Derivatives of sulphosuccinic acid as a dispersing agent in aqueous binder-free pigment preparations
View Patent ↗The invention relates to aqueous binder-free pigment preparations containing (A) 1.0 to 75.0 wt. % of at least one organic or inorganic white or colored pigment or a mixture of different organic and inorganic white or colored pigments, (B) 0.01 to 8.0 wt. % of at least one compound of formula (I), R being a saturated or unsaturated, linear or branched, aliphatic or alicyclic hydrocarbon group with 6 to 18 carbon atoms; n is a whole number from 0 to 10; A is an oxygen atom or a bi-functional group of formula (II), B is a hydrogen atom or a group of formula (III), bonding thereof occurring by means of the valency characterized by *, X and Y are selected from sulphonic acid groups in acidic form or their sodium, potassium and ammonium salt, and hydrogen atoms, where if X represents a sulphonic acid group or its salt then Y is a hydrogen atom, and vice versa if X represents a hydrogen atom then Y is a sulphonic acid group or its salt, and M represents a hydrogen atom or a sodium, potassium or ammonium ion, and if B is a functional group of formula (III), n stands for 0 and M stands for a sodium atom, (C) 0.01 to 12.0 wt. % of a non-ionic surfactant, and (G) is water.
1. An aqueous, binder-free pigment preparation comprising
(A) 1.0 to 75.0 wt % of at least one organic or inorganic white or chromatic pigment or a mixture of different organic and inorganic white or chromatic pigments,
(B) 0.01 to 8.0 wt % of at least one compound of the formula (I),
in which
R is a saturated or unsaturated, linear or branched, aliphatic or alicyclic hydrocarbon radical having 6 to 18 carbon atoms,
n is an integer from 0 to 10,
A is an oxygen atom or a difunctional group of the formula (II)
B is a hydrogen atom or a group of the formula (III),
whose bonding is via the valence marked with *,
X and Y are selected from the group consisting of sulfonic acid groups in acidic form, their respective sodium, potassium, and ammonium salt and hydrogen atoms; wherein if X is a sulfonic acid group or salt thereof, Y is a hydrogen atom, and, conversely, if X is a hydrogen atom, Y is a sulfonic acid group or salt thereof, and
M is a hydrogen atom or a sodium, potassium, or ammonium ion,
and, if B is a functional group of the formula (III), n is 0 and M is a sodium atom,
(C) 0.01 to 12.0 wt % of a nonionic surfactant which is a fatty acid ethanolamide ethoxylate of the formula (VII),
in which m is an integer from 3 to 50 and R 1 is C 7 to C 21 alkyl or alkenyl, and
(G) water.
2. The aqueous, binder-free pigment preparation as claimed in claim 1 , wherein R is an alkyl or alkenyl radical.
3. The aqueous, binder-free pigment preparation as claimed in claim 1 , wherein component (B) is a sulfosuccinic monoester of the formula (IV),
in which
R, n, X, Y, and M have the definitions indicated in claim 1 .
4. The aqueous, binder-free pigment preparation as claimed in claim 1 , wherein component (B) is an alkyl sulfosuccinamate of the formula (V),
in which
R, X, Y, and M have the definitions indicated in claim 1 .
5. The aqueous, binder-free pigment preparation as claimed in claim 1 , wherein component (B) is a sulfosuccinamide of the formula (VI),
in which
R, X, Y, and M have the definitions indicated in claim 1 .
6. The aqueous, binder-free pigment preparation as claimed in claim 1 , containing 1 to 12 wt % of a fatty acid alkanolamide ethoxylate of the formula (VII).
7. The aqueous, binder-free pigment preparation as claimed in claim 1 , containing 1 to 8 wt % of a compound of the formula (I).
8. The aqueous, binder-free pigment preparation as claimed in claim 1 , containing 10 to 75 wt % of water.
9. The aqueous, binder-free pigment preparation as claimed in claim 1 , having a viscosity of 10 to 10 000 mPas as determined using a cone/plate viscometer at a shear rate of 1/60 sec−1.
10. The aqueous, binder-free pigment preparation as claimed in claim 1 , further comprising
(D) 0-8.0 wt % of clay mineral thickeners based on natural or alkali-activated montmorillonite phyllosilicate minerals.
11. The aqueous, binder-free pigment preparation as claimed in claim 1 , further comprising
(E) 0-20.0 wt % of inorganic fillers.
12. The aqueous, binder-free pigment preparation as claimed in claim 1 , further comprising
(F) 0 to 30 wt % of further auxiliaries customary for the production of aqueous, binder-free pigment preparations, selected from wetting agents, humectants, solvents, defoamers, rheological additives, preservatives, buffer substances, and pH regulators.
13. The aqueous, binder-free pigment preparation as claimed in claim 12 , containing up to 15 wt % of at least one humectant or solvent selected from the group consisting of glycol ethers with a 200 to 20 000 g/mol number-average molecular weight.
14. The aqueous, binder-free pigment preparation as claimed in claim 12 , containing up to 2 wt % of defoamers.
15. The aqueous, binder-free pigment preparation as claimed in claim 12 , containing up to 1 wt % of an in-can preservative.
16. A process for coloring a macromolecular material, coating material, paint and ink, comprising the step of adding at least one aqueous, binder-free pigment preparation comprising
(A) 1.0 to 75.0 wt % of at least one organic or inorganic white or chromatic pigment or a mixture of different organic and inorganic white or chromatic pigments,
(B) 0.01 to 8.0 wt % of at least one compound of the formula (I),
in which
R is a saturated or unsaturated, linear or branched, aliphatic or alicyclic hydrocarbon radical having 6 to 18 carbon atoms,
n is an integer from 0 to 10,
A is an oxygen atom or a difunctional group of the formula (II)
B is a hydrogen atom or a group of the formula (III),
whose bonding is via the valence marked with *,
X and Y are selected from the group consisting of sulfonic acid groups in acidic form, their respective sodium, potassium, and ammonium salt and hydrogen atoms; wherein if X is a sulfonic acid group or salt thereof, Y is a hydrogen atom, and, conversely, if X is a hydrogen atom, Y is a sulfonic acid group or salt thereof, and
M is a hydrogen atom or a sodium, potassium, or ammonium ion,
and, if B is a functional group of the formula (III), n is 0 and M is a sodium atom,
(C) 0.01 to 12.0 wt % of a nonionic surfactant which is a fatty acid ethanolamide ethoxylate of the formula (VII),
in which m is an integer from 3 to 50 and R 1 is C 7 to C 21 alkyl or alkenyl, and
(G) water to the macromolecular material, coating material, paint or ink.
17. A macromolecular material, coating material, paint or ink, comprising at least one aqueous, binder-free pigment preparation as claimed in claim 1 .
18. A process for printing a two-dimensional sheet structure comprising the step of contacting the two-dimensional sheet structure with at least one macromolecular material, coating material, paint or ink, as claimed in claim 17 .