Method for producing diisocyanates by phosgenating diamine suspensions
View Patent ↗The invention relates to a method for producing organic diisocyanates by reacting the corresponding diamines with phosgene in inert solvents. High-melting diamines from the series of 1,5-naphthalenediamine, tetralindiamine, 1,4-phenylenediamine, durenediamine, and o-tolidinediamine are used as diamines. According to the invention, a suspension of the diamines in inert solvents is produced, wherein dynamic mixing units, selected from dispersion disks and rotor-stator systems, are used, and the obtained suspension is phosgenated.
1. A process for preparing a diisocyanate selected from the group consisting of naphthalene diisocyanate, phenylene diisocyanate, tetralin diisocyanate, o-tolidine diisocyanate and durene diisocyanate, which comprises the following steps:
(i) producing a suspension of the corresponding diamine in an inert solvent, with the diamine being dispersed in the solvent by means of a dynamic mixing apparatus,
(ii) contacting the diamine suspended in the inert solvent with phosgene to give the respective diisocyanate,
wherein
the dynamic mixing apparatus in step (i) is selected from the group consisting of dispersing discs and rotor-stator systems.
2. The process as claimed in claim 1 , wherein the dynamic mixing apparatus in step (i) is a rotor-stator system.
3. The process as claimed in claim 2 , wherein the rotor-stator system is selected from the group consisting of colloid mills, toothed dispersing machines and three-roll mills.
4. The process as claimed in claim 3 , wherein the rotor-stator system is a toothed dispersing machine.
5. The process as claimed in claim 1 , wherein the dispersing of the diamine in the solvent in step (i) is carried out in such a way that the volume-based average particle diameter D(0.50) of the suspended diamine obtained in step (i) is not more than 140 μm and not more than 1.0% by volume of all suspended diamine particles, based on the total volume of all diamine particles, have a volume-based particle diameter of greater than 1500 μm.
6. The process as claimed in claim 1 , wherein step (i) is carried out at a temperature of from 0° C. to 150° C. and an absolute pressure of from 1.0 bar to 20 bar.
7. The process as claimed in claim 1 , wherein step (ii) is carried out at a temperature of from 0° C. to 350° C. and an absolute pressure of from 1.0 bar to 5.0 bar.
8. The process as claimed in claim 1 , wherein the phosgene required in step (ii) is at least partly placed initially in the inert solvent at a temperature of from −40° C. to +10° C. and an absolute pressure of from 1.0 bar to 20 bar before addition of the diamine and the phosgenation is completed by increasing the temperature to a value in the range from 0° C. to 350° C. at an absolute pressure of from 1.0 bar to 20 bar after production of the suspension.
9. The process as claimed in claim 1 , wherein the diisocyanate is naphthalene diisocyanate.