IP Library › Granted Patent US 10,249,827

Granted Patent B2

US 10,249,827 · App. 14/427,134 · Granted Apr 2, 2019

Azadibenzofurans for electronic applications

Inventors: Annemarie Wolleb (Fehren, CH); Thomas Schaefer (Liestal, CH); Heinz Wolleb (Fehren, CH); Ute Heinemeyer (Neustadt, DE); Nicolle Langer (Lampertheim, DE); Christian Lennartz (Schifferstadt, DE); Gerhard Wagenblast (Wachenheim, DE); Soichi Watanabe (Seoul, KR); Flavio Luiz Benedito (Ludwigshafen, DE); Heinz Hottinger (Ettingen, CH); Oliver Dosenbach (Bad Bellingen, DE)

Assignee: UDC Ireland Limited

H01L51/0072 C07D209/86 C07D405/04 C07D405/14 C07D487/04 C07D491/048 C07D491/147 C07D519/00 C07F7/0814 C09B57/00 C09B57/008 C09K11/025 C09K11/06 H01L51/0071 H01L51/0094 C09K2211/1007 C09K2211/1011 C09K2211/1029 C09K2211/1033 C09K2211/1048 C09K2211/1059 C09K2211/1088 C09K2211/185 H01L51/0054 H01L51/0058 H01L51/0073 H01L51/0085 H01L51/5012 H01L51/5016 H01L51/5056 H01L51/5088 H01L51/5092 H01L51/5206 H01L2251/308 Y02E10/549 Y02P70/521

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Quick Facts

Patent No.: US 10,249,827
App. No.: 14/427,134
Granted: Apr 2, 2019
Kind: B2

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Abstract

The present invention relates to compounds of formula (I), which are characterized in that they substituted by benzimidazo[1,2-a]benzimidazo-5-yl and/or benzimidazo[1,2-a]benzimidazo-2,5-ylene groups and in that at least one of the substituents B 1 , B 2 , B 3 , B 4 , B 5 , B 6 , B 7 and B 8 represents N; a process for their production and their use in electronic devices, especially electroluminescent devices. When used as host material for phosphorescent emitters in electroluminescent devices, the compounds of formula I may provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.

Claims (1096)

1. A compound of the formula

wherein

B 1 is N, or CR 81 ,

B 2 is N, or CR 82 ,

B 3 is N, or CR 83 ,

B 4 is N, or CR 84 ,

B 5 is N, or CR 85 ,

B 6 is N, or CR 86 ,

B 7 is N, or CR 87 ,

B 8 is N, or CR 88 ,

R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 are independently of each other H, a C 1 -C 25 alkyl group, which can optionally be substituted by E and or interrupted by D; a C 6 -C 24 alkyl group, which can optionally be substituted by G, a C 2 -C 30 heteroaryl group, which can optionally be substituted by G; or a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ,

o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1,

A 1 , A 2 , A 3 and A 4 are independently of each other a C 6 -C 24 arylene group, which can optionally be substituted by G, or a C 2 -C 30 heteroarylene group, which can optionally be substituted by G;

R 16 is —NR 10 R 11 , or —Si(R 12 )(R 13 ) (R 14 ), a C 6 -C 24 aryl group, which can optionally be substituted by G; or a C 2 -C 30 heteroarylene group, which can optionally be substituted by G;

R 10 and R 11 are independently of each other a C 6 -C 24 aryl group, which can optionally be substituted by G; or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G;

R 12 , R 13 and R 14 are independently of each other a C 1 -C 25 alkyl group, which can optionally be substituted by E and or interrupted by D; C 6 -C 24 aryl group, which can optionally be substituted by G; or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G;

D is —CO—, —COO—, —S—, —SO—, —SO 2 —, —O—, —NR 65 —, —SiR 70 R 71 —, —POR 72 —, —CR 63 ═CR 64 —, or —C≡C—,

E is —OR 69 , —SR 69 , —NR 65 R 66 , —COR 68 , —COOR 67 , —CONR 65 R 66 , —CN, or F,

G is E, or a C 1 -C 18 alkyl group, a C 6 -C 24 aryl group, a C 6 -C 24 aryl group, which is substituted by F, C 1 -C 18 alkyl, or C 1 -C 18 alkyl which is interrupted by O; a C 2 -C 30 hereroaryl group, or a C 2 -C 30 heteroaryl group, which is substituted by F, C 1 -C 18 alkyl, or C 1 -C 18 alkyl which is interrupted by —O—;

