Lithium secondary battery with excellent performance
View Patent ↗Disclosed is a lithium secondary battery including an electrode assembly including a cathode, an anode, and a separator disposed between the cathode and the anode and an electrolyte, wherein the cathode includes a spinel-structure lithium manganese composite oxide represented by Formula 1 below as a cathode active material, and the lithium secondary battery has a charge cut-off voltage of 3.3 to 4 V and, when the charge cut-off voltage is reached, the anode has a potential of 0.75 to 1.545 V within a range within which a potential of the cathode does not exceed 4.95 V: Li x M y Mn 2−y O 4−z A z (1) wherein 0.9≦x≦1.2, 0<y<2, and 0≦z<0.2; M is at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, Ti, and Bi; and A is at least one monovalent or divalent anion.
1. A lithium secondary battery comprising: an electrode assembly comprising a cathode, an anode, and a separator disposed between the cathode and the anode; and an electrolyte, wherein the capacity of the anode is 80 to 100% the capacity of the cathode,
wherein the cathode comprises a spinel-structure lithium manganese composite oxide represented by Formula 1 below as a cathode active material, and
the lithium secondary battery has a charge cut-off voltage of 3.3 to 4 V and, when the charge cut-off voltage is reached, the anode has a potential of 0.75 to 1.545 V within a range within which a potential of the cathode does not exceed 4.95 V:
Li x M y Mn2− y O4− z A z (1)
wherein 0.9≦x≦1.2, 0<y<2, and 0≦z<0.2;
M is at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, Ti, and Bi; and
A is at least one monovalent or divalent anion.
2. The lithium secondary battery according to claim 1 , wherein the charge cut-off voltage of the lithium secondary battery is in a range of 3.3 to 3.5 V and, when the cut-off voltage is reached, the anode has a potential of 1.2 to 1.545 V within a range within which the potential of the cathode does not exceed 4.95 V.
3. The lithium secondary battery according to claim 1 , wherein the lithium manganese composite oxide of Formula 1 is a lithium nickel manganese complex oxide represented by Formula 2 below:
Li x Ni y Mn2− y O4 (2)
wherein 0.9≦x≦1.2 and 0.4≦y≦0.5.
4. The lithium secondary battery according to claim 3 , wherein the lithium nickel manganese complex oxide is LiNi0.5Mn1.5O4 or LiNi0.4Mn1.6O4.
5. The lithium secondary battery according to claim 1 , wherein the anode comprises, as an anode active material, a lithium metal oxide represented by Formula 3 below:
Li a M′ b O4− c A c (3)
wherein M′ is at least one element selected from the group consisting of Ti, Sn, Cu, Pb, Sb, Zn, Fe, In, Al, and Zr;
0.1≦a≦4 and 0.2≦b≦4 wherein a and b are determined according to oxidation number of M′;
0≦c<0.2 wherein c is determined according to oxidation number of A; and
A is at least one monovalent or divalent anion.
6. The lithium secondary battery according to claim 5 , wherein the lithium metal oxide of Formula 3 is a lithium titanium oxide (LTO) represented by Formula 4 below:
Li a Ti b O4 (4)
wherein 0.5≦a≦3 and 1≦b≦2.5.
7. The lithium secondary battery according to claim 6 , wherein the LTO is Li1.33Ti1.67O4 or LiTi2O4.
8. The lithium secondary battery according to claim 1 , wherein the electrode assembly is a stack-type electrode assembly, a jelly-roll type electrode assembly, or a stack/folding type electrode assembly fabricated by positioning, on a separator film, unit cells comprising cathodes, anodes, and separators and winding the separator film with the unit cells positioned thereon.
9. The lithium secondary battery according to claim 8 , wherein electrodes at outermost sides of the stack-type electrode assembly or stack/folding type electrode assembly are double-sided coated.
10. The lithium secondary battery according to claim 8 , wherein electrodes at outermost sides of the stack-type electrode assembly or stack/folding type electrode assembly are single-sided coated.
11. The lithium secondary battery according to claim 8 , wherein the stack-type electrode assembly or stack/folding type electrode assembly comprises, at outermost sides thereof, A-type bicells, each A-type bicell having a structure of cathode/separator/anode/separator/cathode.
12. The lithium secondary battery according to claim 1 , wherein the potential of the anode is lower than or identical to the capacity of the cathode.
13. The lithium secondary battery according to claim 12 , wherein the capacity of the anode is 80 to 100% the capacity of the cathode.
14. The lithium secondary battery according to claim 13 , wherein a total capacity of anodes constituting the electrode assembly is 90 to 100% a total capacity of cathodes constituting the electrode assembly.
15. A battery module comprising the lithium secondary battery according to claim 1 as a unit battery.
16. A battery pack comprising the battery module according to claim 15 .
17. A device comprising the battery pack according to claim 16 .
18. The device according to claim 17 , wherein the device is an electric vehicle, a hybrid electric vehicle, a plug-in hybrid electric vehicle, or a system for storing power.