Precursor of electrode active material coated with metal and method of preparing the same
View Patent ↗Disclosed are a precursor of an electrode active material for a lithium secondary battery, in which a metal material ionizable through electrolytic decomposition is uniformly coated on a surface of a primary precursor formed of a transition metal hydrate, and a method of preparing the same.
1. A method of preparing a precursor of an electrode material for a lithium secondary battery, comprising: preparing a primary precursor in the form of a hydrate; coating the primary precursor with a material through electrolytic decomposition; and drying the coated primary precursor, wherein the material is uniformly coated on a surface of the primary precursor, and the material comprises an electrolytically decomposable transition metal, P, or Al, wherein the electrolytically decomposable transition metal is at least one element selected from the group consisting of Ni, Co, Mn, Fe, Sn, Mo, Nd, Zr, and Zn; and wherein the primary precursor is represented by Formula 1 below:
M(OH 1−z ) 2 (1)
wherein 0.4<z<1; and M is Ni a Mn b Me c , wherein a+b≤1, 0.3≤a≤0.9, 0.1≤b≤0.8, and O≤c≤0.2; and Me is at least one element selected from the group consisting of Co, Al, Mg, Ti, Sr, Zn, B, Ca, Cr, Si, Ga, Sn, P, V, Sb, Nb, Ta, Mo, W, Zr, Y, and Fe.
2. The method according to claim 1 , wherein the coating is performed such that the material is ionized in an aqueous acid solution, forming an intermediate, followed by reduction.
3. The method of claim 2 , wherein the intermediate is a metal salt.
4. The method of claim 1 , wherein the metal salt is a sulfate or a nitrate.
5. The method of claim 1 , wherein the electrolytic decomposition is performed using a catalyst.
6. The method of claim 1 , wherein the catalyst is at least one selected from the group consisting of a ZnCl 2 -based catalyst, a CoCl 2 -based catalyst, a MnCl 2 -based catalyst, a NiCl 2 -based catalyst, and a SnCl 2 -based catalyst.
7. The method of claim 1 , wherein Me comprises Co.
8. The method of claim 1 , wherein the material has a coating thickness of 0.1 μm to 1 μm.
9. The method of claim 1 , wherein an amount of the material is 0.01% to 5% based on a total weight of the precursor.
10. The method of claim 1 , wherein the material is completely or partially coated on a surface of the primary precursor.