Protected Fischer-Tropsch catalyst and method of providing same to a Fischer-Tropsch process
A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.
1. A system for activating a Fischer-Tropsch catalyst, the system comprising:
an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst, wherein said activation reactor does not contain a liquid medium; and
at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.
2. The system of claim 1 wherein the activation reactor is a fluidized bed reactor.
3. The system of claim 1 wherein the cutoff size is about 10 μm.
4. The system of claim 1 wherein at least one of the at least one separation devices is located at least partially within the activation reactor.
5. The system of claim 4 wherein the at least one separation device located at least partially within the activation reactor is selected from cyclones and filters.
6. The system of claim 5 comprising a cyclone at least partially within the activation reactor.
7. The system of claim 6 further comprising a filtration unit external to the activation reactor, the filtration unit comprising an inlet for the gas stream comprising entrained catalyst fines and configured to separate the catalyst fines from an effluent gas comprising reducing gas.
8. The system of claim 7 further comprising a dessicant vessel downstream the filtration unit and configured to remove water from the effluent gas, providing a dried effluent gas.
9. The system of claim 8 further comprising a recycle line fluidly connecting the dessicant vessel with the activation vessel, whereby dried effluent gas may be recycled.
10. The system of claim 5 comprising a filtration unit at least partially within the activation vessel.
11. The system of claim 10 further comprising a knock out vessel comprising an inlet for the gas stream comprising entrained catalyst fines and configured to separate the catalyst fines, water, or both from an effluent gas comprising reducing gas.
12. The system of claim 11 further comprising a dessicant vessel downstream the knock out vessel and configured to remove water from the effluent gas, providing a dried effluent gas.
13. The system of claim 12 further comprising a recycle line fluidly connecting the dessicant vessel with the activation vessel, whereby dried effluent gas may be recycled.
14. The system of claim 1 wherein the Fischer-Tropsch catalyst is a precipitated iron-based catalyst.
15. The system of claim 1 wherein the Fischer-Tropsch catalyst has an average particle diameter in the range of from about 0.5 μm to about 200 μm.