IP Library Granted Patent US 9,299,933
Granted Patent B2
US 9,299,933 · App. 14/467,503 · Granted Mar 29, 2016

Polymer and organic electroluminescent element

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,299,933
App. No.
14/467,503
Granted
Mar 29, 2016
Kind
B2
Abstract

The present invention relates to a polymer comprising a repeating unit containing a specific partial structure and a repeating unit containing a crosslinking group, a composition for an organic electroluminescent element comprising the polymer, and an organic electroluminescent element comprising an organic layer formed using the composition for an organic electroluminescent element by a wet film formation method.

Claims (39)

1. A polymer, comprising:

a repeating unit having a partial structure represented by formula (1):

and

a repeating unit having a crosslinking group,

wherein, in formula (1):

Ar 1 , Ar 3 , Ar 4 , and Ar 5 each independently represent an aromatic hydrocarbon-cyclic group optionally having a substituent or an aromatic heterocyclic group optionally having a substituent;

Ar 2 represents an aromatic hydrocarbon-cyclic group optionally having a substituent, or an aromatic heterocyclic group optionally having a substituent;

R 1 represents an alkyl group optionally having a substituent, or an alkoxy group optionally having a substituent;

R 2 to R 7 each independently represent a hydrogen atom, an alkyl group optionally having a substituent, an alkoxy group optionally having a substituent, an aromatic hydrocarbon-cyclic group optionally having a substituent, or an aromatic heterocyclic group optionally having a substituent, wherein R 2 and R 3 may bond to each other to form a ring, R 4 and R 5 may bond to each other to form a ring, and R 6 and R 7 may bond to each other to form a ring;

l, m, and n each independently indicate an integer of from 0 to 2; and

multiple Ar 1 to Ar 5 or R 2 to R 7 may be the same or different.

2. The polymer according to claim 1 , wherein in the formula (1), at least one of l, m, and n is an integer differing from the others.

3. The polymer according to claim 1 , further comprising:

a repeating unit having a partial structure of formula (2):

wherein, in formula (2):

Ar 6 and Ar 7 each independently represent an aromatic hydrocarbon-cyclic group optionally having a substituent, or an aromatic heterocyclic group optionally having a substituent;

Ar 8 represents an aromatic hydrocarbon-cyclic group optionally having a substituent, or an aromatic heterocyclic group optionally having a substituent;

R 8 and R 9 each independently represent a hydrogen atom, an alkyl group optionally having a substituent, an alkoxy group optionally having a substituent, an aromatic hydrocarbon-cyclic group optionally having a substituent, or an aromatic heterocyclic group optionally having a substituent;

R 8 and R 9 may bond to each other to form a ring;

p indicates an integer of from 0 to 2; and

multiple substituents of at least one of R 8 , R 9 , and Ar 7 may be the same or different.

4. The polymer according to claim 1 , wherein the crosslinking group is at least one group selected from crosslinking groups of the following formulae:

wherein:

R 21 to R 23 each independently represent a hydrogen atom, or an alkyl group optionally having a substituent;

A 10 represents an aromatic hydrocarbon-cyclic group optionally having a substituent, or an aromatic heterocyclic group optionally having a substituent; and

when multiple crosslinking groups and multiple R 21 to R 23 and Ar 10 are present, the multiple R 21 to R 23 and Ar 10 may be the same or different.

5. The polymer according to claim 1 , wherein the weight-average molecular weight (Mw) of the polymer is 20,000 or more, and the degree of dispersion (Mw/Mn, where Mn indicates the number-average molecular weight of the polymer) is 2.5 or less.

6. A material for organic electroluminescent element, comprising the polymer according to claim 1 .

7. A composition for organic electroluminescent element, comprising the polymer according to claim 1 .

8. An organic electroluminescent element, comprising:

a substrate;

an anode and a cathode on the substrate; and

an organic layer between the anode and the cathode,

wherein the organic layer contains a layer formed according to a wet film formation method using the composition for organic electroluminescent elements according to claim 7 .

9. The organic electroluminescent element according to claim 8 , wherein the layer formed according to a wet film formation method is at least one of a hole injection layer and a hole transport layer.

10. The organic electroluminescent element according to claim 9 , wherein the organic layer includes a hole injection layer, a hole transport layer, and a light-emitting layer, and

wherein all of the hole injection layer, the hole transport layer and the light-emitting layer are a layer formed according to a wet film formation method.

11. An organic EL display device, comprising the organic electroluminescent element according to claim 8 .

12. An organic EL lighting device, comprising the organic electroluminescent element according to claim 8 .

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2014
From: BABA, TATSUSHI; LI, YANJUN; IIDA, KOICHIRO; GOROHMARU, HIDEKI; NAKAMOTO, EMI; SHOUDA, TAKAYUKI
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 034095/0944 →