Organic light emitting display apparatus encapsulated with hydrophobic organic film and manufacturing method thereof

1. An organic light emitting display apparatus, comprising:

a substrate,

an organic light emitting unit on the substrate; and

a film encapsulation layer on the organic light emitting unit, wherein the film encapsulation layer comprises a hydrophobic organic layer disposed at an outermost portion of the film encapsulation layer,

wherein the hydrophobic organic layer is a fluorinated hybrid polymer organic film, and the fluorinated hybrid polymer organic film comprises, in atomic percent, 10 at % to 50 at % of fluorine atom F, 1 at % to 30 at % of silicon atom Si, 1 at % to 30 at % of oxygen atom O, and 15 at % to 50 at % of carbon atom C.

2. The organic light emitting display apparatus according to claim 1 , wherein a contact angle between the hydrophobic organic layer and water ranges from 90° to 170°.

3. The organic light emitting display apparatus according to claim 2 , wherein a contact angle between the hydrophobic organic layer and water ranges from 110° to 160°.

4. The organic light emitting display apparatus according to claim 1 , wherein the film encapsulation layer further comprises at least an inorganic blocking layer disposed between the organic light emitting unit and the hydrophobic organic layer.

5. The organic light emitting display apparatus according to claim 4 , wherein the film encapsulation layer comprises alternately overlapping one or more hydrophobic organic layers and one or more inorganic blocking layers.

6. The organic light emitting display apparatus according to claim 5 , wherein the film encapsulation layer comprises a plurality of layers, wherein each layer includes one hydrophobic organic layer and one inorganic blocking layer which are overlapped, and wherein the number of the layers is N, where 1≦N≦10, and N is a positive integer.

7. The organic light emitting display apparatus according to claim 6 , wherein the film encapsulation layer comprises a plurality of layers, wherein each layer includes one hydrophobic organic layer and one inorganic blocking layer which are overlapped, and the number of the layers is N, where 1≦N≦5, and N is a positive integer.

8. The organic light emitting display apparatus according to claim 1 , wherein the hydrophobic organic layer has a thickness in a range of 500 nm to 3000 nm.

9. The organic light emitting display apparatus according to claim 4 , wherein the inorganic blocking layer has a thickness in a range of 300 nm to 1000 nm.

10. The organic light emitting display apparatus according to claim 4 , wherein the film encapsulation layer has a thickness in a range of 0.5 μm to 10 μm.

11. The organic light emitting display apparatus according to claim 1 , wherein the hydrophobic organic layer is made from a precursor comprising fluorinated silane and silane.

12. The organic light emitting display apparatus according to claim 11 , wherein the hydrophobic organic layer is made from a precursor comprising heptadecafluorodecyl trimethoxysilane and tetramethoxysilane.

13. The organic light emitting display apparatus according to claim 11 , wherein the hydrophobic organic layer is formed with a plasma enhanced chemical vapor deposition method.

14. The organic light emitting display apparatus according to claim 4 , wherein the inorganic blocking layer comprises one or more of a metal oxide, a metal nitride, a silicon oxide, and a silicon nitride.

15. The organic light emitting display apparatus according to claim 14 , wherein the inorganic blocking layer is formed with an atomic layer deposition method, a plasma enhanced chemical vapor deposition method, or a physical vapor deposition method.

16. The organic light emitting display apparatus according to claim 4 , wherein the hydrophobic organic layer has a thickness larger than that of the inorganic blocking layer.

17. The organic light emitting display apparatus according to claim 4 , wherein the hydrophobic organic layer and the inorganic blocking layer are formed by a same deposition method.

18. The organic light emitting display apparatus according to claim 1 , wherein the hydrophobic organic layer comprising hydrophobic organic material having C—F bond, Si—C bond, Si—O—Si bonds and C—H bond.