R 63 and R 64 are independently of each other H, C 6 -C 18 aryl; C 6 -C 18 aryl which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; C 1 -C 18 alkyl; or C 1 -C 18 alkyl which is interrupted by —O—;

R 65 and R 66 are independently of each other a C 6 -C 18 aryl group; a C 6 -C 18 aryl which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—; or

R 65 and R 66 together fonn a five or six membered ring,

R 67 is a C 6 -C 18 aryl group; a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—,

R 68 is H; n a C 6 -C 18 aryl group; a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy; a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—,

R 69 is a C 6 -C 18 aryl; a C 6 -C 18 aryl, which is substituted by C 1 -C 18 alkyl, or C 1 -C 18 alkoxy, a C 1 -C 18 alkyl group; or a C 1 -C 18 alkyl group, which is interrupted by —O—,

R 70 and R 71 are independently of each other a C 1 -C 18 alkyl group, a C 6 -C 18 aryl group, or a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, and

R 72 is a C 1 -C 18 alkyl group, a C 6 -C 18 aryl group, or a C 6 -C 18 aryl group, which is substituted by C 1 -C 18 alkyl, with the proviso that

at least one of the substituents B 1 , B 2 , B 3 , B 4 , B 5 , B 6 , B 7 and B 8 represents N;

not more than two of the groups B 1 , B 2 , B 3 and B 4 represent N; and

not more than two of the groups B 5 , B 6 , B 7 and B 8 represent N; and

with the further proviso that at least one of the substituents R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 represent a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 , wherein R 16 represents a benzimidazo[1,2-a]benzimidazo-5-yl group, which can optionally be substituted by G; and/or at least one of the groups A 1 , A 2 , A 3 and A 4 represents a benzimidazo[1,2-a]benzimidazo-2,5-ylene group, which can optionally be substituted by G.

2. The compound according to claim 1 , which is a compound of formula

wherein R 81 , R 82 , R 83 , R 85 , R 86 and R 87 are as defined in claim 1 .

3. The compound according to claim 2 , wherein

in the compounds of formula (Ia)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ib)

R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ic)

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Id)

R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

the compounds of formula (Ie)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (If)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ig)

R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ih)

R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

the compounds of formula (Ii)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ij)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ik)

R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Il)

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Im)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

the compounds of formula (In)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; wherein

in the compounds of formula (Io)

R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 86 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; or

R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ ; and

R 86 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1;

A 1 , A 2 , A 3 and A 4 are independently of each other a group of the formula

R 16 is a group of the formula

or R 16 has the meaning of R 16′ , if at least one of the groups A 1 , A 2 , A 3 and A 4 represent a group of formula

R 16′ is H, or a group of the formula —Si(R 12 )(R 13 )(R 14 ),

wherein

R 12 , R 13 and R 14 are independently of each other a phenyl group, which can optionally be substituted by one, or more alkyl groups;

R 21 and R 21′ are independently of each other H, a phenyl group, or a C 1 -C 18 alkyl group;

R 22 and R 23 are independently of each other H, or a group of the formula

X is O, S, or NR 24 ,

R 24 is a C 6 -C 24 aryl group, or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G; and

R 89 is H, a group of formula

4. The compound according to claim 2 , wherein

o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1,

A 1 , A 2 , A 3 and A 4 are independently of each other a group of the formula

R 16 is a is group of the formula

or R 16 has the meaning of R 16′ , if at least one of the groups A 1 , A 2 , A 3 and A 4 represent a group of formula

R 16′ is H, or a group of the formula

and R 89 is H, a group of formula

wherein X is O, S, or NR 24 , wherein

R 24 is

5. The compound according to claim 2 , wherein the group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 is a group of formula

6. The compound according to claim 5 , wherein the group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16′ is H, or a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf), or (XIIIg); or a group of formula

7. The compound according to claim 6 , which is

a compound of formula (Ia), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ia), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ib), wherein R 82 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo),(XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ib), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 82 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ic), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ic), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg); and

R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Id), wherein R 81 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg); or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Id), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg); and

R 81 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ie), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ie), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (If), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (If), wherein R 85 is a group of formula (XIIa), (XIII)), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (Ii), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ii), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ij), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIII), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ij), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId);

a compound of formula (Il), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (Il), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (In), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (In), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIII), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIh), (XIIi), (XIIj), (XIIk), ((XIIl)), (XIIm), (XIIn), (XIIo), (XIIp), (XIIq), (XIIr), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVh), (XIVo), (XIVp), (XIVq), (XIVr), (XIVs), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVy), (XIVz), (XVa), (XVb), (XVc), (XVd), (XVe), (XVf), (XVg), (XVh), (XVi), (XVj), (XVk), (XVl), (XVm), (XVn), (XVo), (XVp), (XVq), (XVr), (XVs), (XVt), (XVu), (XVv), (XVw), (XVx), (XVy), (XVz), (XVIa), (XVIb), (XVIc) or (XVId).

