Binder for storage battery device
View Patent ↗To provide a binder for a storage battery device, whereby good adhesion in an electrode and flexibility are obtainable, and it is possible to realize good charge and discharge characteristics when used for a secondary battery. A binder for a storage battery device, which is made of a fluorinated copolymer comprising structural units (a) derived from tetrafluoroethylene and structural units (b) derived from propylene, wherein the molar ratio (a)/(b) is from 40/60 to 50/50, and the total of the structural units (a) and (b) is at least 90 mol % in all structural units.
1. A binder composition for a storage battery device, comprising:
a binder which comprises a fluorinated copolymer comprising structural units (a) derived from tetrafluoroethylene and structural units (b) derived from propylene, wherein the molar ratio (a)/(b) is from 40/60 to 48/52, and the total of the structural units (a) and the structural units (b) is at least 90 mol % with respect to all structural units included in the binder; and
a medium,
wherein the medium is an aqueous medium, and particles made of the fluorinated copolymer are dispersed in the aqueous medium, and the average particle size of the particles made of the fluorinated copolymer is from 10 to 200 nm.
2. The binder composition according to claim 1 , wherein the Mooney viscosity of the fluorinated copolymer is from 5 to 200.
3. The binder composition according to claim 1 , wherein the content of the fluorinated copolymer is from 5 to 60 mass %.
4. The binder composition according to claim 1 , wherein the binder composition is in a state of a latex.
5. An electrode mixture, comprising the binder composition as defined in claim 1 and an electrode active material.
6. An electrode, comprising a current collector and an electrode active material layer formed on the current collector, wherein the electrode active material layer comprises the binder composition as defined in claim 1 and an electrode active material.
7. A secondary battery comprising the electrode as defined in claim 6 and an electrolytic solution.
8. The secondary battery according to claim 7 , wherein the secondary battery is a wound secondary battery.
9. The binder composition according to claim 1 , further comprising an anionic emulsifier.
10. The binder composition according to claim 9 , wherein an amount of the anionic emulsifier is 1.5 to 5.0 weight parts by mass based on 100 parts by mass of the fluorinated copolymer.