Anti-foaming agent and pulp production method
View Patent ↗An anti-foaming agent containing (A) an organopolysiloxane and a finely powdered inorganic filler, (B) a polyoxyalkylene group-containing branched chain organopolysiloxane, and (C) an anionic surfactant. This anti-foaming agent exhibits stable anti-foaming performance even at high temperatures that reach, for example, 80QC or under strongly alkaline conditions and produces no aggregates.
1. A pulp production method comprising adding an anti-foaming agent to water comprising pulp for pulp production, the anti-foaming agent comprising:
(A) an organopolysiloxane and a finely powdered inorganic filler;
(B) a polyoxyalkylene group-containing branched chain organopolysiloxane; and
(C) an anionic surfactant.
2. The production method according to claim 1 , wherein the anti-foaming agent is added at a total concentration of from 1 to 500 g/ton relative to the weight of absolutely dry pulp.
3. The production method according to claim 1 , wherein the anti-foaming agent is added to the water comprising pulp for pulp production in a pulp washing step and/or a pulp bleaching step.
4. The production method according to claim 1 , wherein the finely powdered inorganic filler is selected from microparticulate silica, titanium dioxide, aluminum oxide, fumed TiO 2 , Al 2 O 3 , zinc oxide, magnesium oxide, and mixtures thereof.
5. The production method according to claim 1 , wherein a blending quantity of the (A) organopolysiloxane and finely powdered inorganic filler is from 5 to 90 wt. % relative to the total weight of the anti-foaming agent.
6. The production method according to claim 1 , wherein a blending quantity of the (B) polyoxyalkylene group-containing branched chain organopolysiloxane is from 1 to 40 wt. % relative to the total weight of the anti-foaming agent.
7. The production method according to claim 1 , wherein the (C) anionic surfactant is a sulfonate type anionic surfactant selected from α-sulfo fatty acid alkyl ester salts, α-olefin sulfonate salts, alkane sulfonic acid salts, straight chain alkylbenzene sulfonate salts, and mixtures thereof.
8. The production method according to claim 7 , wherein the sulfonate salts are selected from sodium salts, potassium salts, lithium salts, ammonium salts, and mixtures thereof.
9. The production method according to claim 1 , wherein a blending quantity of the (C) anionic surfactant is from 1 to 30 wt. % relative to the total weight of the anti-foaming agent.
10. The production method according to claim 1 , wherein the anti-foaming agent further comprises (D) a non-ionic surfactant other than component (B).
11. The production method according to claim 10 , wherein a blending quantity of the (D) non-ionic surfactant excluding component (B) is from 0.01 to 25 wt. % relative to the total weight of the anti-foaming agent.
12. The production method according to claim 1 , wherein the anti-foaming agent further comprises (E) a water-soluble polymer.
13. The production method according to claim 1 , wherein the anti-foaming agent further comprises water and is in the form of an emulsion.
14. The production method according to claim 1 , wherein the anti-foaming agent exhibits stable anti-foaming performance at a temperature from 60 to 80° C. or in excess of 80° C.
15. The production method according to claim 1 , wherein the anti-foaming agent exhibits stable anti-foaming performance at a pH of 9.0 or higher.