Hard coating composition
Disclosed herein is a hard coating composition used in forming a hard coating film exhibiting high hardness and excellent properties. The hard coating composition can be used to prepare a hard coating film exhibiting high impact resistance, high scratch resistance and high transparency and having excellent processability.
1. A hard coating composition, comprising:
a tri- to hexa-functional acrylate monomer;
a photocurable elastic polymer having an elongation of 15 to 200%, as measured according to ASTM D638;
a photoinitiator; and
an organic solvent,
wherein the tri- to hexa-functional acrylate monomer includes at least one selected from the group consisting of trimethylolpropane triacrylate (TMPTA), pentaerythritol tetraacrylate (PETA), and dipentaerythritol hexaacrylate (DPHA),
wherein the photocurable elastic polymer includes at least one selected from the group consisting of a polycaprolactone and a polyrotaxane,
wherein the hard coating composition comprises 20 to 79.5 weight parts of the tri- to hexa-functional acrylate monomer, 20 to 79.5 weight parts of the photocurable elastic polymer and 0.5 to 10 weight parts of the photoinitiator, based on 100 weight parts of a solid content of the tri- to hexa-functional acrylate monomer, the photocurable elastic polymer and the photoinitiator, and
wherein a weight ratio of the solid content to the organic solvent is 70:30 to 99:1.
2. The hard coating composition of claim 1 , wherein a weight ratio of the photocurable elastic polymer to the tri- to hexa-functional acrylate monomer is 20:80 to 80:20.
3. The hard coating composition of claim 1 , wherein the photocurable elastic polymer includes polyrotaxane, and the polyrotaxane includes a macrocycle in which lactone compounds with a (meth)acrylate moiety conjugated to the end thereof are bonded each other; a thread moiety held within the macrocycle; and stoppers provided at both ends of the thread moiety so as to prevent dissociation of the macrocycle.
4. The hard coating composition of claim 1 , further comprising an additive.
5. The hard coating composition of claim 4 , wherein the additive includes at least one selected from the group consisting of a mono- to di-functional fluorine-based acrylate, a fluorine-based surfactant and a silicon-based surfactant, or includes a yellowing inhibitor including a benzophenone compound or a benzotriazole compound.
6. The hard coating composition of claim 1 , wherein the hard coating composition has a viscosity of 100 to 1,200 cps at a temperature of 25° C.