Method for preparing a statistical copolymer based on diene monomers and cyclic carbosilane monomers
View Patent ↗The present invention relates to a process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers. This process is characterized in that it comprises a stage of copolymerization, in the presence of an anionic initiator in a reaction medium comprising a polar solvent, of at least one diene monomer and of a cyclic carbosilane monomer corresponding to the Formula I: in which: R 1 and R 2 , which are identical or different, are each a C 1 -C 5 alkyl, C 6 -C 14 aryl or C 7 -C 11 alkylaromatic group; R 3 and R 4 , which are identical or different, are each a hydrogen atom or a C 1 -C 5 alkyl, C 6 -C 14 aryl or C 7 -C 11 alkylaromatic group; and x is an integer with a value ranging from 2 to 5 and is preferably 3.
1. A process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers, comprising a stage of copolymerization, in the presence of an anionic initiator in a polymerization solvent comprising an inert polar solvent, of at least one diene monomer and of at least one cyclic carbosilane monomer corresponding to the Formula I:
with:
R1 and R2, which are identical or different, each being a C1-C5 alkyl, C6-C14 aryl or C7-C11 alkylaromatic group;
R3 and R4, which are identical or different, each being a hydrogen atom or a C1-C5 alkyl, C6-C14 aryl or C7-C11 alkylaromatic group; and
x being an integer with a value ranging from 2 to 5.
2. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 1 , wherein a fraction by volume of inert polar solvent with respect to a total volume of solvent is at least 10%.
3. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 1 , wherein the polymerization solvent also comprises an inert nonpolar solvent.
4. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 1 , wherein the anionic initiator comprises an alkali metal.
5. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 1 , wherein the diene monomer is 1,3-butadiene.
6. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 1 , wherein at least one other monomer copolymerizes during the copolymerization stage.
7. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 6 , wherein the other monomer is a vinylaromatic compound.
8. A random copolymer comprising, distributed randomly within a main linear chain of the copolymer, unsaturated units resulting from at least one diene monomer and dialkylcarbosilane units resulting from at least one cyclic carbosilane monomer of Formula I:
with:
R1 and R2, which are identical or different, each being a C1-C5 alkyl, C6-C14 aryl or C7-C11 alkylaromatic group;
R3 and R4, which are identical or different, each being a hydrogen atom or a C1-C5 alkyl, C6-C14 aryl or C7-C11 alkylaromatic group; and
x being an integer with a value ranging from 2 to 5,
the diene monomer being inserted predominantly according to an enchainment of 1,4-type.
9. The random diene copolymer according to claim 8 , wherein the diene monomer is 1,3-butadiene.
10. The random diene copolymer according to claim 8 , further comprising, in addition to these unsaturated units and these dialkylcarbosilane units, units resulting from at least one other monomer.
11. The random diene copolymer according to claim 10 , wherein this other monomer is styrene.
12. A random diene copolymer, prepared according to the process defined in claim 1 .
13. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 4 , wherein the anionic initiator comprises an aliphatic organolithium compound.
14. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 7 , wherein the vinylaromatic compound is styrene.
15. The process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers according to claim 1 , wherein x has a value of 3.
16. The random diene copolymer according to claim 8 , wherein x has a value of 3.