Reinforced electrolyte membrane and process for producing same
View Patent ↗A reinforced electrolyte membrane having an electrolyte membrane containing a fluoropolymer having ion exchange groups, reinforced by a woven fabric made of a reinforcing thread and a sacrificial thread, where the sacrificial thread remains in the electrolyte membrane, a void is formed between the sacrificial thread and the electrolyte membrane, and 2000 μm 2 <A<6000 μm 2 and 0.3≦B/A<1.0 are satisfied, where A is the total of a cross-sectional area of the sacrificial thread and a cross-sectional area of the void, and B is the cross-sectional area of the sacrificial thread.
1. A reinforced electrolyte membrane having an electrolyte membrane comprising a fluoropolymer having ion exchange groups, reinforced by a woven fabric comprising a reinforcing thread and a sacrificial thread, wherein
the sacrificial thread remains in the electrolyte membrane,
a void is formed between the sacrificial thread and the electrolyte membrane, and
the following formulae (1) and (2) are satisfied, wherein A is the total of a cross-sectional area of the sacrificial thread and a cross-sectional area of the void, and B is the cross-sectional area of the sacrificial thread:
2000 μm 2 <A< 6000 μm 2 (1)
0.3≦ B/A< 1.0 (2).
2. The reinforced electrolyte membrane according to claim 1 , wherein the following formula (1′) is satisfied:
2000 μm 2 <A< 4000 μm 2 (1′).
3. The reinforced electrolyte membrane according to claim 1 , wherein the sacrificial thread is a thread comprising at least one member selected from the group consisting of polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, rayon and cellulose.
4. The reinforced electrolyte membrane according to claim 1 , wherein the sacrificial thread is a thread of polyethylene terephthalate.
5. The reinforced electrolyte membrane according to claim 1 , wherein the sacrificial thread is a thread comprising a mixture of polyethylene terephthalate and polybutylene terephthalate.
6. The reinforced electrolyte membrane according to claim 1 , wherein the sacrificial thread is a thread of polybutylene terephthalate.
7. The reinforced electrolyte membrane according to claim 1 , wherein the sacrificial thread is a thread of polytrimethylene terephthalate.
8. A process for producing the reinforced electrolyte membrane according to claim 1 , comprising:
bringing a reinforced precursor membrane having a precursor membrane comprising a fluoropolymer having precursor groups for the ion exchange groups reinforced by a woven fabric comprising a reinforcing thread and a sacrificial thread, into contact with an alkaline aqueous solution, thereby hydrolyzing and converting the precursor groups into the ion exchange groups to produce the reinforced electrolyte membrane.
9. The process for producing a reinforced electrolyte membrane according to claim 8 , wherein, at the time of bringing the reinforced precursor membrane into contact with an alkaline aqueous solution, only a part of the sacrificial thread is hydrolyzed and eluted in the alkaline aqueous solution so as to satisfy formula (2).