Aliphatic/semi-aromatic block copolyamide
View Patent ↗The invention relates to a method for the melted production, especially by reactive extrusion, of block copolyamide comprising at least one aliphatic polyamide block and at least one semi-aromatic block, especially wherein the aromatic group has at least one hydroxyl or sulfonate function. The invention also relates to the block copolyamide that can be produced by said method; to a composition comprising the block copolyamide; to granules comprising such a copolyamide or such a composition; to a method for producing an item from a copolyamide or a composition of said copolyamide; and to uses of the copolyamide.
1. A process for the melt preparation of a copolyamide comprising at least one aliphatic block originating from an aliphatic polyamide and at least one semi-aromatic block originating from a semi-aromatic polyamide, said process comprising:
mixing at least one aliphatic polyamide and at least one semi-aromatic polyamide,
wherein the semi-aromatic polyamide comprises repeating units originating from at least one aromatic diacid comprising a hydroxy and/or sulfonate function or repeating units originating from at least one aromatic diamine comprising a hydroxy and/or sulfonate function, said polyamides being terminated with functions that are capable of reacting together,
heating the mixture so that the polyamides are molten and a polycondensation reaction can take place between the polyamides,
recovering the copolyamide comprising the at least one aliphatic block and the at least one semi-aromatic block.
2. The process according to claim 1 , wherein the the polycondensation reaction takes place during extrusion.
3. The process according to claim 1 , wherein the duration of the polycondensation step is less than 30 minutes.
4. The process according to claim 1 , wherein the temperature at which the polycondensation step is performed ranges from the highest melting point to the highest melting point plus 80° C.
5. The process according to claim 1 , wherein the mixture comprises a polycondensation catalyst.
6. The process according to claim 1 , wherein the aliphatic polyamide comprises at least one repeating unit originating from an aliphatic diamine H 2 N—R 1 —NH 2 in which R 1 is an aliphatic radical comprising at least 2 carbon atoms.
7. The process according to claim 1 , wherein the aliphatic polyamide comprises at least one repeating unit originating from an aliphatic diacid HOOC—R 2 —COOH in which R 2 is an aliphatic radical comprising at least 2 carbon atoms.
8. The process according to claim 1 , wherein the aliphatic polyamide comprises repeating units originating from aliphatic amino acids.
9. The process according to claim 1 , wherein when the aliphatic polyamides have a GTC>GTA, the semi-aromatic polyamides have a GTA>GTC, or vice versa.
10. The process according to claim 1 , wherein the semi-aromatic polyamide comprises repeating units originating from 2-hydroxyterephthalic acid, 5-hydroxyisophthalic acid, 4-hydroxyisophthalic acid, 2,5-dihydroxyterephthalic acid, sodium 5-sulfoisophthalic, lithium 5-sulfoisophthalic acid, or potassium 5-sulfoisophthalic acid.
11. A semi-crystalline block copolyamide comprising at least one aliphatic block and at least one semi-aromatic block obtained via the process according to claim 1 .
12. The block copolyamide according to claim 11 , wherein the aliphatic block comprises repeating units originating from aliphatic diamines, aliphatic diacids and/or aliphatic amino acids, and/or the semi-aromatic block comprises repeating units originating from at least one aromatic diacid or at least one aromatic diamine.
13. The block copolyamide according to claim 11 , wherein the aliphatic polyamide blocks comprise on average at least 8 repeating units and/or the semi-aromatic polyamide blocks have a mean size of greater than or equal to 3 repeating units.
14. A composition comprising at least one copolyamide according to claim 11 .
15. A granule comprising at least one copolyamide according claim 11 .
16. A process for manufacturing an article, the process comprising molding a composition according to claim 14 .
17. An agent for increasing the difference in viscosity η of a polymer composition measured as a function of shear rate,
an agent for improving the impact strength of a polymer composition,
an agent for improving the impermeability of a polymer composition, and/or
an agent for improving the fatigue life of a polymer composition comprising the block copolymer according to claim 11 .