IP Library Granted Patent US 9,054,502
Granted Patent B1
US 9,054,502 · App. 14/452,802 · Granted Jun 9, 2015

Ceramic for ignition device insulator with low relative permittivity

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,054,502
App. No.
14/452,802
Granted
Jun 9, 2015
Kind
B1
Abstract

A ceramic insulator for surrounding an electrode of an ignition device, such as a corona igniter or spark plug, is provided. The insulator is formed of a ceramic material including alumina in an amount of 28 to 38 wt. %, silica in an amount of 57 to 67 wt. %, and calcium oxide in an amount of 3 to 7 wt. %, based on the total weight of the ceramic material. The ceramic insulator is typically formed by firing a mixture of Kaolin, calcium carbonate, and silica, wherein the calcium carbonate acts as a flux during firing. The ceramic material has a relative permittivity of about 5.5 to 6.5 and thus improves the electrical efficiency of the ignition device. The ceramic material is also capable of withstanding temperatures of 900 to 1000° C. and has excellent thermal shock resistance, making it suitable for use in internal combustion engines.

Claims (83)

1. An insulator for an ignition device, comprising:

a ceramic material including alumina in an amount of 28 to 38 wt. %, silica in an amount of 57 to 67 wt. %, and calcium oxide in an amount of 3 to 7 wt. %, based on the total weight of said ceramic material.

2. The insulator of claim 1 , wherein said ceramic material includes a mixture of calcium aluminosilicate glass and mullite crystals.

3. The insulator of claim 1 , wherein said alumina is present in an amount of 33 wt. %, said silica is present in an amount of 62 wt. %, and said calcium oxide is present in an amount of 5 wt. %, based on the total weight of said ceramic material.

4. The insulator of claim 1 , wherein said ceramic material has a relative permittivity of 5.5 to 6.5.

5. The insulator of claim 1 , wherein said ceramic material includes crystalline silica in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material.

6. The insulator of claim 1 , wherein said ceramic material includes alkalis in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material.

7. The insulator of claim 6 , wherein said alkalis include at least one of sodium, potassium, sodium oxide, and potassium oxide.

8. The insulator of claim 1 , wherein said alumina is present in an amount of 33 wt. %, said silica is present in an amount of 62 wt. %, and said calcium oxide is present in an amount of 5 wt. %, based on the total weight of said ceramic material;

said ceramic material includes a mixture of calcium aluminosilicate glass and mullite crystals;

said ceramic material has a relative permittivity of 5.5 to 6.5;

said ceramic material includes crystalline silica in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material;

said ceramic material includes alkalis in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material; and

wherein said insulator is produced by firing a mixture of Kaolin, calcined Kaolin, calcium carbonate, silica, calcium silicate, and/or calcium sulfate.

9. The insulator of claim 1 , wherein said insulator extends longitudinally along a center axis from an insulator upper end to an insulator nose end; and

said insulator presents an insulator inner surface surrounding a bore extending longitudinally from said insulator upper end to said insulator nose end for receiving a central electrode.

10. The insulator of claim 9 , wherein said alumina is present in an amount of 33 wt. %, said silica is present in an amount of 62 wt. %, and said calcium oxide is present in an amount of 5 wt. %, based on the total weight of said ceramic material;

said ceramic material includes a mixture of calcium aluminosilicate glass and mullite crystals;

said ceramic material has a relative permittivity of 5.5 to 6.5;

said ceramic material includes crystalline silica in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material;

said ceramic material includes alkalis in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material;

said insulator presents an insulator outer surface having an insulator outer diameter extending across and perpendicular to said center axis;

said insulator outer surface extends longitudinally from said insulator upper end to said insulator nose end;

said insulator outer diameter decreases along a portion of said insulator adjacent said insulator nose end and moving toward said insulator nose end to present an insulator nose region;

said insulator outer diameter decreases along a portion of said insulator spaced from said insulator nose region and moving toward said insulator nose end to present an insulator lower shoulder;

said insulator outer diameter decreases along a portion of said insulator moving toward said insulator upper end at a location spaced from said insulator lower shoulder to present an insulator upper shoulder;

said insulator inner surface presents an insulator inner diameter extending across and perpendicular to said center axis; and

said insulator inner diameter decreases along a portion of said insulator moving toward said insulator nose end for supporting said central electrode.

11. An ignition device including the insulator of claim 1 , and further comprising a central electrode extending from a terminal end to a firing end for igniting a fuel-air mixture; and

said insulator surrounding at least a portion of said central electrode.

12. The ignition device of claim 11 , wherein said ignition device is a corona igniter, and said central electrode includes a firing tip at said firing end for emitting a corona discharge.

13. The ignition device of claim 12 , wherein said alumina is present in an amount of 33 wt. %, said silica is present in an amount of 62 wt. %, and said calcium oxide is present in an amount of 5 wt. %, based on the total weight of said ceramic material after firing;

said ceramic material includes a mixture of calcium aluminosilicate glass, and mullite crystals;

said ceramic material has a relative permittivity of 5.5 to 6.5;

said ceramic material includes crystalline silica in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material;

said ceramic material includes alkalis in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material;

said insulator extends longitudinally along a center axis from an insulator upper end to an insulator nose end;

said insulator presents an insulator inner surface surrounding a bore extending longitudinally from said insulator upper end to said insulator nose end for receiving said central electrode;

said insulator inner surface presents an insulator inner diameter extending across and perpendicular to said center axis and decreasing along a portion of said insulator moving toward said insulator nose end for supporting a portion of said center electrode;

