Electrode structure including insulating layer, manufacturing method thereof, and electrochemical device including the electrode
View Patent ↗Disclosed is a method for manufacturing an electrode structure including (S1) coating and drying a slurry for an electrode active material layer on an electrode current collector placed on a heated bottom surface, (S2) coating and drying a slurry for an insulating layer including inorganic particles, a binder, and a solvent, on a heated roller located at a predetermined distance from the bottom surface, and (S3) transferring the dried slurry for an insulating layer to the dried slurry for an electrode active material layer on the bottom surface, and thermo-compressing the dried slurry for an insulating layer and the dried slurry for an electrode active material layer, to form an insulating layer on an electrode surface.
1. A method for manufacturing an electrode structure, comprising:
(S1) coating and drying a slurry for an electrode active material layer on an electrode current collector placed on a heated bottom surface;
(S2) coating and drying a slurry for an insulating layer including inorganic particles, a binder, and a solvent, on a heated roller located at a predetermined distance from the bottom surface to form a dried slurry dry product for the insulating layer; and
(S3) transferring the dried slurry dry product for the insulating layer to the dried slurry for the electrode active material layer on the bottom surface, and thermo-compressing the dried slurry dry product for the insulating layer and the dried slurry for the electrode active material layer, to form an insulating layer on an electrode surface.
2. The method for manufacturing the electrode structure according to claim 1 , wherein when thermo-compressing the dried slurry dry product for the insulating layer and the dried slurry for the electrode active material layer, a porous substrate is interposed between the dried slurry dry product for the insulating layer and the dried slurry for the electrode active material layer.
3. The method for manufacturing the electrode structure according to claim 1 , wherein a temperature of the heated bottom surface is from 40 to 200° C.
4. The method for manufacturing the electrode structure according to claim 1 , wherein a temperature of the heated roller is from 40 to 200° C.
5. The method for manufacturing the electrode structure according to claim 1 , wherein a distance between the heated bottom surface and the heated roller is from 0.01 to 10 mm.
6. The method for manufacturing the electrode structure according to claim 1 , wherein a pressing condition for the thermo-compression is from 1 to 500 kgf/cm 2 .
7. The method for manufacturing the electrode structure according to claim 1 , wherein the bottom surface is a surface of a belt connected to a transfer means.
8. The method for manufacturing the electrode structure according to claim 1 , wherein the solvent is any one solvent selected from the group consisting of acetone, tetrahydrofuran, methylene chloride, chloroform, dimethylformamide, dimethylacetamide, hexamethylphosphoamide, acetonitrile, cyclohexanone, N-methyl-2-pyrrolidone (NMP), cyclohexane, and water (distilled water), or mixtures thereof.
9. The method for manufacturing the electrode structure according to claim 1 , wherein the binder is any one binder polymer selected from the group consisting of polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethylmethacrylate, polybutylacrylate, polyacrylonitrile, polyvinylpyrrolidone, polyvinylacetate, polyethylene-co-vinyl acetate, polyethylene oxide, polyarylate, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylpullulan, cyanoethylpolyvinylalcohol, cyanoethylcellulose, cyanoethylsucrose, pullulan, carboxyl methyl cellulose (CMC), and styrene-butadiene rubber (SBR), or mixtures thereof.
10. The method for manufacturing the electrode structure according to claim 1 , wherein a thickness of the thermo-compressed insulating layer is from 1 to 100 μm.
11. The method for manufacturing the electrode structure according to claim 1 , wherein an average grain diameter of the inorganic particles is from 0.001 to 10 μm.
12. The method for manufacturing the electrode structure according to claim 1 , wherein a weight ratio of the inorganic particles and the binder polymer is from 50:50 to 99:1.
13. The method for manufacturing the electrode structure according to claim 1 , wherein a thickness of the thermo-compressed electrode active material layer is from 0.5 to 200 μm.
14. The method for manufacturing the electrode structure according to claim 1 , wherein an electrode active material included in the slurry for the electrode active material layer is a cathode active material, and the electrode structure is a cathode structure.
15. The method for manufacturing the electrode structure according to claim 1 , wherein an electrode active material included in the slurry for the electrode active material layer is an anode active material, and the electrode structure is an anode structure.