Electrode for electrochemical device with low resistance, method for manufacturing the same, and electrochemical device comprising the electrode
The present disclosure relates to an electrode that may minimize an electrical resistance increase caused by a binder polymer or a conductive material used in the electrode and provide a high capacity, a method for manufacturing the same, and an electrochemical device comprising the electrode, and an electrode mix slurry is prepared using a high shearing mixing process for each step such that fine grained conductive material and a binder polymer are uniformly dispersed in an electrode mix, and a high capacity electrode active material is used in the electrode mix, to manufacture a high capacity electrochemical device.
1. A method for manufacturing an electrode, comprising:
mixing a first slurry including a binder polymer dispersed in a solvent, wherein the solvent is selected from N-methyl pyrrolidone;
adding a conductive material to the first slurry to form a second slurry, mixing the second slurry;
adding an electrode active material and dispersing the same in the mixed second slurry to obtain an electrode mix slurry, wherein the electrode active material is selected from a first group consisting of a compound represented by Li a Ni x Mn y Co z O 2 where 0.6<a/(x+y+z)<1.0 and 1.4<x+y+z<2.5, LiCoO 2 , and LiFeO 4 , and mixtures thereof, or selected from a second group consisting of a silicon-based compound, a tin-based compound, and a mixtures thereof;
coating the electrode mix slurry on a current collector; and
drying the electrode mix slurry on the current collect to form the electrode.
2. The method for manufacturing an electrode according to claim 1 , wherein the mixing of the first slurry and the mixing of the second slurry is, independently, performed by a beads mil, a microfludizer, a Fil mixer, or a planetary dispersive mixer.
3. The method for manufacturing an electrode according to claim 1 , wherein each of the mixing of the first slurry and the mixing of the second slurry is performed at a shear pressure ranging from 20,000 to 40,000 psi.
4. The method for manufacturing an electrode according to claim 1 , wherein the binder polymer after the mixing of the first slurry has a molecular weight in a range of 27,000 to 380,000.
5. The method for manufacturing an electrode according to claim 1 , wherein the second slurry after the mixing of the second slurry has an absolute value of Zeta potential in a range of 20 mV to 100 mV.