Metal-resin composite and method for producing the same
A metal-resin composite and method for producing the same are provided. The method comprises: A) forming nanopores in at least a part of a surface of a metal sheet; and B) injection molding a thermoplastic resin directly on the surface of the metal sheet. The thermoplastic resin includes a main resin and a polyolefin resin. The main resin includes a mixture of polyphenylene ether and polyphenylene sulfide. And the polyolefin resin has a melting point of about 65° C. to about 105° C.
1. A method for producing a composite of a metal and a resin, comprising:
A) forming nanopores on at least a part of a surface of a metal sheet; and
B) injection molding a thermoplastic resin directly on the surface of the metal sheet, wherein the thermoplastic resin includes a main resin and a polyolefin resin, the main resin includes a mixture of polyphenylene ether and polyphenylene sulfide, and the polyolefin resin has a melting point of about 65° C. to about 105° C.,
wherein forming the nanopores comprises anodizing at least a part of the surface of the metal sheet to form an oxide layer having the nanopores thereon, and immersing the metal sheet having the oxide layer on the surface thereof in an etching solution to form corrosion pores on an outer surface of the oxide layer to form a double-layer pore structure including the corrosion pores having diameters of about 200 nm to about 2000 nm and the nanopores having an average diameter of about 10 nm to about 100 nm, wherein the corrosion pores are in communication with the nanopores.
2. The method according to claim 1 , wherein the oxide layer has a thickness of about 1 μm to about 10 μm, and the nanopores have an average depth of about 0.5 μm to about 9.5 μm.
3. The method according to claim 1 , wherein the anodizing comprises:
placing the metal sheet as an anode in a H 2 SO 4 solution with a concentration of about 10 wt % to about 30 wt %; and
electrolyzing the metal sheet at a temperature of about 10° C. to about 30° C. at a voltage of about 10V to about 100V for about 1 minute to about 40 minutes to form the oxide layer with a thickness of about 1 μm to about 10 μm on at least a part of the surface of the metal sheet.
4. The method according to claim 1 , wherein the corrosion pores have depths of about 0.5 μm to about 9.5 μm.
5. The method according to claim 1 , wherein the etching solution corrodes the oxide layer.
6. The method according to claim 1 , wherein based on 100 weight parts of the thermoplastic resin, the amount of the main resin is about 70 weight parts to about 95 weight parts, and the amount of the polyolefin resin is about 5 weight part to about 30 weight parts.
7. The method according to claim 6 , wherein the thermoplastic resin further includes a flow improver, and based on 100 weight parts of the thermoplastic resin, the amount of the flow improver is about 1 weight part to about 5 weight parts, and wherein the flow improver includes a cyclic polyester.
8. The method according to claim 6 , wherein the thermoplastic resin further includes a fiberglass, and based on 100 weight parts of the thermoplastic resin, the amount of the fiberglass is about 1 weight part to about 30 weight parts.
9. The method according to claim 1 , wherein the weight ratio of polyphenylene ether and polyphenylene sulfide in the main resin is about 3:1 to about 1:3.
10. The method according to claim 1 , wherein the polyolefin resin includes a grafted polyethylene.
11. The method according to claim 1 , wherein the metal sheet includes at least one selected from a group of aluminum, stainless steel and magnesium.
12. A method for producing a composite of a metal and a resin, comprising:
A) forming nanopores on at least a part of a surface of a metal sheet by anodizing at least the part of the surface of the metal sheet to form an oxide layer having the nanopores thereon;
B) immersing the metal sheet having the oxide layer on the surface thereof in an etching solution to form corrosion pores on an outer surface of the oxide layer; and
C) injection molding a thermoplastic resin directly on the oxide layer of the metal sheet, wherein the thermoplastic resin includes a main resin and a polyolefin resin, the main resin includes a mixture of polyphenylene ether and polyphenylene sulfide, and the polyolefin resin has a melting point of about 65° C. to about 105° C.,
wherein the nanopores and the corrosion pores form a double-layer pore structure, the nanopores have an average diameter of about 10 nm to about 100 nm and the corrosion pores have an average diameter of about 200 nm to about 2000 nm, wherein the corrosion pores are in communication with the nanopores.