IP Library Granted Patent US 9,669,265
Granted Patent B2
US 9,669,265 · App. 14/487,225 · Granted Jun 6, 2017

Three-cover-layer golf ball having transparent or plasticized polyamide intermediate layer

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Quick Facts
Patent No.
US 9,669,265
App. No.
14/487,225
Granted
Jun 6, 2017
Kind
B2
Abstract

A golf ball includes a core and a three-layer cover disposed adjacent the core. The three-layer cover includes an inner cover, an intermediate cover, and an outer cover. The inner cover includes a non-ionomeric E/Y copolymer where E is an olefin and Y is a carboxylic acid. The inner cover has a hardness of about 45 to 68 Shore D. The outer cover includes a castable thermoset polyurethane and has a hardness of about 40 to 62 Shore D. The intermediate cover layer, disposed between the inner and outer cover layers, is formed from a polyamide composition, where the polyamide composition includes a transparent polyamide having a light transmission of about 50% or greater.

Claims (28)

1. A golf ball comprising:

a core; and

a cover disposed adjacent the core, the cover comprising:

a non-ionomeric inner cover layer comprising an E/Y copolymer where E is an olefin and Y is a carboxylic acid, the inner cover being disposed about the core and having a hardness of 45 Shore D to 68 Shore D;

a castable thermoset polyurethane outer cover layer having a hardness between 40 Shore D and 62 Shore D; and

an intermediate cover layer disposed between the inner and outer cover layers, the intermediate layer comprising a polyamide composition;

wherein the polyamide composition comprises a transparent polyamide having a light transmission of about 50% or greater and has a ratio of Charpy notched impact-resistance measured at 23° C. and measured at −30° C. of at least about 2.0.

2. The golf ball of claim 1 , wherein the transparent polyamide comprises a transparent polyether-amide block copolymer.

3. The golf ball of claim 1 , wherein the transparent polyamide has an amorphous, quasi-amorphous, semicrystalline, or microcrystalline structure.

4. The golf ball of claim 1 , wherein the transparent polyamide has a glass transition temperature in the range of about 75° C. to about 160° C.

5. The golf ball of claim 4 , wherein the transparent polyamide has a glass transition temperature in the range of about 80° C. to about 95° C.

6. The golf ball of claim 1 , wherein the Charpy notched impact-resistance is about 50 kJ/m 2 or greater when measured at 23° C.

7. The golf ball of claim 1 , wherein the transparent polyamide has a light transmission of about 80% or greater.

8. The golf ball of claim 7 , wherein the light transmission is about 90% or greater.

9. The golf ball of claim 1 , wherein the intermediate layer hardness is greater than the inner cover layer hardness.

10. The golf ball of claim 9 , wherein the intermediate layer hardness is greater than the inner cover layer hardness by at least 5 Shore D.

11. The golf ball of claim 1 , wherein the intermediate layer hardness is greater than the outer cover layer hardness.

12. The golf ball of claim 11 , wherein the intermediate layer hardness is greater than the outer cover layer hardness by at least 5 Shore D.

13. The golf ball of claim 1 , wherein the core comprises a center and at least one outer core layer.

14. The golf ball of claim 1 , wherein the non-ionomeric inner cover layer further comprises a polyester/polycarbonate blend, a polyester resin, an acetal resin, a polyamide resin, a polyetheramide resin, a polyester resin, a polyester elastomer, a liquid crystalline polyester, a polyester/polyamide blend, a poly(arylene ether)/polyester resin, or a polyimide.

15. The golf ball of claim 1 , wherein the olefin is ethylene and the carboxylic acid is acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, or a combination thereof.

16. A golf ball comprising:

a core; and

a cover disposed adjacent the core, the cover comprising:

a non-ionomeric inner cover layer comprising an E/Y copolymer where E is an olefin and Y is a carboxylic acid, the inner cover being disposed about the core and having a hardness of 45 Shore D to 68 Shore D;

a castable thermoset polyurethane outer cover layer having a hardness between 40 Shore D and 62 Shore D; and

an intermediate cover layer disposed between the inner and outer cover layers, the intermediate layer comprising a polyamide composition;

wherein the polyamide composition comprises a transparent polyamide having a light transmission of about 50% or greater, and about 1% by weight to about 60% by weight of an acid anhydride-modified polyolefin.

Assignments (6)
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (034623/0720) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0483 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY INTEREST Recorded Jan 4, 2015
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 034623/0720 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 16, 2014
From: SULLIVAN, MICHAEL J.; BULPETT, DAVID A.; BLINK, ROBERT; BINETTE, MARK L.; COMEAU, BRIAN
To: ACUSHNET COMPANY
Reel/Frame 033746/0334 →