IP Library Granted Patent US 9,127,224
Granted Patent B2
US 9,127,224 · App. 14/484,953 · Granted Sep 8, 2015

External steam reduction method in a fluidized catalytic cracker

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Quick Facts
Patent No.
US 9,127,224
App. No.
14/484,953
Granted
Sep 8, 2015
Kind
B2
Abstract

The present disclosure generally relates to methods to reduce the external steam supplied to a fluidized catalytic cracker by injecting a stream comprising a water-containing renewable fuel oil into a riser of a fluidized catalytic cracker.

Claims (36)

1. A method to reduce the external steam supplied to a fluidized catalytic cracker having a riser, comprising:

injecting a first stream comprising a petroleum fraction into the riser at a first injection point;

injecting a second stream comprising a water-containing unenriched renewable fuel oil into the riser at a second injection point; and

vaporizing the water in the water-containing unenriched renewable fuel oil present in the second stream,

wherein the water-containing unenriched renewable fuel oil comprises:

the product of a mechanical and thermal conversion of a cellulosic biomass comprising grinding and non-catalytic rapid thermal processing to convert at least 60 wt. % of the cellulosic biomass to the water-containing unenriched renewable fuel oil; and

a carbon content of at least 40 wt. % on a moisture-free basis, an oxygen content in the range of between 20-50 wt. % on a moisture-free basis, and a water content in the range of between 10-40 wt. %.

2. The method of claim 1 , wherein the second stream consists substantially of the water-containing renewable fuel oil.

3. The method of claim 1 , wherein the first stream and the second stream together comprise:

i) 93-99.95 wt. % of the petroleum fraction; and

ii) 0.05-7 wt. % of the water-containing unenriched renewable fuel oil.

4. The method of claim 1 , wherein the injecting of the second stream is via a recycle lift vapor line.

5. The method of claim 1 , wherein the injecting of the second stream is via a lift steam line located at the bottom of the riser.

6. The method of claim 1 , wherein the first injection point is above the second injection point.

7. The method of claim 1 , wherein the second injection point is in the lower third of the riser.

8. The method of claim 7 , wherein the first injection point is above the second injection point.

9. The method of claim 1 , wherein the water-containing unenriched renewable fuel oil has a solids content of less than 0.5 wt. %.

10. The method of claim 1 , wherein the water-containing unenriched renewable fuel oil has an ash content of less than 0.05 wt. %.

11. The method of claim 10 , wherein the water-containing unenriched renewable fuel oil has a solids content of less than 0.1 wt. %.

12. The method of claim 1 , wherein the water-containing unenriched renewable fuel oil has an energy content level in the range of between 60-80% of the energy content contained in the cellulosic biomass.

13. A method to reduce the external steam supplied to a fluidized catalytic cracker having a riser, comprising:

injecting a first stream comprising a petroleum fraction into the riser at a first injection point;

injecting a second stream comprising an water-containing unenriched renewable fuel oil into the riser at a second injection point located below the first injection point, the second injection point further located in the lower third of the riser; and

vaporizing the water in the water-containing unenriched renewable fuel oil present in the second stream,

wherein the water-containing unenriched renewable fuel oil comprises:

the product of a mechanical and thermal conversion of a cellulosic biomass comprising grinding and non-catalytic rapid thermal processing to convert at least 60 wt. % of the cellulosic biomass to the water-containing unenriched renewable fuel oil; and

a carbon content of at least 40 wt. % on a moisture-free basis, an oxygen content in the range of between 20-50 wt. % on a moisture-free basis, a water content in the range of between 10-40 wt. %, and a solids content of less than 0.5 wt. %.

14. The method of claim 13 , wherein the first stream and the second stream together comprise:

i) 93-99.95 wt. % of the petroleum fraction; and

ii) 0.05-7 wt. % of the water-containing unenriched renewable fuel oil.

15. The method of claim 14 , wherein the water-containing unenriched renewable fuel oil has an ash content of less than 0.05 wt. % and the solids content is less than 0.1 wt. %.

16. The method of claim 15 , wherein the water-containing unenriched renewable fuel oil has an energy content level in the range of between 60-80% of the energy content contained in the cellulosic biomass.

17. The method of claim 16 , wherein the fluidized catalytic cracker is operated with a catalyst contact time in the range of between 3-5 seconds.

18. The method of claim 16 , wherein the petroleum fraction comprises a heavy gas oil or a heavy-middle distillate feedstock.

19. The method of claim 16 , wherein the cellulosic biomass comprises bagasse, palm fronds, or empty fruit bunches.

20. The method of claim 16 , wherein the cellulosic biomass comprises wood or wood residues.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Sep 3, 2019
From: VENTURE LENDING & LEASING VII, INC.; VENTURE LENDING & LEASING VIII, INC.
To: ENSYN RENEWABLES, INC.
Reel/Frame 050257/0622 →
SECURITY INTEREST Recorded Jan 12, 2016
From: ENSYN RENEWABLES, INC.
To: VENTURE LENDING & LEASING VII, INC.; VENTURE LENDING & LEASING VIII, INC.
Reel/Frame 037470/0040 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 12, 2014
From: FREEL, BARRY A.; GRAHAM, ROBERT G.
To: ENSYN RENEWABLES, INC.
Reel/Frame 033731/0633 →