IP Library Granted Patent US 10,087,304
Granted Patent B2
US 10,087,304 · App. 14/425,132 · Granted Oct 2, 2018

Composition for protecting beta-carotene

Inventors: Ling Zhu (Shanghai, CN); Gang Li (Shanghai, CN); Wenyu Shang (Shanghai, CN)
Assignee: PolyOne—Shanghai, China
C08K5/005B65B43/00B65B55/00C08K5/0041C08K2201/014Y10T428/1352
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Quick Facts
Patent No.
US 10,087,304
App. No.
14/425,132
Granted
Oct 2, 2018
Kind
B2
Abstract

A composition to protect beta-carotene from visible light photo-oxidation is disclosed. The composition uses a combination of a quinophthalone dye, a pyrazolone dye, and a methine dye to protect the beta-carotene from visible light in the range of 400-500 nm.

Claims (28)

1. A composition for protection of beta-carotene within a plastic vessel, comprising:

(a) polyester;

(b) protective colorants consisting essentially of a quinophthalone dye, a pyrazolone dye, and a methine dye; and

(c) an ultra-violet light absorbing chemical;

wherein beta-carotene absorbs visible light in the range of 400 nm-500 nm and wherein the combination of the quinophthalone dye, the pyrazolone dye, and the methine dye absorb visible light in the range of 390 nm-480 nm; and

wherein the weight percent of ingredients of the composition are

polyester resin=79.34-99.91;

quinophthalone dye=0.02-0.06;

pyrazolone dye=0.01-0.05;

methine dye=0.01-0.05;

ultra-violet light absorbing chemical=0.05-0.5; and

optional additives=0-20.

2. The composition of claim 1 , wherein the polyester is selected from the group consisting of terephthalates; terephthalate glycols; lactides; (hydroxy)alkanoates; copolyesters of terephthalic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 1,4-cyclohexanedimethanol; and combinations thereof.

3. The composition of claim 2 , wherein the polyester is selected from the group consisting of polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polylactic acid (PLA), polyhydroxybutyrate (PHB), polyhydroxybutyrate-co-valerate (PHBV), and combinations thereof.

4. The composition of claim 1 , wherein the ultra-violet light absorbing chemical is 2-(2-Hydroxy-3,5-di-a-cumylphenyl)-2H-benzotriazole (CAS No. 70321-86-7).

5. The composition of claim 4 , wherein the composition further comprises adhesion promoters; biocides; anti-fogging agents; anti-static agents; foaming agents; dispersants; fillers; flame retardants; smoke suppresants; impact modifiers; initiators; lubricants; micas; colorants; plasticizers; processing aids; release agents; slip agents; anti-blocking agents; stabilizers; stearates; viscosity regulators;

waxes; or combinations of them.

6. A plastic vessel made from the composition of claim 1 .

7. The plastic vessel of claim 6 , wherein the plastic vessel is selected from the group consisting of flexible packaging, rigid packaging, bottles, containers, and other vessels for transport and storage of food.

8. The vessel of claim 6 , wherein the polyester is selected from the group consisting of terephthalates; terephthalate glycols; lactides; (hydroxy)alkanoates; copolyesters of terephthalic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and 1,4-cyclohexanedimethanol; and combinations thereof.

9. The vessel of claim 6 , wherein the polyester is selected from the group consisting of polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polylactic acid (PLA), polyhydroxybutyrate (PHB), polyhydroxybutyrate-co-valerate (PHBV), and combinations thereof.

10. The vessel of claim 6 , wherein the ultra-violet light absorbing chemical is 2-(2-Hydroxy-3,5-di-a-cumylphenyl)-2H-benzotriazole (CAS No. 70321-86-7).

11. The vessel of claim 6 , wherein the composition further comprises adhesion promoters; biocides; anti-fogging agents; anti-static agents; foaming agents; dispersants; fillers; flame retardants; smoke suppressants; impact modifiers; initiators; lubricants; micas; colorants; plasticizers; processing aids; release agents; slip agents; anti-blocking agents; stabilizers; stearates; viscosity regulators; waxes; or combinations of them.

12. A method of using dyes to protect beta-carotene within a plastic vessel, comprising the steps of:

(a)

shaping the composition of claim 1 into the plastic vessel; and

(b) placing a liquid containing beta-carotene into the plastic vessel;

wherein beta-carotene absorbs visible light in the range of 400 nm-500 nm and wherein the combination of the quinophthalone dye, the pyrazolone dye, and the methine dye absorb visible light in the range of 390 nm-480 nm.

Assignments (5)
RELEASE OF SECURITY INTERESTS IN PATENTS RECORDED AT REEL 067697, FRAME 0369. Recorded Jun 24, 2025
From: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
To: AVIENT CORPORATION; COLORMATRIX HOLDINGS, INC.
Reel/Frame 071708/0376 →
PATENT SECURITY AGREEMENT (TERM) Recorded Jun 12, 2024
From: AVIENT CORPORATION; COLORMATRIX HOLDINGS, INC.
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 067699/0676 →
SECURITY INTEREST Recorded Jun 11, 2024
From: AVIENT CORPORATION; COLORMATRIX HOLDINGS, INC.
To: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 067697/0369 →
CHANGE OF NAME Recorded Jul 13, 2020
From: POLYONE CORPORATION
To: AVIENT CORPORATION
Reel/Frame 053197/0141 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 3, 2015
From: ZHU, LING; LI, GANG; SHANG, WENYU
To: POLYONE - SHANGHAI, CHINA
Reel/Frame 035074/0718 →
Priority Claims (1)
CN 2012 1 0315827 · Aug 30, 2012 · national
Continuity (1)
Related Publication 20150203655A1 · Jul 23, 2015
Cited By (1)
US 12,291,635