Low temperature impact properties in PC-siloxane copolymer blend with black and white color capacity
View Patent ↗The present disclosure describes polycarbonate-siloxane blends with a constant percentage of siloxane in the formulations. The polycarbonate-siloxane blends achieve improved impact properties, as well as the ability to achieve deep black and bright white colors.
1. A polycarbonate blend composition comprising:
a. a polycarbonate polymer;
b. a first polysiloxane-polycarbonate copolymer comprising:
i. polydiorganosiloxane blocks comprising repeating structural units of formula:
wherein the polydiorganosiloxane block length (E) is from 30 to 60; and
ii. polycarbonate blocks comprising polycarbonate units of formula:
wherein at least 60 percent of the total number of R 1 groups comprise aromatic moieties and the balance thereof comprise aliphatic, alicyclic, or aromatic moieties;
wherein the first polysiloxane-polycarbonate copolymer comprises a diorganosiloxane content of from 4 to 8 wt % diorganosiloxane based on the total weight of the first polysiloxane-polycarbonate copolymer;
c. a second polysiloxane-polycarbonate copolymer comprising:
i. polydiorganosiloxane blocks comprising repeating structural units of formula:
wherein the polydiorganosiloxane block length (E) is from 30 to 100; and
ii. polycarbonate blocks comprising polycarbonate units of formula:
wherein at least 60 percent of the total number of R 1 groups comprise aromatic moieties and the balance thereof comprise aliphatic, alicyclic, or aromatic moieties;
wherein the second polysiloxane-polycarbonate copolymer comprises a diorganosiloxane content of from 15 to 30 wt % diorganosiloxane based on the total weight of the second polysiloxane-polycarbonate copolymer; and
d. a colorant composition;
wherein the blend composition has an average melt flow rate (MFR) of 7 or greater measured at 300° C./1.2 kg; and
wherein a molded part having a thickness of 3.2 mm formed from the blend composition has a black color characterized by an average L* value of 27 or less as measured by the CIE Lab method, 10 degree observer, D65 illuminant, specular component included, measured in reflectance mode; and
wherein a molded part having a thickness of 3.2 mm formed from the blend composition has an average notched Izod impact energy at −30° C. of 650 J/m or greater according to ASTM D256-2010 and a % ductility at −30° C. of 100%; and
wherein R is the same or different, and is a C 1-13 monovalent organic group; R 2 is independently a divalent C 1 -C 30 organic group; M is independently a halogen, cyano, nitro, C 1 -C 8 alkylthio, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, C 2 -C 8 alkenyl, C 2 -C 8 alkenyloxy group, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkoxy, C 6 -C 10 aryl, C 6 -C 10 aryloxy, C 7 -C 12 aralkyl, C 7 -C 12 aralkoxy, C 7 -C 12 alkylaryl, or C 7 -C 12 alkylaryloxy, wherein each n is independently 0, 1, 2, 3, or 4.
2. The composition of claim 1 , wherein the colorant composition comprises less than 1.5 wt % of an inorganic colorant based on the total weight of the colorant composition.
3. The composition of claim 1 , wherein the second polysiloxane-polycarbonate copolymer is present in the blend composition in an amount of about 2.5 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
4. The composition of claim 1 , wherein the polycarbonate polymer is present in an amount in the range of from 15 wt % to 30 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
5. The composition of claim 1 , wherein the polycarbonate polymer is present in an amount in the range of from 22 wt % to 29 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
6. The composition of claim 1 , wherein the total combined weight percent of the first and second polysiloxane-polycarbonate copolymers present in the blend composition is in the range of from 70 wt % to 80 wt % relative to the total combined weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer; and/or
wherein the first polysiloxane-polycarbonate copolymer is present in an amount in the range of from 65 wt % to 75 wt % relative to the total combined weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
7. The composition of claim 1 , wherein the second polysiloxane-polycarbonate copolymer is present in an amount in the range of from greater than 0 wt % to 5 wt % relative to the total combined weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
8. The composition of claim 1 , wherein the total weight percentage of siloxane ranges from 4.5 wt % to 5.5 wt % based on the total combined weight of the first polysiloxane-polycarbonate, second polysiloxane-polycarbonate, and the polycarbonate.
