Personal care composition for a keratin substrate comprising conditioning and/or styling polymer
View Patent ↗A personal care conditioning and/or styling composition for a keratin substrate comprising: (i) about 50 wt. % to 95 wt. % of at least one cationic or pseudo-cationic monomer selected from the group consisting of acrylamidopropyl trimethylammonium chloride (APTAC) and/or Vinylpyrrolidone (VP); (ii) about 1 wt. % to 30 wt. % of at least one anionic monomer selected from the group consisting of (a) acrylic acid (AA), (b) acrylamido methylpropyl sulfonate (AMPS), and/or (c) sodium methyl allyl sulfonate (SMAS); and (iii) about 0.1 wt. % to 20 wt. % of at least one hydrophobic monomer selected from the group consisting of (a) polyoxyethylene (PEG)-18-behenylether-methacrylate (BEM) (b) Lauryl-ethoxylated-methacrylate (LEM), (c) stearyl acrylate (SA), (d) Stream-10-allyl-ether, (e) Vinylcaprolactam (V-cap), and/or (f) Hydroxyethyl-pyrrolidone-methacrylate (M06). Also described is a process of preparing said polymer, and its method of use.
1. A conditioning and/or styling terpolymer for a keratin substrate obtained by polymerizing:
i. about 50 wt. % to 95 wt. % of acrylamidopropyl trimethylammonium chloride (APTAC), a cationic monomer;
ii. about 1 wt. % to 30 wt. % of acrylamido methylpropyl sulfonate (AMPS), an anionic second monomer; and
iii. about 0.1 wt. % to 20 wt. % polyoxyethylene (PEG)-18-behenylether methacrylate (BEM), a hydrophobic third
wherein said terpolymer has a cationic degree of substitution (Cat-DS) of greater than about 0.001 units, and wherein the cationic charge density is in the range of about 1 meq/g to about 6 meq/g.
2. The composition according to claim 1 , wherein the average molecular weight of said terpolymer is in the range of from about 100,000 to 1000,000 g/mol as determined by gel permeation chromatography.
3. The composition according to claim 1 , wherein the average molecular weight of said terpolymer ranges from about 200,000 to 500,000 g/mol as determined by gel permeation chromatography.
4. A conditioning and/or styling terpolymer for a keratin substrate obtained by polymerizing:
i. about 50 wt. % to 95 wt. % of acrylamidopropyl trimethylammonium chloride (APTAC);
ii. about 1 wt. % to 30 wt. % of acrylic acid (AA), an anionic monomer; and
iii. about 0.1 wt. % to 20 wt. % polyoxyethylene (PEG)-18-behenylether methacrylate (BEM);
wherein said terpolymer has a cationic degree of substitution (Cat-DS) of greater than about 0.001 units, and wherein the cationic charge density is in the range of about 1 meq/g to about 6 meq/g.
5. The composition according to claim 4 , wherein the average molecular weight of said terpolymer is in the range of from 100,000 to 100,000 g/mol as determined by gel permeation chromatography.
6. The composition according to claim 4 , wherein the average molecular weight of said terpolymer ranges from 200,000 to 500,000 g/mol as determined by gel permeation chromatography.