said insulator presents an insulator outer surface having an insulator outer diameter extending across and perpendicular to said center axis;

said insulator outer surface extends longitudinally from said insulator upper end to said insulator nose end;

said insulator outer diameter decreases along a portion of said insulator adjacent said insulator nose end and moving toward said insulator nose end to present an insulator nose region;

said insulator outer diameter decreases along a portion of said insulator spaced from said insulator nose region and moving toward said insulator nose end to present an insulator lower shoulder;

said insulator outer diameter decreases along a portion of said insulator moving toward said insulator upper end at a location spaced from said insulator lower shoulder to present an insulator upper shoulder;

said central electrode is formed of an electrically conductive material;

said central electrode has a length extending along said center axis from a terminal end to a firing end, wherein a majority of said length of said central electrode is surrounded by said insulator;

said firing tip of said central electrode includes a plurality of branches extending radially outwardly from said center axis for providing the corona discharge;

and further comprising:

a terminal disposed in said bore of said insulator and engaging said terminal end of said central electrode;

a seal disposed on said terminal end of said central electrode and around a portion of said terminal and filling a portion of said bore;

a shell formed of metal extending along said center axis from a shell upper end to a shell lower end and surrounding a portion of said insulator;

said shell upper end being disposed between said insulator upper shoulder and said insulator upper end and engaging said insulator; and

said shell lower end being disposed adjacent said insulator nose region such that at least a portion of said insulator nose region extends axially outwardly of said shell lower end.

14. The ignition device of claim 11 , wherein said ignition device is a spark plug and said central electrode includes a central firing surface at said firing end for emitting a spark.

15. The ignition device of claim 14 , wherein said alumina is present in an amount of 33 wt. %, said silica is present in an amount of 62 wt. %, and said calcium oxide is present in an amount of 5 wt. %, based on the total weight of said ceramic material after firing;

said ceramic material includes a mixture of calcium aluminosilicate glass and mullite crystals;

said ceramic material has a relative permittivity of 5.5 to 6.5;

said ceramic material includes crystalline silica in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material;

said ceramic material includes alkalis in an amount of 0 wt. % to 2 wt. %, based on the total weight of said ceramic material;

said insulator extends longitudinally along a center axis from an insulator upper end to an insulator nose end;

said insulator presents an insulator inner surface surrounding a bore extending longitudinally from said insulator upper end to said insulator nose end for receiving said central electrode;

said insulator inner surface presents an insulator inner diameter extending across and perpendicular to said center axis and decreasing along a portion of said insulator moving toward said insulator nose end for supporting a portion of said central electrode;

said insulator presents an insulator outer surface having an insulator outer diameter extending across and perpendicular to said center axis;

said insulator outer surface extends longitudinally from said insulator upper end to said insulator nose end;

said insulator outer diameter decreases along a portion of said insulator adjacent said insulator nose end and moving toward said insulator nose end to present an insulator nose region;

said insulator outer diameter decreases along a portion of said insulator spaced from said insulator nose region and moving toward said insulator nose end to present an insulator lower shoulder;

said insulator outer diameter decreases along a portion of said insulator moving toward said insulator upper end at a location spaced from said insulator lower shoulder to present an insulator upper shoulder;

said central electrode is formed of an electrically conductive material;

said central electrode has a length extending along said center axis from said terminal end to said firing end, wherein a majority of said length of said central electrode is surrounded by said insulator;

and further comprising:

a terminal disposed in said bore of said insulator and coupled to said terminal end of said central electrode;

a seal filling a portion of said bore of said insulator and coupling said terminal end of said central electrode and said terminal;

a shell formed of metal extending along said center axis from a shell upper end to a shell lower end and surrounding a portion of said insulator;

said shell upper end being disposed between said insulator upper shoulder and said insulator upper end and engaging said insulator;

said shell lower end being disposed adjacent said insulator nose region such that at least a portion of said insulator nose region extends axially outwardly of said shell lower end;

a ground electrode formed of an electrically conductive material and extending from said shell lower end toward said central electrode; and

said ground electrode including a ground firing surface facing said central firing surface to provide a spark gap between said firing surfaces.

16. A method of manufacturing an insulator for an ignition device, comprising the steps of:

firing a mixture of Kaolin and at least one of: a) calcium carbonate and silica; b) calcium silicate; and c) calcium sulfate and silica.

17. The method of claim 16 , wherein the firing step includes firing a mixture of Kaolin, calcium carbonate, and silica.

18. The method of claim 16 , wherein the firing step includes firing a mixture of Kaolin and calcium silicate.

19. The method of claim 16 , wherein the firing step includes firing a mixture of Kaolin, calcium sulfate, and silica.

20. The method of claim 16 , wherein the firing step includes forming a ceramic material including alumina in an amount of 28 to 38 wt. %, silica in an amount of 57 to 67 wt. %, and calcium oxide in an amount of 3 to 7 wt. %, based on the total weight of the ceramic material after firing.

Assignments (14)
PATENT SECURITY AGREEMENT (ABL) Recorded Apr 7, 2023
From: TENNECO INC.; DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 063268/0506 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 22, 2022
From: DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 061989/0689 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 056886/0455 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 058392/0274 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 22, 2019
From: FEDERAL-MOGUL IGNITION COMPANY
To: FEDERAL-MOGUL IGNITION LLC
Reel/Frame 049821/0536 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0771 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT AGREEMENT Recorded Apr 3, 2018
From: CITIBANK, N.A., AS COLLATERAL TRUSTEE
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0765 →