9. The composition of claim 1 , wherein the second polysiloxane-polycarbonate copolymer has a weight-averaged molecular weight, Mw, in the range of from 25,000 to 35,000, wherein the polycarbonate polymer is a Bisphenol-A-polycarbonate, wherein the siloxane units of the first and second polysiloxane polycarbonate copolymers are dimethylsiloxane units, wherein the polydiorganosiloxane has moieties derived from eugenol, 4-allylphenol or 2-allylphenol, wherein the PDI of the first polysiloxane-polycarbonate and the second polysiloxane-polycarbonate ranges from 2 to 3.
10. The composition of claim 1 , wherein the polycarbonate polymer comprises a blend of at least two polycarbonate polymers, wherein the polycarbonate polymer comprises a first polycarbonate polymer and a second polycarbonate polymer, wherein the first polycarbonate polymer is a low flow polycarbonate, and wherein the second polycarbonate polymer is a high flow polycarbonate.
11. The composition of claim 10 , wherein the first polycarbonate polymer is present in an amount in the range of from 11 wt % to 29 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer and wherein the second polycarbonate polymer is present in an amount in the range of from greater than 0 wt % to 8 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
12. The composition of claim 10 , wherein the first polycarbonate polymer is present in an amount in the range of from 14 wt % to 29 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer and wherein the second polycarbonate polymer is present in an amount in the range of from greater than 0 wt % to 8 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
13. An article of manufacture formed from the blend composition of claim 1 .
14. The article of manufacture of claim 13 , wherein the article is a component for an electronic device, a sports goggle or an eyeglass frame, and wherein the thickness of the article is less than 1.5 mm in at least a portion of the article.
15. A polycarbonate blend composition comprising:
a. a first polysiloxane-polycarbonate copolymer comprising:
i. polydiorganosiloxane blocks comprising repeating structural units of formula:
wherein the polydiorganosiloxane block length (E) is from 30 to 60; and
ii. polycarbonate blocks comprising polycarbonate units of formula:
wherein at least 60 percent of the total number of R 1 groups comprise aromatic moieties and the balance thereof comprise aliphatic, alicyclic, or aromatic moieties;
wherein the first polysiloxane-polycarbonate copolymer comprises a diorganosiloxane content of from 4 to 8 wt % diorganosiloxane based on the total weight of the first polysiloxane-polycarbonate copolymer;
b. a second polysiloxane-polycarbonate copolymer comprising:
i. polydiorganosiloxane blocks comprising repeating structural units of formula:
wherein the polydiorganosiloxane block length (E) is from 30 to 100; and
ii. polycarbonate blocks comprising polycarbonate units of formula:
wherein at least 60 percent of the total number of R 1 groups comprise aromatic moieties and the balance thereof comprise aliphatic, alicyclic, or aromatic moieties;
wherein the second polysiloxane-polycarbonate copolymer comprises a diorganosiloxane content of from 15 to 30 wt % diorganosiloxane based on the total weight of the second polysiloxane-polycarbonate copolymer; and
c. a colorant composition;
wherein the blend composition has an average melt flow rate (MFR) of 7 or greater measured at 300° C./1.2 kg; and
wherein a molded part having a thickness of 3.2 mm formed from the blend composition has a black color characterized by an average L* value of 28 or less as measured by the CIE Lab method, 10 degree observer, D65 illuminant, specular component included, measured in reflectance mode; and
wherein a molded part having a thickness of 3.2 mm formed from the blend composition has an average notched Izod impact energy at −30° C. of 600 J/m or greater according to ASTM D256-2010 and a % ductility at −30° C. of 80%; and
wherein R is the same or different, and is a C 1-13 monovalent organic group; R 2 is independently a divalent C 1 -C 30 organic group; M is independently a halogen, cyano, nitro, C 1 -C 8 alkylthio, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, C 2 -C 8 alkenyl, C 2 -C 8 alkenyloxy group, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkoxy, C 6 -C 10 aryl, C 6 -C 10 aryloxy, C 7 -C 12 aralkyl, C 7 -C 12 aralkoxy, C 7 -C 12 alkylaryl, or C 7 -C 12 alkylaryloxy, wherein each n is independently 0, 1, 2, 3, or 4.
