Biorenewable naphtha
View Patent ↗The present technology generally relates to a method for producing a naphtha product from a biorenewable feedstock. The method includes hydrotreating the biorenewable feedstock to produce a hydrocarbon product stream, hydrocracking hydrocarbons from the hydrocarbon product stream to produce a distribution of cracked hydrocarbons, and separating a biorenewable naphtha fraction from the distribution of cracked hydrocarbons.
1. A method comprising:
(a) hydrotreating a biorenewable feedstock to produce a hydrocarbon product stream;
(b) hydrocracking hydrocarbons from the hydrocarbon product stream of step (a) to produce a distribution of cracked hydrocarbons;
(c) separating a heavy fraction and a biorenewable naphtha fraction from the distribution of cracked hydrocarbons; and
(d) separating from the heavy fraction a middle distillate fraction;
wherein the hydrocracking step comprises a pressure falling in the range of about 1,000 psig to about 3,000 psig.
2. The method of claim 1 , further comprising recycling the heavy fraction remaining after step (d) to the hydrocracking step (b).
3. The method of claim 1 , further comprising isomerizing a C 5 /C 6 fraction of the biorenewable naphtha fraction.
4. The method of claim 1 , wherein the hydrotreating step comprises
a temperature falling in the range of about 300° F. to about 850° F.; and
a pressure falling in the range of about 300 psig to 3,000 psig.
5. The method of claim 1 , wherein the hydrotreating step comprises
a temperature falling in the range of about 550° F. to about 650° F.; and
a pressure falling in the range of about 1,000 psig to about 2,000 psig.
6. The method of claim 1 , wherein the hydrotreating step occurs in the presence of a catalyst comprising nickel-molybdenum, nickel-tungsten, or cobalt-molybdenum.
7. The method of claim 1 , wherein the hydrotreating step
occurs in the presence of a catalyst comprising nickel-molybdenum, nickel-tungsten, or cobalt-molybdenum; and
comprises
a temperature falling in the range of about 300° F. to about 850° F.; and
a pressure falling in the range of about 300 psig to 3,000 psig.
8. The method of claim 7 , wherein the hydrocarbon product stream has no detectable cracked products as determined by gas chromatography.
9. The method of claim 1 , wherein the hydrocracking step comprises
a temperature falling in the range of about 400° F. to about 900° F.
10. The method of claim 1 , wherein the hydrocracking step comprises
a temperature falling in the range of about 580° F. to about 750° F.; and
a pressure falling in the range of about 1,000 psig to about 2,000 psig.
11. The method of claim 1 , wherein the hydrocracking step occurs in the presence of a hydrocracking catalyst comprising a Group VIII metal on an amorphous or crystalline support.
12. The method of claim 11 , wherein the hydrocracking catalyst comprises palladium, platinum, or a combination thereof on an amorphous silica-alumina support.
13. The method of claim 1 , wherein the hydrocarbon product stream comprises n-paraffins falling in the C 15 to C 18 range.
14. The method of claim 1 , wherein the hydrocarbon product stream has no detectable cracked products as determined by gas chromatography.
15. The method of claim 1 , wherein the distribution of cracked hydrocarbons comprises hydrocarbons falling in the C 3 to C 18 range.
16. The method of claim 1 , wherein the biorenewable naphtha fraction comprises paraffins falling in the C 4 -C 10 range.
17. The method of claim 1 , wherein the biorenewable naphtha fraction comprises C 4 , C 5 , C 6 , C 7 , C 8 , C 9 , and C 10 paraffins.
18. The method of claim 1 , wherein the biorenewable naphtha fraction has a boiling point falling in the range of about 70° F. to about 400° F.; and a specific gravity at 20° C. falling in the range of about 0.680 to about 0.740.
19. The method of claim 1 , wherein the biorenewable feedstock comprises monoglycerides, diglycerides, triglycerides, free fatty acids, or combinations of any two or more thereof.
20. The method of claim 1 , wherein the biorenewable feedstock comprises animal fats, animal oils, poultry fat, poultry oil, vegetable fats, vegetable oils, rendered fats, rendered oils, restaurant grease, brown grease, waste industrial frying oils, fish oils, fish fats, or combinations thereof.
21. The method of claim 1 , wherein the biorenewable naphtha is suitable for use as a feedstock for a steam cracker, for use as an alternative gasoline fuel, or for producing a gasoline blend stock.