App. No.
14/422,433
Granted
Jul 3, 2018
Kind
B2
Abstract

The invention provides a process for the production of purified dimethylether (DME). Methanol is dehydrated to provide a first DME-containing product. The first DME-containing product is purified in a two-stage process. The invention also provides an apparatus arranged to carry out said process.

Claims (15)

1. A process for the production of dimethylether (DME), said process comprising:

a. dehydrating a methanol stream in the presence of a catalyst bed in a DME reactor system by passing the methanol stream over the catalyst to provide a first DME-containing product;

b. reducing the first DME-containing product temperature and directly introducing the reduced temperture product into an olefin stripper column, stripping the reduced temperature product in said stripper column into two streams:

i. an olefin stripper light fractions, and

ii. a second DME-containing product;

wherein sensible heat of the reduced temperature product provides energy for the olefin stripper column;

c. introducing the second DME-containing product into a DME column, in which it is separated into:

i. DME column overhead light fractions,

ii. purified DME and

iii. unreacted methanol and water bottoms fractions, and

d. recycling the unreacted methanol and water bottoms fraction of step c.iii. to said DME reactor.

2. The process according to claim 1 , wherein the olefin stripper light fractions is cooled and in a gas/liquid separator, separated in a gas fraction and a reflux liquid and the reflux liquid is used as reflux liquid in the olefin stripper.

3. The process according to claim 1 , wherein one or more of the light fractions are separated into DME-containing off-gases, said off-gases are combined, washed with methanol to extract DME and the DME-containing methanol recycled to the methanol stream inputted to step a.

4. The process according to claim 1 , wherein said methanol stream of step a. is obtained by passing a feed of crude methanol through a combined stabiliser/waste water column.

5. The process according to claim 1 , wherein heat from step a is used to heat the combined stabiliser/waste water column.

Assignments (2)
CHANGE OF NAME Recorded Oct 3, 2023
From: HALDOR TOPSØE A/S
To: TOPSOE A/S
Reel/Frame 065108/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 25, 2015
From: DAHL, PER JUUL; OSTERGAARD, JANNI
To: HALDOR TOPSOE A/S
Reel/Frame 035247/0656 →
Priority Claims (1)
WO PCT/EP2012/066253 · Aug 21, 2012 · international
Continuity (1)
Related Publication 20150239813A1 · Aug 27, 2015