8. The compound according to claim 6 , which is

a compound of formula (Ia), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ia), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId);

a compound of formula (Ib), wherein R 82 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 87 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ib), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 82 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId);

a compound of formula (Ic), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (Ic), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), or (XIIIg), and

R 85 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Id), wherein R 81 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (Id), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 81 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId);

a compound of formula (Ie), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (Ie), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (If), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (If), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId); or

a compound of formula (Ij), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (Ij), wherein R 85 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIj), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (In), wherein R 83 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

a compound of formula (In), wherein R 87 is a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv), (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), and

R 83 is H, a group of formula (XIIa), (XIIb), (XIIc), (XIId), (XIIe), (XIIf), (XIIg), (XIIk), (XIIn), (XIIo), (XIIq), (XIIs), (XIIt), (XIIu), (XIIv) (XIIw), (XIIx), (XIIy), (XIIz), (XIIIa), (XIIIb), (XIIIc), (XIIId), (XIIIe), (XIIIf) or (XIIIg), or a group of formula (XIVb), (XIVc), (XIVd), (XIVe), (XIVf), (XIVg), (XIVo), (XIVp), (XIVq), (XIVr), (XIVt), (XIVu), (XIVv), (XIVw), (XIVx), (XIVz), (XVa), (XVb), (XVc), (XVk), (XVl), (XVo), (XVp), (XVs), (XVw), (XVx), (XVy), (XVIa), (XVIb), (XVIc) or (XVId).

9. The compound according to claim 1 :

Compound

R 83

R 87

A-1

A-2

A-3

A-4

A-5

A-6

A-7

A-8

A-9

A-10

A-11

A-12

A-13

A-14

A-15

A-16

A-17

A-18

A-19

A-20

A-21

A-22

A-23

A-24

A-25

A-26

A-27

A-28

A-29

A-30

A-31

A-32

A-33

A-34

A-35

A-36

A-37

A-38

A-39

A-40

A-41

A-42

A-43

A-44

A-45

A-46

A-47

A-48

A-49

A-50

A-51

A-52

A-53

A-54

A-55

A-56

A-57

A-58

A-59

A-60

A-61

A-62

A-63

A-64

A-65

Compound

R 82

R 87

B-1

B-2

B-3

B-4

B-5

B-6

B-7

B-8

Compound

R 85

R 87

C-1

C-2

C-3

C-4

C-5

C-6

C-7

C-8

C-9

C-10

C-11

C-12

C-13

C-14

C-15

C-16

C-17

C-18

C-19

C-20

C-21

C-22

C-23

C-24

C-25

C-26

C-27

C-28

C-29

C-30

C-31

C-32

C-33

C-34

C-35

C-36

C-37

C-38

C-39

C-40

C-41

C-42

C-43

C-44

C-45

C-46

C-47

C-48

C-49

C-50

C-51

C-52

C-53

C-54

C-55

C-56

C-57

C-58

C-59

C-60

C-61

C-62

C-63

C-64

C-65

Cmp.

R 81

R 83

R 85

R 87

D-1

D-2

D-3

D-4

D-5

D-6

D-7

D-8

Compound

R 83

R 87

E-1

E-2

E-3

E-4

E-5

E-6

E-7

E-8

E-9

E-10

E-11

E-12

E-13

E-14

E-15

E-16

E-17

E-18

E-19

E-20

E-21

E-22

E-23

E-24

E-25

E-26

E-27

E-28

E-29

E-30

E-31

E-32

E-33

E-34

E-35

E-36

E-37

E-38

E-39

E-40

E-41

E-42

E-43

E-44

E-45

E-46

E-47

E-48

E-49

E-50

E-51

E-52

E-53

E-54

E-55

E-56

E-57

E-58

E-59

E-60

E-61

E-62

E-63

E-64

E-65

Compound

R 83

R 85

F-1

F-2

F-3

F-4

F-5

F-6

F-7

F-8

F-9

F-10

F-11

F-12

F-13

F-14

F-15

F-16

F-17

F-18

F-19

F-20

F-21

F-22

F-23

F-24

F-25

F-26

F-27

F-28

F-29

F-30

F-31

F-32

F-33

F-34

F-35

F-36

F-37

F-38

F-39

F-40

F-41

F-42

F-43

F-44

F-45

F-46

F-47

F-48

F-49

F-50

F-51

F-52

F-53

F-54

F-55

F-56

F-57

F-58

F-59

F-60

F-61

F-62

F-63

F-64

F-65

10. An electronic device, comprising a compound according to claim 1 .

11. The electronic device according to claim 10 , which is an electroluminescent device.

12. A hole transport layer, or an emitting layer comprising a compound according to claim 1 .

13. The emitting layer according to claim 12 , comprising the compound as host material in combination with a phosphorescent emitter.

