IP Library Granted Patent US 9,309,674
Granted Patent B2
US 9,309,674 · App. 14/446,213 · Granted Apr 12, 2016

Non-black rubber membranes

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Quick Facts
Patent No.
US 9,309,674
App. No.
14/446,213
Granted
Apr 12, 2016
Kind
B2
Abstract

A roofing membrane comprising an olefinic rubber; and from about 20 to about 250 parts by weight of a silica filler per 100 parts by weight rubber; wherein the silica filler is chemically coupled to the olefinic rubber; and wherein the roofing membrane is non-black.

Claims (16)

1. A process for preparing a roofing membrane, the method comprising:

i. mixing ethylene-propylene-diene rubber, silica, and a coupling agent defined by the formula:

where R 8 is a divalent organic group or a bond, R 9 is a halogen atom or an alkoxy group, and each R 10 is independently a halogen, an alkoxy group, or a monovalent organic group, and where R 11 is a blocking group to form a mixture, where the mixture is devoid of carbon black;

ii. adding a curative to the mixture to form a vulcanizable rubber composition;

iii. fabricating the vulcanizable composition into an uncured sheet; and

iv. curing the uncured sheet.

2. The process of claim 1 , further comprising the step of introducing ethylene-propylene-diene rubber with a coupling agent, where the coupling agent is dispersed in a carrier.

3. The process of claim 1 , where the curative is sulfur or a sulfur-containing compound.

4. The process of claim 3 , further comprising the step of adding a cure accelerator.

5. The process of claim 1 , where the coupling agent is a thioester, a thiophosphinate, a thiophosphate, or a thiosulphonate.

6. The process of claim 1 , where the mixture includes at least 30 and less than 120 parts by weight processing oil per 100 parts by weight rubber.

7. The process of claim 6 , where the processing oil has a sulfur content of less than 0.5 weight percent and an unsaturation level of less than 3%.

8. The process of claim 1 , where the vulcanizable composition includes:

i. an ethylene-propylene-diene rubber;

ii. from about 20 to about 250 parts by weight of a silica filler per 100 parts by weight rubber; and

iii. from about 0.1 to about 5 parts by weight of a silane coupling agent per 100 parts by weight rubber; wherein the silane coupling agent is compatible with both the ethylene-propylene-diene rubber and the silica filler such that the ethylene-propylene-diene rubber is chemically coupled to the silica filler.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 28, 2025
From: HOLCIM TECHNOLOGY LTD
To: AMRIZE TECHNOLOGY SWITZERLAND LLC
Reel/Frame 073030/0406 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2022
From: FIRESTONE BUILDING PRODUCTS COMPANY, LLC
To: HOLCIM TECHNOLOGY LTD
Reel/Frame 060920/0869 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 17, 2015
From: WANG, HAO; DAVIS, JAMES A.; BARHAM, WILLIAM F., JR
To: FIRESTONE BUILDING PRODUCTS CO.,LLC
Reel/Frame 036118/0196 →