Polymer powder with polyamide, use in a shaping process, and moldings produced from this polymer powder
View Patent ↗The present invention relates to a polymer powder which comprises nylon-11, and to the use of this powder for shaping processes, and also to moldings produced from this polymer powder. The moldings constructed using the inventive powder exhibit marked advantages in terms of component properties, particularly surface finish. There are also improvements here in processing and in recycling capability when comparison is made with conventional polyamide powders.
1. A polymer powder for use in a layer-by-layer process in which regions of a respective pulverulent layer are selectively melted via introduction of electromagnetic energy,
wherein the polymer powder comprises at least one nylon-11 having an enthalpy of fusion of at least 125 J/g and a recrystallization temperature of at least 148° C., and wherein the polymer powder has a BET surface area smaller than 6 m 2 /g and a median grain diameter of from 40 to 120 μm.
2. The polymer powder of claim 1 , which comprises at least one nylon-11 having an enthalpy of fusion of at least 130 J/g and a recrystallization temperature of at least 150° C.
3. The polymer powder of claim 1 , which has a BET surface area smaller than 5 m 2 /g and a median grain diameter of from 45 to 100 μm.
4. The polymer powder of claim 1 , which has a BET surface area smaller than 5 m 2 /g and a median grain diameter of from 50 to 70 μm.
5. The polymer powder of claim 1 , wherein the selectivity is achieved by application of at least one component selected from the group consisting of a susceptor, inhibitor, absorber, and mask,
wherein the polymer powder has a BET surface area smaller than 5 m 2 /g and a median grain diameter of from 50 to 70 μm.
6. The polymer powder of claim 1 , wherein the selectivity is achieved by focusing a laser beam,
wherein the polymer powder has a BET surface area smaller than 5 m 2 /g and a median grain diameter of from 50 to 70 μm.
7. The polymer powder of claim 1 , which comprises at least nylon-11 prepared by polycondensation of at least one one ω-aminoundecanoic acid.
8. The polymer powder of claim 1 , wherein the polymer powder has been obtained by precipitative crystallization.
9. The polymer powder of claim 1 , which comprises an unregulated nylon-11.
10. The polymer powder of claim 1 , which comprises nylon-11 regulated by a regulator.
11. The polymer powder of claim 10 , wherein the regulator comprises a monoamine, diamine or polyamine.
12. The polymer powder of claim 1 , wherein the polymer powder is a polyamide powder having a solution viscosity of from 1.4 to 2.1.
13. The polymer powder of claim 1 , wherein the polymer powder is a polyamide powder having a solution viscosity of from 1.5 to 1.9.
14. The polymer powder of claim 1 , wherein the polymer powder is a polyamide powder having a solution viscosity of from 1.6 to 1.7.
15. The polymer powder of claim 10 , wherein the regulator comprises a monocarboxylic acid, dicarboxylic acid or polycarboxylic acid.
16. The polymer powder of claim 1 , which comprises nylon-11 partially regulated by a regulator.
17. The polymer powder of claim 1 , which further comprises an auxiliary, filler, or a mixture thereof.
18. The polymer powder of claim 17 , which comprises a powder-flow aid as the auxiliary.
19. The polymer powder of claim 17 , which comprises glass particles as the filler.
20. The polymer powder of claim 17 , which comprises a metal soap as the auxiliary.
21. The polymer powder of claim 1 , further comprising an organic, an inorganic pigment, or a mixture thereof.
22. The polymer powder of claim 21 , which comprises a carbon black.
23. The polymer powder of claim 21 , which comprises a titanium dioxide.