14. An apparatus selected from the group consisting of stationary visual display units; mobile visual display units; illumination units; keyboards; items of clothing; furniture; wallpaper, comprising the organic electronic device according to claim 10 .

15. A device selected from the group consisting of electrophotographic photoreceptors, photoelectric converters, organic solar cells, switching elements, organic light emitting field effect transistors, image sensors, dye lasers and electroluminescent devices comprising the compound according to claim 1 .

16. A compound of the formula

wherein

B 1 is N, or CR 81 ,

B 2 is N, or CR 82 ,

B 3 is N, or CR 83 ,

B 4 is N, or CR 84 ,

B 5 is N, or CR 85 ,

B 6 is N, or CR 86 ,

B 7 is N, or CR 87 ,

B 8 is N, or CR 88 , wherein R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 are independently of each other H, a C 1 -C 25 alkyl group, which can optionally be substituted by E and or interrupted by D; a C 6 -C 24 aryl group, which can optionally be substituted by G, a C 2 -C 30 heteroaryl group, which can optionally be substituted by G; a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 , or -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -X 1 ,

wherein R 84 does not include a Cl atom;

o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1,

at least one of the substituents R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 represents a group of formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -X 1 ; wherein

X 1 is Cl, Br, or I, ZnX 12 , X 12 is a halogen atom; —SnR 207 R 208 R 209 , wherein R 207 , R 208 and R 209 are identical or different and are H or C 1 -C 8 alkyl, wherein two radicals optionally form a common ring and these radicals are optionally branched or unbranched; —B(OH) 2 , —B(OY 1 ) 2 ,

—BF 4 Na, or —BF 4 K, wherein Y 1 is independently in each occurrence a C 1 -C 18 alkyl group and Y 2 is independently in each occurrence a C 2 -C 10 alkylene group, and Y 13 and Y 14 are independently of each other hydrogen, or a C 1 -C 18 alkyl group, and o, p, q, r, G, A 1 , A 2 , A 3 , A 4 , R 81 , R 82 , R 83 , R 84 , R 85 , R 86 , R 87 and R 88 are as defined in claim 1 , with the proviso that the following compounds are excluded:

are excluded.

17. The electronic device according to claim 10 , comprising a compound of formula

wherein R 81 , R 82 , R 83 , R 85 , R 86 and R 87 are as defined in claim 1 .

18. The electronic device according to claim 17 , wherein

in the compounds of formula (Ia)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ib)

R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ic)

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Id)

R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

the compounds of formula (Ie)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (If)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ig)

R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ih)

R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

the compounds of formula (Ii)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ij)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Ik)

R 81 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 81 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Il)

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

in the compounds of formula (Im)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 85 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

the compounds of formula (In)

R 83 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 83 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 87 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; wherein

in the compounds of formula (Io)

R 82 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 86 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; or

R 82 is H, or a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ; and

R 86 is a group of the formula -(A 1 ) o -(A 2 ) p -(A 3 ) q -(A 4 ) r -R 16 ;

o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1;

A 1 , A 2 , A 3 and A 4 are independently of each other a group of the formula

R 16 is a group of the formula

or R 16 has the meaning of R 16 ′, if at least one of the groups A 1 , A 2 , A 3 and A 4 represent a group of formula

R 16″ is H, or a group of the formula—Si(R 12 )(R 13 )(R 14 ),

wherein

R 12 , R 13 , R 14 are independently of each other a phenyl group, which can optionally be substituted by one, or more alkyl groups;

R 21 and R 21' are independently of each other H, a phenyl group, or a C 1 -C 18 alkyl group;

R 22 and R 23 are independently of each other H, or a group of the formula

X is O, S, or NR 24,

R 24 is a C 6 -C 24 _aryl group, or a C 2 -C 30 heteroaryl group, which can optionally be substituted by G; and

