Vinylidene chloride copolymer composition for barrier film
The present disclosure is directed to a composition comprising (a) a vinylidene chloride/methyl acrylate interpolymer having greater than 6 wt % methyl acrylate mer units in the interpolymer, (b) greater than 6 wt % of an epoxy plasticizer; and (c) less than 4 wt % of an acrylate polymer. The composition exhibits a crystallization time greater than 25 minutes to crystallization at 35° C. Films made from the present composition show improved processability and find advantageous application as permeable barrier film for food packaging, for specialty food packaging, and for gassy cheese.
1. A packaging film for food application comprising a composition comprising:
(A) from 86 wt % to 91 wt % of a vinylidene chloride/methyl acrylate interpolymer having from 7.7 wt % to 8.5 wt % methyl acrylate mer units in the interpolymer;
(B) from 7 wt % to 10 wt % of an epoxy plasticizer that is epoxidized soybean oil based on total weight of the composition; and
(C) from 2 wt % to less than 4 wt % of an acrylate polymer based on total weight of the composition, the acrylate polymer consisting of an interpolymer of methyl methacrylate, butyl methacrylate, and butyl acrylate; wherein
(D) the composition has a crystallization time greater than 50 minutes to crystallization at 35° C. measured with a differential scanning calorimeter; and
(E) the composition has an oxygen transmission rate of 1.5 to 9.0 cc-mil/100 in 2 -atm-day as measured in accordance with ASTM D 3985,
wherein the packaging film expels CO 2 generated from food.
2. The packaging film for food application of claim 1 wherein the epoxy plasticizer has a molecular weight greater than 600 Daltons.
3. A multi-layer film for food application comprising:
(A) first and second surface layers; and
(B) an inner layer disposed between the surface layers, the inner layer comprising the packaging film of claim 1 .
4. The multi-layer film for food application of claim 3 wherein the multi-layer film is in contact with a gassy cheese.