Separator for electrochemical device and method for manufacturing the same
View Patent ↗The present disclosure relates to a separator for an electrochemical device with pores having predetermined diameter, permeation time, and tortuosity, to allow for smooth movement of lithium ions and a method for manufacturing the same, and smooth movement of lithium ions may be optimized by the separator for an electrochemical device.
1. A separator for an electrochemical device, comprising:
a porous substrate consisting of a single layer, the single layer comprising a polymer,
wherein the single layer has a permeation time of 5 to 500 s/100 cc and pores having a diameter from 1 to 100 nm,
wherein the pores extend from a first side of the porous substrate to a second side of the porous substrate, the first side and the second side of the porous substrate separated by a thickness of the porous substrate,
wherein the pores have a cylindrical shape, the cylindrical shape having little or no tortuous nature, where no tortuous nature is equivalent to a tortuosity of 1,
wherein the polymer is selected from the group consisting of polyethylene, low density polyethylene, linear low density polyethylene, ultrahigh molecular weight polyethylene, polypropylene, polyethyleneterephthalate, polybutyleneterephthalate, polyester, polyacetal, polyamide, polycarbonate, polyimide, polyetheretherketone, polyethersulfone, polyphenyleneoxide, polyphenylenesulfidro, polyethylenenaphthalene, polysulfone, cellulose acetate, and polystyrene, and mixtures thereof, and
wherein the tortuosity is determined by dividing a distance a molecule moving within a pore travels between a first point and second point by a straight line distance between the first point and the second point, the first point located on the first side of the porous substrate and the second point located on the second side of the porous substrate.
2. An electrochemical device, comprising: a cathode, an anode, a separator interposed between the cathode and the anode, and an electrolyte solution, wherein the separator is a separator defined in claim 1 .
3. The electrochemical device according to claim 2 , wherein the electrochemical device is a lithium secondary battery.
4. A method for manufacturing a separator for an electrochemical device, the method comprising:
irradiating a substrate with an ion beam, the substrate consisting of a single layer, the single layer comprising a polymer; and
applying an etching solution to the irradiated substrate to form pores in the substrate, wherein the pores extend from a first side of the porous substrate to a second side of the porous substrate, the first side and the second side of the porous substrate separated by a thickness of the porous substrate,
wherein the porous substrate has a permeation time of 5 to 500 s/100 cc and pores having a diameter from 1 to 100 nm,
wherein the pores have a cylindrical shape, the cylindrical shape having little or no tortuous nature, where no tortuous nature is equivalent to a tortuosity of 1,
wherein the polymer is selected from the group consisting of polyethylene, low density polyethylene, linear low density polyethylene, ultrahigh molecular weight polyethylene, polypropylene, polyethyleneterephthalate, polybutyleneterephthalate, polyester, polyacetal, polyamide, polycarbonate, polyimide, polyetheretherketone, polyethersulfone, polyphenyleneoxide, polyphenylenesulfidro, polyethylenenaphthalene, polysulfone, cellulose acetate, and polystyrene, and mixtures thereof, and
wherein the tortuosity is determined by dividing a distance a molecule moving within a pore travels between a first point and second point by a straight line distance between the first point and the second point, the first point located on the first side of the porous substrate and the second point located on the second side of the porous substrate.
5. The method for manufacturing a separator for an electrochemical device according to claim 4 , wherein the ion beam has an acceleration voltage in a range of 100 to 300 MeV.
6. The method for manufacturing a separator for an electrochemical device according to claim 4 , wherein the etching solution is any one selected from the group consisting of sodium hydroxide (NaOH), potassium hydroxide (KOH), calcium hydroxide (Ca(OH)2), sodium hypochlorite (NaClO), and hydrogen peroxide (H2O2), or mixtures thereof.
7. The method for manufacturing a separator for an electrochemical device according to claim 4 , wherein the etching solution has concentration from 1 to 10 M.
8. The method for manufacturing a separator for an electrochemical device according to claim 4 , wherein the etching solution is applied to the film for 1 to 30 minutes.
9. The method for manufacturing a separator for an electrochemical device according to claim 4 , wherein the ion beam is oriented at a right angle to the substrate.