IP Library Granted Patent US 9,346,954
Granted Patent B2
US 9,346,954 · App. 14/428,130 · Granted May 24, 2016

Curable resin composition

Inventors: Emi Kim (Hiratsuka, JP); Yoshihito Takei (Hiratsuka, JP); Tsubasa Ito (Hiratsuka, JP); Kazunori Ishikawa (Hiratsuka, JP)
Assignee: The Yokohama Rubber Co., Ltd.
C08L83/04C08G77/12C08G77/20C08G77/80C08L2205/025H01L23/296H01L33/56
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Quick Facts
Patent No.
US 9,346,954
App. No.
14/428,130
Granted
May 24, 2016
Kind
B2
Abstract

The object of the present invention is to provide a curable resin composition having excellent adhesion. This curable resin composition contains: a straight-chain organopolysiloxane (A) having at least two silicon-bonded hydrogen atoms and at least one aryl group in each molecule, the degree of polymerization being greater than 10; a branched-chain organopolysiloxane (B) having at least three alkenyl groups and at least one aryl group in each molecule; and a hydrosilylation reaction catalyst (C).

Claims (24)

1. A curable resin composition containing:

a straight-chain organopolysiloxane (A) having at least two silicon-bonded hydrogen atoms and at least one aryl group in each molecule, the degree of polymerization being greater than 10;

a branched-chain organopolysiloxane (B) having at least three alkenyl groups and at least one aryl group in each molecule;

a hydrosilylation reaction catalyst (C); and

a straight-chain organopolysiloxane (G) represented by the following formula (16)

HR 2 2 SiO(R 2 2 SiO) k SiR 2 2 H  (16)

In formula (16), each R 2 moiety is independently an alkyl group, an aryl group, a hydroxy group (—OH), or an alkoxy group, and at least one of the R 2 moieties is an aryl group;

in formula (16), k is a positive number from 1 to 5.

2. The curable resin composition according to claim 1 , wherein the degree of polymerization of the straight-chain organopolysiloxane (A) is greater than 30.

3. The curable resin composition according to claim 1 , wherein the branched-chain organopolysiloxane (B) is an organopolysiloxane represented by the following average unit formula (4)

(R 3 SiO 3/2 ) a (R 3 2 SiO 2/2 ) b (R 3 3 SiO 1/2 ) c (SiO 4/2 ) d (X 1 O 1/2 ) e   (4)

in formula (4), each R 3 moiety is independently a substituted or unsubstituted monovalent hydrocarbon group, however in each molecule, at least three of the R 3 moieties are alkenyl groups, and at least one R 3 is an aryl group;

in formula (4), X 1 is a hydrogen atom or an alkyl group;

in formula (4), a is a positive number; b is 0 or a positive number; c is 0 or a positive number; d is 0 or a positive number; e is 0 or a positive number; b/a is a number within a range of from 0 to 10; c/a is a number within a range of from 0 to 5; d/(a+b+c+d) is a number within a range of from 0 to 0.3; and e/(a+b+c+d) is a number within a range of from 0 to 0.4.

4. The curable resin composition according to claim 1 , further containing a low-viscosity organopolysiloxane (D) having a viscosity of at most 50,000 mPa·s at 25° C.

5. The curable resin composition according to claim 1 , wherein the composition is a composition for sealing an optical semiconductor element.

6. The curable resin composition according to claim 2 , wherein the branched-chain organopolysiloxane (B) is an organopolysiloxane represented by the following average unit formula (4)

(R 3 SiO 3/2 ) a (R 3 2 SiO 2/2 ) b (R 3 3 SiO 1/2 ) c (SiO 4/2 ) d (X 1 O 1/2 ) e   (4)

in formula (4), each R 3 moiety is independently a substituted or unsubstituted monovalent hydrocarbon group, however in each molecule, at least three of the R 3 moieties are alkenyl groups, and at least one R 3 is an aryl group;

in formula (4), X 1 is a hydrogen atom or an alkyl group;

in formula (4), a is a positive number; b is 0 or a positive number; c is 0 or a positive number; d is 0 or a positive number; e is 0 or a positive number; b/a is a number within a range of from 0 to 10; c/a is a number within a range of from 0 to 5; d/(a+b+c+d) is a number within a range of from 0 to 0.3; and e/(a+b+c+d) is a number within a range of from 0 to 0.4.

7. The curable resin composition according to claim 2 , further containing a low-viscosity organopolysiloxane (D) having a viscosity of at most 50,000 mPa·s at 25° C.

8. The curable resin composition according to claim 3 , further containing a low-viscosity organopolysiloxane (D) having a viscosity of at most 50,000 mPa·s at 25° C.

9. The curable resin composition according to claim 6 , further containing a low-viscosity organopolysiloxane (D) having a viscosity of at most 50,000 mPa·s at 25° C.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 21, 2024
From: SIKA JAPAN LTD.
To: SIKA TECHNOLOGY AG
Reel/Frame 066641/0001 →
MERGER Recorded Feb 5, 2024
From: SIKA HAMATITE CO., LTD.
To: SIKA JAPAN LTD.
Reel/Frame 066493/0072 →
DE-MERGER Recorded Dec 8, 2021
From: THE YOKOHAMA RUBBER CO., LTD.
To: SIKA HAMATITE CO., LTD.
Reel/Frame 060439/0022 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 13, 2015
From: KIM, EMI; TAKEI, YOSHIHITO; ITO, TSUBASA; ISHIKAWA, KAZUNORI
To: THE YOKOHAMA RUBBER CO., LTD.
Reel/Frame 035163/0024 →
Priority Claims (1)
JP 2012-202767 · Sep 14, 2012 · national
Continuity (1)
Related Publication 20150252191A1 · Sep 10, 2015