Metal oxide particles aftertreated with organic phosphorus compounds
The invention relates to metal oxide particles and/or metal hydroxide particles, aftertreated with an organic phosphorus compound, process for the preparation thereof, and compositions comprising same.
1. A method for the stabilization of a cosmetic composition comprising a cosmetically suitable carrier and/or at least one cosmetic adjuvant and dihydroxyacetone or a derivative of dihydroxyacetone, the method comprising adding to the cosmetic composition metal oxide particles and/or metal hydroxide particles having a primary particle size according to the Scherrer method in the range from 5 nm to 100 nm, wherein said particles have been treated with an organic phosphorus compound selected from: hydroxyalkyldiphosphonic acids; alkylphosphonic acids, which may be substituted by at least one COOH group; aminoalkylenephosphonic acids; or organic phosphoric acid esters or salts thereof.
2. The method of claim 1 , wherein the particles have been treated with an organic phosphorus compound selected from phosphoric acid monoalkyl esters or salts thereof.
3. The method of claim 1 , wherein the organic phosphorus compound is applied to the particles in an amount of 5 to 20 per cent by weight.
4. The method of claim 1 , wherein the metal oxide and/or hydroxide for the particles is selected from the oxides and hydroxides of silicon, titanium, zinc, aluminium, cerium, iron, yttrium or zirconium or mixtures thereof.
5. The method of claim 1 , wherein the metal oxide and/or hydroxide for the particles is selected from the oxides and hydroxides of titanium or mixtures thereof.
6. The method of claim 1 , wherein before the particles have been treated with the organic phosphorus compound, at least one further coating is applied to the particles comprising: metal oxides or hydroxides of silicon, titanium, zinc, aluminium, cerium, iron, yttrium, manganese or zirconium, where the metal is selected differently to the metal of the base particle; organic acids selected from stearic acid, lauric acid, caproic acid or palmitic acid; polyols; polymers; or organosilicone compounds.
7. The method of claim 1 , wherein resulting composition is an aqueous or oily dispersion.
8. The method of claim 1 , wherein the resulting composition is a composition which can be applied topically.
9. The method of claim 1 , wherein the concentration of the dihydroxyacetone or the dihydroxyacetone derivative in the resulting composition is in the range from 1 to 12 per cent by weight, based on the composition.
10. The method of claim 1 , wherein the resulting composition further comprises at least one organic UV filter.
11. The method of claim 1 , wherein the particles are titanium dioxide particles.
12. The method of claim 1 , wherein the organic phosphorus compound used to treat the particles comprises a phosphoric acid monoalkyl ester selected from phosphoric acid monomethyl ester, phosphoric acid monoethyl ester, phosphoric acid monooctyl ester, phosphoric acid monocetyl ester, phosphoric acid monostearyl ester or phosphoric acid monododecyl ester or salts thereof or mixtures thereof.
13. The method of claim 1 , wherein the organic phosphorus compound used to treat the particles comprises phosphoric acid monocetyl ester.
14. The method of claim 1 , wherein the metal oxide particles and/or metal hydroxide particles are titanium dioxide particles and the organic phosphorus compound used to treat the particles comprises a phosphoric acid monoalkyl ester selected from phosphoric acid monomethyl ester, phosphoric acid monoethyl ester, phosphoric acid monooctyl ester, phosphoric acid monocetyl ester, phosphoric acid monostearyl ester or phosphoric acid monododecyl ester or salts thereof or mixtures thereof.
15. The method of claim 6 , wherein the particles are titanium dioxide particles having a coating of silicon dioxide before the treatment with the organic phosphorus compound and the organic phosphorus compound for the treatment is phosphoric acid monocetyl ester.
16. The method of claim 1 , wherein the cosmetic compositions contains at least one cosmetic adjuvant which is a thickener, softener, moisturiser, surface-active agent, emulsifier, preservative, antifoam, perfume, wax, lanolin, propellant, dye or pigment used for cosmetics.