Multilayer matte biaxially oriented polypropylene film with ultra low seal initiation temperature
View Patent ↗A heat-sealable polymer-based multilayer film having a low sealing initiation temperature, good haze, and low gloss for packaging applications. The film comprises a seal interlayer formed from a blend having a propylene-butene copolymer and a skin layer applied over the seal interlayer, with the seal interlayer being between the skin layer and the core layer.
1. A heat-sealable polymer-based multilayer film comprising:
a polymer-based core layer;
a seal interlayer applied to a first side of the core layer, wherein the seal interlayer consists of a matte resin, two distinct seal-layer propylene-butene copolymers, and optionally antiblock agents;
a skin layer applied over the seal interlayer with the seal interlayer being between the skin layer and the core layer, wherein the skin layer comprises a skin-layer propylene-butene copolymer comprising 20 to 32 wt % butene, wherein the skin layer is formed from a blend comprising polypropylene, polyethylene, and up to 12 wt % of the skin-layer propylene-butene copolymer; and
one or more polymer-based layers applied to a second side of the core layer opposite the first side;
wherein:
the multilayer film is biaxially oriented and has a seal initiation temperature of below 87° C.;
the film has a haze of above 65% as determined by ASTM D 1003-07;
the two distinct seal-layer propylene-butene copolymers comprise a first propylene-butene copolymer and a second propylene-butene copolymer and the first propylene-butene copolymer has a butene content which is at least 10 wt % greater than a butene content of the second propylene-butene copolymer;
the matte resin of the seal interlayer comprises a blend of polypropylene and polyethylene; and
a ratio of propylene-butene copolymer in the seal interlayer to propylene-butene copolymer in the skin layer is between about 5 and about 15.
2. The heat-sealable polymer-based multilayer film of claim 1 wherein the skin layer contains the skin-layer propylene-butene copolymer in a concentration between 6 and 12 wt %.
3. The heat-sealable polymer-based multilayer film of claim 1 wherein the skin-layer propylene-butene copolymer has a composition different from the seal-layer propylene-butene copolymers and the skin layer is devoid of the seal-layer propylene-butene copolymers.
4. The heat-sealable polymer-based multilayer film of claim 1 wherein the skin layer is formed from a blend consisting essentially of said polypropylene, said polyethylene, antiblock additive, and said up to 12 wt % of the skin-layer propylene-butene copolymer.
5. The heat-sealable polymer-based multilayer film of claim 1 wherein the matte resin of the seal interlayer comprises between 40 and 60 wt % polypropylene and between 40 and 60 wt % polyethylene.
6. The heat-sealable polymer-based multilayer film of claim 1 wherein:
the first propylene-butene copolymer has a butene content which is between 20 and 40 wt % greater than a butene content of the second propylene-butene copolymer.
7. The heat-sealable polymer-based multilayer film of claim 5 wherein:
the first propylene-butene copolymer has a butene content which is between 20 and 40 wt % greater than a butene content of the second propylene-butene copolymer.
8. The heat-sealable polymer-based multilayer film of claim 1 wherein:
the matte resin constitutes between 17 and 25 wt % of the seal interlayer, the first propylene-butene copolymer constitutes between 20 and 30 wt % of the seal interlayer, and the second propylene-butene copolymer constitutes between 40 and 60 wt % of the seal interlayer.
9. The heat-sealable polymer-based multilayer film of claim 5 wherein:
the matte resin constitutes between 17 and 25 wt % of the seal interlayer, the first propylene-butene copolymer constitutes between 20 and 30 wt % of the seal interlayer, and the second propylene-butene copolymer constitutes between 40 and 60 wt % of the seal interlayer.
10. The heat-sealable polymer-based multilayer film of claim 4 wherein the skin layer contains the skin-layer propylene-butene copolymer in a concentration between 6 and 12 wt %.
11. The heat-sealable polymer-based multilayer film of claim 1 wherein:
the core layer comprises from 90 to 100 wt % of a homopolymer of polypropylene.
12. The heat-sealable polymer-based multilayer film of claim 1 wherein:
the one or more polymer-based layers applied to the second side of the core layer opposite the first side consist of a single layer having a thickness in the range of about 0.7 to about 1.3 μm.
13. The heat-sealable polymer-based multilayer film of claim 1 wherein:
the one or more polymer-based layers applied to the second side of the core layer opposite the first side consist of a first layer having a thickness in the range of about 0.5 to about 1.0 μm and a second layer having a thickness in the range of about 0.7 to about 1.3 μm.
14. The heat-sealable polymer-based multilayer film of claim 1 wherein:
the seal interlayer has a thickness between about 1 and about 3 μm and comprises a matte resin which comprises a blend of polypropylene and polyethylene, and two distinct seal-layer propylene-butene copolymers comprising a first propylene-butene copolymer and a second propylene-butene copolymer wherein the first propylene-butene copolymer has a butene content which is between about 16 and about 28 wt % butene and the second propylene-butene copolymer has a butene content of less than about 16 wt %;
the skin layer has a thickness in the range of about 1.5 to about 4 μm and contains the skin-layer propylene-butene copolymer in a concentration between 6 and 12 wt %, the skin layer propylene-butene copolymer contains between about 20 and about 32 wt % butene and has a composition different from the seal-layer propylene-butene copolymer and the skin layer is devoid of the propylene-butene copolymers of the seal layer; and
the core layer has a thickness in the range of about 8 to about 16 μm and comprises from 90 to 100% of a homopolymer of polypropylene.
15. The heat-sealable polymer-based multilayer film of claim 1 wherein the skin layer consists of the polypropylene, the polyethylene, the skin-layer propylene-butene copolymer in a concentration of no more than 12 wt %, an optional antiblock additive, and an optional fluoroelastomer.
16. The heat-sealable polymer-based multilayer film of claim 1 wherein:
the skin layer contains between 6 and 12 wt % of the skin-layer propylene-butene copolymer, and the propylene-butene has butene (C4) content of from 20 to 30 wt. %.
17. The heat-sealable polymer-based multilayer film of claim 1 wherein the film has a haze of above 75% as determined by ASTM D 1003-07.