Process for producing 2, 3, 3, 3-tetrafluoropropene
View Patent ↗To provide an economically advantageous process for producing industrially useful HFO-1234yf efficiently and in a sufficiently controlled state by one reaction involving thermal decomposition, by using readily available raw material. A process for producing 2,3,3,3-tetrafluoropropene from a raw material composition containing chlorodifluoromethane and chloromethane, by a synthetic reaction involving thermal decomposition, which comprises (a) a step of supplying the chlorodifluoromethane and the chloromethane to a reactor, as preliminarily mixed or separately, in such amounts that the chloromethane would be in a ratio of from 0.01 to 3 mol to 1 mol of the chlorodifluoromethane, (b) a step of supplying a heat medium to the reactor, and (c) a step of bringing the heat medium in contact with the chlorodifluoromethane and the chloromethane in the reactor to form the 2,3,3,3-tetrafluoropropene.
1. A process for producing 2,3,3,3-tetrafluoropropene from chlorodifluoromethane and chloromethane, the process comprising:
(a) supplying chlorodifluoromethane and chloromethane to a reactor, as preliminarily mixed or separately, in a molar ratio of chloromethane to chlorodifluoromethane of from 0.01 to 3,
(b) supplying a heat medium to the reactor, and
(c) contacting the heat medium with chlorodifluoromethane and chloromethane in the reactor to form 2,3,3,3-tetrafluoropropene.
2. The process according to claim 1 , wherein the molar ratio of chloromethane to chlorodifluoromethane is from 0.01 to 1.5.
3. The process according to claim 1 , wherein
in said contacting (c), 1,1-difluoroethylene is further formed, and
a molar ratio of 2,3,3,3-tetrafluoropropene to 1,1-difluoroethylene is at least 0.14.
4. The process according to claim 1 , wherein a temperature in the reactor in said contacting (c) is adjusted to be from 400 to 1,200° C.
5. The process according to claim 4 , wherein the temperature in the reactor is adjusted to be from 600 to 900° C.
6. The process according to claim 4 , wherein the temperature in the reactor is adjusted to be from 710 to 830° C.
7. The process according to claim 1 , wherein chloromethane is supplied to the reactor at a temperature of from 0 to 1,200° C.
8. The process according to claim 7 , wherein the temperature of chloromethane supplied to the reactor is from 100 to 600° C.
9. The process for producing 2,3,3,3-tetrafluoropropene according to claim 1 , wherein chlorodifluoromethane is supplied to the reactor at a temperature of from 0 to 600° C.
10. The process according to claim 9 , wherein the temperature of chlorodifluoromethane supplied to the reactor is from 100 to 500° C.
11. The process according to claim 1 , wherein the heat medium is at least one selected from the group consisting of steam, nitrogen and carbon dioxide.
12. The process according to claim 1 , wherein the heat medium is supplied to the reactor at a temperature of from 100 to 1,200° C.
13. The process according to claim 1 , wherein the heat medium is supplied to the reactor at an amount of from 20 to 98 vol % in an entire gas supplied to the reactor.
14. The process according to claim 1 , wherein a contact time of the heat medium with chlorodifluoromethane and chloromethane in said contacting (c) is from 0.01 to 10 seconds.
15. The process according to claim 1 , further comprising:
(d) after said contacting (c), withdrawing from the reactor a reaction mixture comprising 2,3,3,3-tetrafluoropropene formed in the reactor,
wherein said supplying (a), said supplying (b), and said withdrawing (d) are continuously carried out.