Fluorinated elastomer composition and method for its production, molded product, cross-linked product, and covered electric wire
View Patent ↗To provide a fluorinated elastomer composition which is excellent in flexibility and oil resistance to lubricant oil such as automatic transmission oil, is less susceptible to heat discoloration and is excellent also in moldability, and a molded product, cross-linked product and covered electric wire, using such a fluorinated elastomer composition. A fluorinated elastomer composition comprising a tetrafluoroethylene/propylene copolymer (a), an ethylene/tetrafluoroethylene copolymer (b) and an ethylene copolymer (c) containing epoxy groups, wherein the mass ratio [(a)/(b)] of the tetrafluoroethylene/propylene copolymer (a) to the ethylene/tetrafluoroethylene copolymer (b) is from 70/30 to 40/60, and the mass ratio [(b)/(c)] of the ethylene/tetrafluoroethylene copolymer (b) to the ethylene copolymer (c) containing epoxy groups is from 100/0.1 to 100/10.
1. A fluorinated elastomer composition comprising the following tetrafluoroethylene/propylene copolymer (a), the following ethylene/tetrafluoroethylene copolymer (b) and an ethylene copolymer (c) containing epoxy groups, wherein the mass ratio [(a)/(b)] of the tetrafluoroethylene/propylene copolymer (a) to the ethylene/tetrafluoroethylene copolymer (b) is from 70/30 to 40/60, and the mass ratio [(b)/(c)] of the ethylene/tetrafluoroethylene copolymer (b) to the ethylene copolymer (c) containing epoxy groups is from 100/0.1 to 100/10,
tetrafluoroethylene/propylene copolymer (a): a copolymer comprising from 45 to 70 mol % of units derived from tetrafluoroethylene, from 30 to 55 mol % of units derived from propylene, and from 0 to 20 mol % of units derived from other monomer, and
ethylene/tetrafluoroethylene copolymer (b): a copolymer comprising from 45 to 70 mol % of units derived from tetrafluoroethylene, from 30 to 55 mol % of units derived from ethylene, and from 0 to 20 mol % of units derived from other monomer.
2. The fluorinated elastomer composition according to claim 1 , which has a melt flow rate of from 4 to 50 g/10 min. as measured at a temperature of 297° C.
3. The fluorinated elastomer composition according to claim 1 , wherein the ethylene/tetrafluoroethylene copolymer (b) is a copolymer comprising units derived from tetrafluoroethylene, units derived from ethylene, and units derived from CF 3 CF 2 CF 2 CF 2 CF═CH 2 or CF 3 CF 2 CF 2 CF 2 CF 2 CF 2 CH═CH 2 .
4. The fluorinated elastomer composition according to claim 1 , wherein the ethylene copolymer (c) containing epoxy groups is a copolymer comprising units derived from ethylene, units derived from glycidyl methacrylate and units derived from an ethylene unsaturated ester.
5. A method for producing a fluorinated elastomer composition as defined in claim 1 , which comprises a step of kneading the tetrafluoroethylene/propylene copolymer (a), the ethylene/tetrafluoroethylene copolymer (b) and the ethylene copolymer (c) containing epoxy groups under a heating condition of from 250 to 320° C.
6. The method for producing a fluorinated elastomer composition according to claim 5 , wherein the step of kneading is a step of kneading for from 1 to 30 minutes by means of an extruder.
7. A molded product obtained by molding the fluorinated elastomer composition as defined in claim 1 .
8. Across-linked product obtained by cross-linking the fluorinated elastomer composition as defined in claim 1 .
9. A covered electric wire comprising a conductor and a covering material for covering the conductor, wherein the covering material is the fluorinated elastomer composition as defined in claim 1 .
10. A covered electric wire comprising a conductor and a covering material for covering the conductor, wherein the covering material is the cross-linked product as defined in claim 8 .