Cathode additives for lithium secondary battery with high capacity
View Patent ↗The present disclosure refers to a lithium secondary battery comprising Li 2 NiO 2 in a cathode active material so as to improve the phenomenon that the capacity retention ratio decreases at initial cycles when using an anode active material selected from the group consisting of Si, SiC, SiO x (0<x<2), Sn, SnO 2 , Sb, Ge and a mixture thereof. The lithium secondary battery according to the present disclosure can substantially improve the decrease of a capacity retention ratio during initial cycles.
1. A lithium secondary battery comprising a cathode containing a cathode active material, an anode containing an anode active material and a separator, wherein
the cathode active material contains
(1) a compound of Li 2 NiO 2 in an amount of 1 to 10 wt %, and
(2) a lithium-containing transition metal oxide other than the compound of Li 2 NiO 2 , and the anode active material contains
(1) a carbon-based material, and
(2) SiO x (0<x<2) in an amount of 10 to 15 wt %.
2. The lithium secondary battery of claim 1 , wherein the lithium-containing transition metal oxide other than the compound of Li 2 NiO 2 is any one selected from the group consisting of Li x CoO 2 (0.5<x<1.3), Li x NiO 2 (0.5<x<1.3), Li x MnO 2 (0.5<x<1.3), Li x Mn 2 O 4 (0.5<x<1.3), Li x (Ni a Co b Mn c )O 2 (0.5<x<1.3, 0<a<1, 0<b<1, 0<c<1, a+b+c=1), Li x Ni 1-y Co y O 2 (0.5<x<1.3, 0<y<1), Li x Co 1-y Mn y O 2 (0.5<x<1.3, 0≦y<1), Li x Ni 1-y Mn y O 2 (0.5<x<1.3, O≦y<1), Li x (Ni a Co b Mn c )O 4 (0.5<x<1.3, 0<a<2, 0<b<2, 0<c<2, a+b+c=2), Li x Mn 2-z Ni z O 4 (0.5<x<1.3, 0<z<2), Li x Mn 2-z Co z O 4 (0.5<x<1.3, 0<z<2), Li x CoPO 4 (0.5<x<1.3), Li x FePO 4 (0.5<x<1.3) and a mixture thereof.
3. The lithium secondary battery of claim 1 , wherein the carbon-based material is any one selected from the group consisting of soft carbon, hard carbon, natural graphite, kish graphite, pyrolytic carbon, mesophase pitch based carbon fiber, meso-carbon microbeads, Mesophase pitches, petroleum derived cokes, coal tar pitch derived cokes and a mixture thereof.
4. The lithium secondary battery of claim 1 , which has a capacity retention of 90% or more after 50 cycles.