16. The composition of claim 15 , wherein the first polysiloxane-polycarbonate copolymer is present in an amount in the range of from 50 wt % to 95 wt % relative to the total combined weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer, and wherein the second polysiloxane-polycarbonate copolymer is present in an amount in the range of from greater than 0 wt % to 5 wt % relative to the total combined weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
17. The composition of claim 15 , wherein the total weight percentage of siloxane ranges from 4.0 wt % to 7 wt % based on the total combined weight of the first polysiloxane-polycarbonate, second polysiloxane-polycarbonate, and the polycarbonate.
18. The composition of claim 15 , wherein the second polysiloxane-polycarbonate copolymer is present in the blend composition in an amount less than 5 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.
19. A polycarbonate blend composition comprising:
a. a polycarbonate polymer;
b. a first polysiloxane-polycarbonate copolymer comprising:
i. polydiorganosiloxane blocks comprising repeating structural units of formula:
wherein the polydiorganosiloxane block length (E) is from 30 to 60; and
ii. polycarbonate blocks comprising polycarbonate units of formula:
wherein at least 60 percent of the total number of R 1 groups comprise aromatic moieties and the balance thereof comprise aliphatic, alicyclic, or aromatic moieties;
wherein the first polysiloxane-polycarbonate copolymer comprises a diorganosiloxane content of from 4 to 8 wt % diorganosiloxane based on the total weight of the first polysiloxane-polycarbonate copolymer;
c. a second polysiloxane-polycarbonate copolymer comprising:
i. polydiorganosiloxane blocks comprising repeating structural units of formula:
wherein the polydiorganosiloxane block length (E) is from 30 to 100; and
ii. polycarbonate blocks comprising polycarbonate units of formula:
wherein at least 60 percent of the total number of R 1 groups comprise aromatic moieties and the balance thereof comprise aliphatic, alicyclic, or aromatic moieties;
wherein the second polysiloxane-polycarbonate copolymer comprises a diorganosiloxane content of from 15 to 30 wt % diorganosiloxane based on the total weight of the second polysiloxane-polycarbonate copolymer; and
d. a colorant composition;
wherein the blend composition has an average melt flow rate (MFR) of 7 or greater measured at 300° C./1.2 kg; and
wherein a molded part having a thickness of 3.2 mm formed from the blend composition has a black color characterized by an average L* value of 28 or less as measured by the CIE Lab method, 10 degree observer, D65 illuminant, specular component included, measured in reflectance mode; and
wherein a molded part having a thickness of 3.2 mm formed from the blend composition has an average notched Izod impact energy at −30° C. of 600 J/m or greater according to ASTM D256-2010 and a % ductility at −30° C. of 80%; and
wherein R is the same or different, and is a C 1-13 monovalent organic group; R 2 is independently a divalent C 1 -C 30 organic group; M is independently a halogen, cyano, nitro, C 1 -C 8 alkylthio, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, C 2 -C 8 alkenyl, C 2 -C 8 alkenyloxy group, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkoxy, C 6 -C 10 aryl, C 6 -C 10 aryloxy, C 7 -C 12 aralkyl, C 7 -C 12 aralkoxy, C 7 -C 12 alkylaryl, or C 7 -C 12 alkylaryloxy, wherein each n is independently 0, 1, 2, 3, or 4.
20. The composition of claim 19 , wherein the polycarbonate polymer comprises a first polycarbonate polymer and a second polycarbonate polymer and wherein the first polycarbonate polymer is present in an amount in the range of from 10 wt % to 30 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer and wherein the second polycarbonate polymer is present in an amount in the range of from greater than 0 wt % to 15 wt % relative to the total weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer; and
wherein the total combined weight percent of the first and second polysiloxane-polycarbonate copolymers present in the blend composition is in the range of from 54 wt % to 100 wt % relative to the total combined weight percent of the polycarbonate polymer, first polysiloxane-polycarbonate copolymer, and second polysiloxane-polycarbonate copolymer.