R 89 is H, a group of formula

19. The electronic device according to claim 17 , wherein

o is 0, or 1, p is 0, or 1, q is 0, or 1, r is 0, or 1,

A 1 , A 2 , A 3 and A 4 are independently of each other a group of the formula

R 16 is a group of the formula

or R 16 has the meaning of R 16′ , if at least one of the groups A 1 , A 2 , A 3 and A 4 represent a group of formula

R 16′ is H, or a group of the formula

and R 89 is H, a group of formula

wherein X is O, S, or NR 24 , wherein

R 24 is

20. The electronic device according to claim 17 , comprising a compound selected from the group consisting of:

Compound

R 83

R 87

A-1

A-2

A-3

A-4

A-5

A-6

A-7

A-8

A-9

A-10

A-11

A-12

A-13

A-14

A-15

A-16

A-17

A-18

A-19

A-20

A-21

A-22

A-23

A-24

A-25

A-26

A-27

A-28

A-29

A-30

A-31

A-32

A-33

A-34

A-35

A-36

A-37

A-38

A-39

A-40

A-41

A-42

A-43

A-44

A-45

A-46

A-47

A-48

A-49

A-50

A-51

A-52

A-53

A-54

A-55

A-56

A-57

A-58

A-59

A-60

A-61

A-62

A-63

A-64

A-65

Compound

R 82

R 87

B-1

B-2

B-3

B-4

B-5

B-6

B-7

B-8

Compound

R 85

R 87

C-1

C-2

C-3

C-4

C-5

C-6

C-7

C-8

C-9

C-10

C-11

C-12

C-13

C-14

C-15

C-16

C-17

C-18

C-19

C-20

C-21

C-22

C-23

C-24

C-25

C-26

C-27

C-28

C-29

C-30

C-31

C-32

C-33

C-34

C-35

C-36

C-37

C-38

C-39

C-40

C-41

C-42

C-43

C-44

C-45

C-46

C-47

C-48

C-49

C-50

C-51

C-52

C-53

C-54

C-55

C-56

C-57

C-58

C-59

C-60

C-61

C-62

C-63

C-64

C-65

Cmp.

R 81

R 83

R 85

R 87

D-1

D-2

D-3

D-4

D-5

D-6

D-7

D-8

Compound

R 83

R 87

E-1

E-2

E-3

E-4

E-5

E-6

E-7

E-8

E-9

E-10

E-11

E-12

E-13

E-14

E-15

E-16

E-17

E-18

E-19

E-20

E-21

E-22

E-23

E-24

E-25

E-26

E-27

E-28

E-29

E-30

E-31

E-32

E-33

E-34

E-35

E-36

E-37

E-38

E-39

E-40

E-41

E-42

E-43

E-44

E-45

E-46

E-47

E-48

E-49

E-50

E-51

E-52

E-53

E-54

E-55

E-56

E-57

E-58

E-59

E-60

E-61

E-62

E-63

E-64

E-65

Compound

R 83

R 85

F-1

F-2

F-3

F-4

F-5

F-6

F-7

F-8

F-9

F-10

F-11

F-12

F-13

F-14

F-15

F-16

F-17

F-18

F-19

F-20

F-21

F-22

F-23

F-24

F-25

F-26

F-27

F-28

F-29

F-30

F-31

F-32

F-33

F-34

F-35

F-36

F-37

F-38

F-39

F-40

F-41

F-42

F-43

F-44

F-45

F-46

F-47

F-48

F-49

F-50

F-51

F-52

F-53

F-54

F-55

F-56

F-57

F-58

F-59

F-60

F-61

F-62

F-63

F-64

F-65

and

Assignments (3)

CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT APPL. NO. 14/901,736 PREVIOUSLY RECORDED AT REEL: 039460 FRAME: 0615. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 8, 2017

From: BASF SE

To: UDC IRELAND LIMITED

Reel/Frame 042740/0222 →

ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2016

From: BASF SE

To: UDC IRELAND LIMITED

Reel/Frame 039460/0615 →

ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2015

From: WOLLEB, ANNEMARIE; SCHAEFER, THOMAS; WOLLEB, HEINZ; HEINEMEYER, UTE; LANGER, NICOLLE; LENNARTZ, CHRISTIAN; WAGENBLAST, GERHARD; WATANABE, SOICHI; BENEDITO, FLAVIO LUIZ; HOTTINGER, HEINZ; DOSENBACH, OLIVER

To: BASF SE

Reel/Frame 035127/0179 →

Priority Claims (1)

EP 12185230 · Sep 20, 2012 · regional

Continuity (2)

Provisional Application 61703289 · Sep 20, 2012

Related Publication 20150243907A1 · Aug 27, 2015