Compositions and materials for electronic applications
View Patent ↗Embodiments disclosed herein relate to using cobalt (Co) to fine tune the magnetic properties, such as permeability and magnetic loss, of nickel-zinc ferrites to improve the material performance in electronic applications. The method comprises replacing nickel (Ni) with sufficient Co +2 such that the relaxation peak associated with the Co +2 substitution and the relaxation peak associated with the nickel to zinc (Ni/Zn) ratio are into near coincidence. When the relaxation peaks overlap, the material permeability can be substantially maximized and magnetic loss substantially minimized. The resulting materials are useful and provide superior performance particularly for devices operating at the 13.56 MHz ISM band.
1. An RF device comprising:
a composition represented by the formula
Ni 1-w-x-y-z Zn w Co x Mn y Cu z Fe 2-a O 4-1.5a ,
w being greater than or equal to 0.2 and less than or equal to 0.6;
x being greater than or equal to 0 and less than or equal to 0.2;
y being greater than or equal to 0 and less than or equal to 0.2;
z being greater than or equal to 0 and less than or equal to 0.2;
a being greater than or equal to 0 and less than or equal to 0.2; and
said RF device operates in the 13.56 MHz band.
2. The RF device of claim 1 wherein z=0 in the formula representing the composition.
3. The RF device of claim 1 wherein y=0 in the formula representing the composition.
4. An RF device comprising:
a composition represented by the formula
Ni 1-w-x-y-z Zn w Co x Mn y Cu z Fe 2-a O 4-1.5a ,
w being greater than or equal to 0.2 and less than or equal to 0.6;
x being greater than or equal to 0 and less than or equal to 0.2;
y being greater than or equal to 0 and less than or equal to 0.2;
z being greater than or equal to 0 and less than or equal to 0.2;
a being greater than or equal to 0 and less than or equal to 0.2; and
said RF device is an antenna.
5. The RF device of claim 4 wherein z=0 in the formula representing the composition.
6. The RF device of claim 4 wherein y=0 in the formula representing the composition.
7. An RF device comprising:
a modified nickel-zinc ferrite composition represented by the formula
Ni 1-x-y Zn x Co y Fe 2 O 4 ,
x being greater than or equal to 0.2 and less than 0.6, and y being greater than or equal zero and less than 0.2; and
said RF device is selected from the group consisting of RFID tags, biomedical sensors, and RF antennas.
8. An RF device comprising:
a modified nickel-zinc ferrite composition represented by the formula
Ni 1-x-y Zn x Co y Fe 2 O 4 ,
x being greater than or equal to 0.2 and less than 0.6, and y being greater than or equal zero and less than 0.2; and
said RF device operates in the 13.56 MHz band.