Manufacturing method of green compacts of rare earth alloy magnetic powder and a manufacturing method of rare earth magnet
The present invention discloses a manufacturing method of green compacts of rare earth alloy magnetic powder and a manufacturing method of rare earth magnet, it is a manufacturing method that pressing the rare earth alloy magnetic powder added with organic additive in a closed space filled with inert gases to manufacture the green compacts, wherein the rare earth alloy magnetic powder is compacted under magnetic field in a temperature atmosphere of 25° C.-50° C. and a relative humidity atmosphere of 10%-40%. This method is to set the temperature of the inert atmosphere in a fully closed space, inhibiting bad forming phenomenon of the magnet with low oxygen content (broken, corner-breakage, crack) after sintering, and increasing the degree of orientation, Br and (BH)max.
1. A method of manufacturing a green compact composed of rare earth alloy magnetic powder, the method comprising:
(a) preparing a rare earth alloy magnetic powder in a closed space by:
(i) providing a melt comprised of a rare earth alloy;
(ii) rapidly cooling the melt at a cooling rate ranging between 100° C/s and 10000° C/s to solidify the rare earth alloy;
(iii) performing hydrogen decrepitation on the solidified rare earth alloy to provide a decrepitated alloy; and
(iv) crushing the decrepitated alloy using a fine crusher provided in a pulverizing room having a controlled atmosphere to obtain said rare earth alloy magnetic powder, the controlled atmosphere having a concentration of less than 100 ppm of an oxide gas comprised of at least one of oxygen and water; and
(b) preparing said green compact by:
(i) pressing the rare earth alloy magnetic powder with at least one organic additive under a magnetic field in a closed space having an atmosphere comprised of at least one inert gas, having a temperature ranging from 40° C.-45° C. and a relative humidity ranging from 20%-35%, to provide said green compact.
2. The method according to claim 1 , wherein the rare earth alloy magnetic powder is a NdFeB series rare earth alloy magnetic powder.
3. The method according to claim 2 , wherein the atmosphere during pressing has a an oxygen concentration below 1000 ppm.
4. The method according to claim 3 , wherein the organic additive is at least one of a mineral oil, a synthetic oil, an animal oil, a vegetable oil, at least one organic ester, a paraffin, a polyethylene wax, a modified wax, and
wherein a weight ratio of the organic additive and the rare earth alloy magnetic powder ranges from 0.01˜1.5:100.
5. The method according to claim 4 , wherein the at least one organic ester is a methyl caprylate.
6. A method of manufacturing a rare earth magnet from a green compact composed of a rare earth alloy magnetic powder, the method comprising:
(a) preparing said rare earth alloy magnetic powder in a closed space by:
(i) providing a melt comprised of a rare earth alloy;
(ii) rapidly cooling the melt at a cooling rate ranging between 100° C/s and 10000° C/s to solidify the rare earth alloy;
(iii) performing hydrogen decrepitation on the solidified rare earth alloy to provide a decrepitated alloy; and
(iv) crushing the decrepitated alloy using a fine crusher provided in a pulverizing room having a controlled atmosphere to obtain a rare earth alloy magnetic powder, the controlled atmosphere having a concentration of less than 100 ppm of an oxide gas comprised of at least one of oxygen and water; and
(b) preparing said green compact by pressing the rare earth alloy magnetic powder with at least one organic additive under a magnetic field in a closed space having an atmosphere comprised of at least one inert gas, having a temperature ranging from 40° C.-45° C. and a relative humidity ranging from 20%-35% provide said green compact; and
(c) sintering the green compact to provide said rare earth magnet.