Cathode active material for lithium secondary battery and method for manufacturing the same
View Patent ↗The present disclosure relates to a cathode active material for a lithium secondary battery with improved rate characteristics in which a spinel surface structure is formed by fluorine coating on a surface of layered lithium nickel-manganese-cobalt cathode active material and a method for manufacturing the same, and according to the present disclosure, there is provided a lithium secondary battery with improved rate characteristics that may be charged to a capacity close to a full charge in a short time when compared to a related art and thus is suitable for high capacity of a secondary battery.
1. A cathode active material for a lithium secondary battery, wherein the cathode active material is represented by the following general formula 2:
Li x Ni y Mn z Co 1-y-z M α O 2 [General Formula 2]
where z≥0.5, z>y, z>1-y-z≥0, 1.5≥x≥1, 0≤α≤1, and M is at least one metal selected from the group consisting of B, Li, Mg, Al, Ca, Sr, Cr, V, Ti, Fe, Co, Ni, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, and combinations thereof;
and wherein the cathode active material has a layered structure and a fluorine-coated surface, the fluorine-coated surface has a spinel-like phase, and the fluorine-coated surface is made by a compound comprising polyvinylidene fluoride (PVdF).
2. The cathode active material for a lithium secondary battery according to claim 1 , wherein the cathode active material has a grain size of a longest diameter from 20 nm to 200 μm.
3. The cathode active material for a lithium secondary battery according to claim 1 , wherein the fluorine-coated surface has a thickness from 2 nm to 20 μm.
4. The cathode active material for a lithium secondary battery according to claim 1 , wherein a z/y value representing an Mn/Ni atomic ratio in the general formula 2 is 1<z/y≤20.
5. A cathode for a lithium secondary battery, manufactured from a cathode mix slurry including the cathode active material for a lithium secondary battery according to claim 1 .
6. A lithium secondary battery comprising: a cathode, an anode, a separator interposed between the cathode and the anode, and an electrolyte solution, wherein the cathode is the cathode for a lithium secondary battery according to claim 5 .
7. A battery module comprising the lithium secondary battery according to claim 6 as a unit cell.
8. A battery pack comprising the battery module according to claim 7 .
9. A device comprising the battery pack according to claim 8 , wherein the device is an electric vehicle, a hybrid electric vehicle, a plug-in electric vehicle, or an energy storage system.
10. A method for manufacturing the cathode active material of claim 1 , the method comprising:
(a) uniformly mixing a nickel compound, a manganese compound, and cobalt compound;
(b) adding a lithium compound to a resultant of (a) and performing a baking treatment to obtain a layered lithium nickel-manganese-cobalt cathode active material; and
(c) coating fluorine on a surface of the layered lithium nickel-manganese-cobalt cathode active material so that the fluorine coated surface has a spinel-like phase.
11. The method according to claim 10 , wherein the fluorine coating is performed by a solid state reaction method using heat treatment, a spray drying method, or a vapor reaction method.