Hard coating film
The present invention relates to a hard coating film, and, more particularly, to a hard coating film having hardness and excellent physical properties. According to the present invention, the hard coating film has high physical properties including hardness, scratch resistance, transparency, durability, light resistance, and light transmittance. Thus, the hard coating film can find useful applications in various fields thanks to its excellent physical properties.
1. A hard coating film, comprising:
a supporting substrate;
a first hard coating layer, formed on one side of the supporting substrate and having an elongation strain of 4% to 12% in a stress-strain curve as measured by ASTM D882; and
a second hard coating layer, formed on the other side of the supporting substrate,
wherein the first hard coating layer has a first elastic modulus, and the second hard coating layer has a second elastic modulus, and the second elastic modulus is greater by 500 MPa to about 3000 MPa than the first elastic modulus.
2. The hard coating film of claim 1 , wherein the first elastic modulus is 1500 MPa or less, and the second elastic modulus is 2000 MPa or more.
3. The hard coating film of claim 1 , wherein the first and second hard coating layers independently comprise a photocurable crosslinking copolymer of a tri- to hexa-functional acrylate monomer, the photocurable crosslinking copolymer of the first hard coating layer being identical to or different from that of the second hard coating layer.
4. The hard coating film of claim 3 , wherein the first and second hard coating layers independently comprise a photocurable crosslinking copolymer of a mono- to bi-functional acrylate monomer in addition to the tri- to hexa-functional acrylate monomer, the photocurable crosslinking copolymer of the first hard coating layer being identical to or different from that of the second hard coating layer.
5. The hard coating film of claim 3 , wherein the first and second hard coating layers independently comprise a photocurable crosslinking copolymer of a photocurable elastic polymer in addition to the tri- to hexa-functional acrylate monomer, the photocurable crosslinking copolymer of the first hard coating layer being identical to or different from that of the second hard coating layer.
6. The hard coating film of claim 5 , wherein the photocurable elastic polymer has an elongation of 15 to 200%, as measured by ASTM D638.
7. The hard coating film of claim 5 , wherein the photocurable elastic polymer comprises at least one selected from the group consisting of polycaprolactone, a urethane acrylate polymer and polyrotaxane.
8. The hard coating film of claim 5 , wherein the polyrotaxane comprises a cyclic moiety (macrocycle) in which lactone compounds with a (meth)acrylate moiety conjugated to the end thereof are bonded each other; a thread moiety held within the macrocycle; and stoppers provided at both ends of the thread moiety so as to prevent dissociation of the macrocycle.
9. The hard coating film of claim 3 , wherein the second hard coating layer further comprises inorganic particles dispersed in the photocurable crosslinking polymer.
10. The hard coating film of claim 1 , wherein thicknesses of the first and second hard coating layers are identical or different, and independently range from 50 to 300 μm.
11. The hard coating film of claim 3 , wherein the tri- to hexa-functional acrylate monomer comprises at least one selected from the group consisting of trimethylolpropane triacrylate (TMPTA), trimethylolpropane ethoxy triacrylate (TMPEOTA), glycerin-propoxylated triacrylate (GPTA), pentaerythritol tetraacrylate (PETA) and dipentaerythritol hexaacrylate (DPHA).
12. The hard coating film of claim 1 , wherein the supporting substrate includes at least one selected from consisting of polyethyleneterephthalate (PET), ethylene vinyl acetate (EVA), a cyclic olefin polymer (COP), a cyclic olefin copolymer (COC), polyacrylate (PAC), polycarbonate (PC), polyethylene (PE), polymethylmethacrylate (PMMA), polyetheretherketone (PEEK), polyethylenenaphthalate (PEN), polyetherimide (PEI), polyimide (PI), triacetylcellulose (TAC), methyl methacrylate (MMA) and a fluorine resin.
13. The hard coating film of claim 1 , wherein the hard coating film does not crack when a 22 g steel ball is freely dropped ten times thereon from a height of 50 cm.
14. The hard coating film of claim 1 , exhibiting a pencil hardness of 7H or more at a load of 1 kg.
15. The hard coating film of claim 1 , wherein the hard coating film allows two or less scratches to appear thereon after it is doubly rubbed 400 times with a steel wool #0000 under a load of 500 g.
16. The hard coating film of claim 1 , having a light transmittance of 91% or more, a haze of 0.4 or less, and a color b* value of 1.0 or less.
17. The hard coating film of claim 1 , wherein the hard coating film has a color b* value after exposure to UV-B for 72 hr which differs from a pre-exposed, color b* value by 0.5 or less.
18. The hard coating film of claim 1 , wherein when the hard coating film is disposed on a plane after exposure to a temperature of 50° C. or higher at a humidity of 80% or higher for 70 hr or longer, each edge or side of the hard coating film is spaced apart from the plane by 1.0 mm or less, maximally.
19. The hard coating film of claim 1 , further comprising on the first hard coating layer or the second hard coating layer at least one layer selected from the group consisting of a plastic resin film, an adhesive film, a releasable film, an electrically conductive film, an electrically conductive layer, a coating layer, a curable resin layer, a non-conductive film, a metal mesh layer and a patterned metal layer.