Method for producing a galvannealed steel sheet
View Patent ↗A galvannealed steel sheet includes: a scale-removed rolled steel sheet; and a galvannealed layer arranged on the scale-removed rolled steel sheet. When ten measurement points of the galvannealed steel sheet are set in a transverse direction by equally dividing a line-segment having a reference length of 50 mm by 10, a minimum P content of the galvannealed layer in the ten measurement points is 50% or more as compared with a maximum P content therein.
1. A method for producing a galvannealed steel sheet, the method comprising:
casting a molten steel which comprises, as a chemical composition, by mass %,
0.0005% to 0.01% of C,
0.001% to 1.0% of Si,
0.01% to 2.0% of Mn,
0.005% to 0.1% of P,
0.01% to 0.10% of Al,
0.02% or less of S,
0.1% or less of Ni,
0.1% or less of Cu,
0.01% or less of N, and
a balance consisting of Fe and unavoidable impurities in order to obtain a slab;
heating the slab in 1100° C. to 1300° C.;
hot-rolling the slab after the heating under conditions such that a finishing temperature is in 800° C. to 1050° C. and a coiling temperature is in 500° C. to 800° C. in order to obtain a hot-rolled steel sheet;
surface-removing the hot-rolled steel sheet within a range in μm of GL expressed by a following Expression 1 or more and GU expressed by a following Expression 2 or less from an interface toward a steel along a thickness direction in order to obtain a scale-removed rolled steel sheet, when ten measurement points of the hot-rolled steel sheet are set in a transverse direction by equally dividing a line-segment having a reference length of 50 mm by 10, when a steel surface part of the hot-rolled steel sheet is from the interface between a scale and the steel to 2 μm in depth toward the steel along the thickness direction, and when a Ni max and a Cu max are respectively a maximum Ni content and a maximum Cu content in mass % of the steel surface part in the ten measurement points of the hot-rolled steel sheet;
galvanizing the scale-removed rolled steel sheet after the surface-removing in order to obtain a galvanized steel sheet; and
galvannealing the galvanized steel sheet after the galvanizing in order to obtain a galvannealed steel sheet,
GL=(Ni max +0.8×Cu max )×0.2 (Expression 1),
GU=(Ni max +0.8×Cu max )×4 (Expression 2).
2. The method for producing the galvannealed steel sheet according to claim 1 ,
wherein the molten steel further comprises, as the chemical composition, by mass %, at least one selected from
0. 0001% to 0.0050% of B,
0.001% to 0.1% of Nb,
0.001% to 0.1% of Ti, and
0.001% to 0.1% of Mo.
3. The method for producing the galvannealed steel sheet according to claim 2 , the method further comprising
pickling at least a surface of the hot-rolled steel sheet before the surface-removing or the scale-removed rolled steel sheet after the surface-removing.
4. The method for producing the galvannealed steel sheet according to claim 1 , the method further comprising
pickling at least a surface of the hot-rolled steel sheet before the surface-removing or the scale-removed rolled steel sheet after the surface-removing.
5. The method for producing the galvannealed steel sheet according to claim 1 , the method further comprising:
cold-rolling the scale-removed rolled steel sheet before the galvanizing under a cold-reduction of 50% to 95%; and
annealing the scale-removed rolled steel sheet after the cold-rolling in a temperature which is a recrystallization temperature or higher.
6. The method for producing the galvannealed steel sheet according to claim 2 , the method further comprising:
cold-rolling the scale-removed rolled steel sheet before the galvanizing under a cold-reduction of 50% to 95%; and
annealing the scale-removed rolled steel sheet after the cold-rolling in a temperature which is a recrystallization temperature or higher.
7. The method for producing the galvannealed steel sheet according to claim 3 , the method further comprising:
cold-rolling the scale-removed rolled steel sheet before the galvanizing under a cold-reduction of 50% to 95%; and
annealing the scale-removed rolled steel sheet after the cold-rolling in a temperature which is a recrystallization temperature or higher.
8. The method for producing the galvannealed steel sheet according to claim 4 , the method further comprising:
cold-rolling the scale-removed rolled steel sheet before the galvanizing under a cold-reduction of 50% to 95%; and
annealing the scale-removed rolled steel sheet after the cold-rolling in a temperature which is a recrystallization temperature or higher.