Micronutrient-enhanced polymeric seed coatings
Improved, micronutrient-supplemented polymeric seed coatings are provided which include at least one polyanionic polymer in combination with respective amounts of Zn, Mn, and Cu micronutrients. Preferably, the coatings comprise polyanionic polymers having a backbone comprising dicarboxylic repeat units with Zn, Mn, and Cu bound to the backbone. The most preferred polymers contain maleic and itaconic repeat units, optionally with sulfonate repeat units. The invention also provides a method of treating seeds using the coatings, and coated seed products.
1. A water soluble coating composition for seeds, comprising a polymer having a backbone containing maleic, itaconic, and sulfonate repeat units and having micronutrients consisting of Zn, Mn, and Cu, wherein Zn, Mn, and Cu are the only micronutrients present in the coating composition, wherein said polymer comprises at least about 50% by mole repeat units containing at least one carboxylate group, wherein said polymer is in a partial Zn, Mn, Cu combined salt form, and wherein said coating composition has a polymer content of from about 35% to about 55% by weight based on the total weight of the coating composition.
2. The coating composition of claim 1 , said micronutrients being chemically bound to said polymer backbone.
3. The coating composition of claim 1 , said coating composition being an aqueous mixture containing said polymer.
4. The coating composition of claim 3 , said mixture having a pH of from about 3-8.
5. The coating composition of claim 4 , said mixture having a pH of from about 4-6.5.
6. The coating composition of claim 1 , said polymer having at least four different repeat units therein.
7. The coating composition of claim 1 , said polymer having at least 80 mole percent of repeat units including at least one anionic group.
8. A method of treating seeds comprising the step of coating seeds with the coating composition of claim 1 .
9. The method of claim 8 , said seeds are selected from the group consisting of wheat and corn.
10. A method of treating seeds comprising the step of coating seeds with the coating composition of claim 3 .
11. The method of claim 10 , said coating being applied by spraying the composition onto said seeds, or by dipping the seeds in the composition.
12. A seed product comprising a seed having on the surface thereof the coating composition of claim 1 .
13. The seed product of claim 12 , wherein said seed is selected from the group consisting of wheat and corn.
14. A water soluble coating composition for seeds, comprising a polymer composition including an anionic polymer comprising at least four repeat units distributed along a length of a polymer chain, said at least four repeat units including at least one each of a maleic, itaconic, and sulfonate repeat unit, and said composition having Zn, Mn, and Cu as the only micronutrients therein, wherein said polymer comprises at least about 50% by mole repeat units containing at least one carboxylate group, wherein said polymer is in a partial Zn, Mn, Cu combined salt form, and wherein said coating composition has a polymer content of from about 30% to about 60% by weight based on the total weight of the coating composition.
15. The coating composition of claim 14 , said micronutrients being chemically bound to the backbone of said polymer.
16. The coating composition of claim 14 , said composition being an aqueous mixture.
17. The coating composition of claim 16 , said aqueous mixture having a pH of from about 3-8.
18. A method of treating seeds comprising the step of coating said seeds with the coating composition of claim 14 .
19. A seed product comprising seeds having on the surface thereof the coating composition of claim 14 .
20. The seed product of claim 19 , said seeds selected from the group consisting of wheat and corn.
21. A method of controlling nematodes comprising the step of introducing a water soluble polymer into a region of nematode infestation, said polymer including a polymer backbone containing maleic, itaconic, and sulfonate repeat units and having Zn, Mn, and Cu as the only micronutrients therein, wherein said polymer comprises at least about 50% A by mole repeat units containing at least one carboxylate group, wherein said polymer is in a partial Zn, Mn, Cu combined salt form, and wherein said coating composition has a polymer content of from about 30% to about 60% by weight based on the total weight of the coating composition.
22. The method of claim 21 , said micronutrients being chemically bound to said polymer backbone.
23. The method of claim 21 , said polymer-introduction steps comprising the step of applying the polymer to the surfaces of seeds, and planting the seeds into said region.
24. The composition of claim 1 , said polymer having about 0.1%-12% by weight Zn, about 0.1%-7.5% Mn, and about 10-1500 ppm Cu present, wherein these percentages are based on the total weight of the polymer.
25. The composition of claim 1 , said sulfonate repeat units comprising allylsulfonic repeat units, methallylsulfonic repeat units, or a combination thereof.
26. The composition of claim 25 , said polymer having about 1-20 mole percent methallylsulfonic repeat units and about 0.1-10 mole percent allylsulfonic repeat units.
27. A coating composition for seeds, consisting of a polymer having a backbone containing maleic, itaconic, and sulfonate repeat units and having micronutrients consisting of Zn, Mn, and Cu, said polymer being in a Zn, Mn, and Cu combined partial salt form, and wherein said coating composition has a polymer content of from about 35% to about 55% by weight based on the total weight of the coating composition.
28. The composition of claim 1 , said polymer having two sulfonate repeat units.
29. The composition of claim 1 , said polymer having about 2%-6% by weight Zn, about 0.8-4.5% Mn, and about 100-1400 ppm Cu present, wherein these percentages are based on the total weight of the polymer.
30. The composition of claim 27 , said polymer having about 2%-6% by weight Zn, about 0.8-4.5% Mn, and about 100-1400 ppm Cu present, wherein these percentages are based on the total weight of the polymer.
31. The composition of claim 1 , wherein the polymer comprises about 20-55 mole percent maleic repeat units, about 35-65 mole percent itaconic repeat units and about 2-40 mole percent sulfonate repeat units.