LED based device with wide color gamut
View Patent ↗The invention provides a lighting unit comprising a source of blue light, a source of green light, a first source of red light comprising a first red luminescent material, configured to provide red light with a broad band spectral light distribution, and a second source of red light comprising a second red luminescent material, configured to provide red light with a spectral light distribution comprising one or more red emission lines. Especially, the first red luminescent material comprises (Mg,Ca,Sr)AlSiN 3 :Eu and/or (Ba,Sr,Ca) 2 Si 5-x Al x O x N 8-x :Eu, and the second red luminescent material comprises K 2 SiF 6 :Mn.
1. A lighting unit comprising a source of blue light, a source of green light, a first source of red light comprising a first red luminescent material, arranged to provide red light with a broad band spectral light distribution, and a second source of red light comprising a second red luminescent material, arranged to provide red light with a spectral light distribution comprising one or more red emission lines.
2. The lighting unit according to claim 1 , wherein the first source of red light is configured to provide red light with a broad band spectral light distribution having a centroid emission wavelength ≧590 nm and with a full width half maximum of ≧70 nm.
3. The lighting unit according to claim 1 , wherein the first source of red light comprises said first red luminescent material selected from the group consisting of a divalent europium containing sulfide, a divalent europium containing nitride and a divalent europium containing oxynitride.
4. The lighting unit according to claim 1 , wherein the first source of red light comprises said first red luminescent material, selected from the group consisting of AlSiN 3 :Eu and (Ba,Sr,Ca) 2 Si 5-x Al x O x N 8-x :Eu, wherein 0≦x≦4.
5. The lighting unit according to claim 1 , wherein the second source of red light is configured to provide red light with a spectral light distribution comprising one or more red emission lines having a centroid emission wavelength ≧610 nm and with one or more red emission lines having a full width half maximum (FWHM) of ≦6 nm.
6. The lighting unit according to claim 1 , wherein the second source of red light comprises said second red luminescent material selected from the group consisting of M 2 AX 6 doped with tetravalent manganese, wherein M comprises monovalent cations, selected from the group consisting of Li, Na, K, Rb, Cs, NH 4 , wherein A comprises a tetravalent cation selected from the group consisting of Si, Ti, Ge, Sn, and Zr, and wherein X comprises a monovalent anion selected from the group consisting of F, Cl, Br and I, but at least comprising F.
7. The lighting unit according to claim 1 , wherein the second source of red light comprises said second red luminescent material comprising K 2 SiF 6 :Mn.
8. The lighting unit according to claim 1 , wherein the second source of red light comprises said second red luminescent material comprising a light converter nano particle material.
9. The lighting unit according to claim 1 , wherein the source of blue light comprises a blue light emitting diode.
10. The lighting unit according to claim 1 , wherein the source of green light comprises a luminescent material that is configured to convert at least part of the blue light of the source of blue light, and to convert said blue light into green light.
11. The lighting unit according to claim 1 , wherein the source of green light comprises a luminescent material comprising M 3 A 5 O 12 :Ce 3+ , wherein M is selected from the group consisting of Sc, Y, Tb, Gd, and Lu and wherein A is selected from the group consisting of Al and Ga.
12. The lighting unit according to claim 1 , wherein the source of green light comprises a LED with a centroid emission wavelength in the range of 510-540 nm.
13. The lighting unit according to claim 1 , wherein the source of blue light comprises a blue light emitting diode, wherein the source of green light comprises a LED with centroid emission wavelength in the range of 510-540 nm, wherein the first source of red light comprises the first red luminescent material, selected from the group consisting of (Mg,Ca,Sr,Ba)AlSiN 3 :Eu and (Ba,Sr,Ca) 2 Si 5-x Al x O x N 8-x :Eu, wherein x=0≦x≦4, and wherein the second source of red light comprises said second red luminescent material comprising K 2 SiF 6 :Mn.
14. An LCD display device comprising the lighting unit according to claim 1 configured as backlighting unit.
15. A combination of phosphors comprising a green luminescent material selected from the group consisting of a divalent europium containing oxynitride, a divalent europium containing thiogallate, a trivalent cerium containing nitride, a trivalent cerium containing oxynitride, and a trivalent cerium containing garnet, a first red luminescent material, selected from the group consisting of, (Mg,Ca,Sr,Ba)AlSiN 3 :Eu and (Ba,Sr,Ca) 2 Si 5-x Al x O x N 8-x :Eu, wherein 0≦x≦4, and a second red luminescent material selected from the group consisting of M 2 AQ 6 doped with tetravalent manganese, wherein M comprises monovalent cations, selected from the group consisting of Li, Na, K, Rb, Cs, NH 4 , wherein A 20 comprises a tetravalent cation selected from the group consisting of Si, Ti, Ge, Sn, and Zr, and wherein Q comprises a monovalent anion selected from the group consisting of F, Cl, Br and I, but at least comprising F.